Pablo
García-Álvarez - Publications
2019
83. A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral
copper(I) and T-shaped silver(I) and gold(I) PGeP pincer complexes.
J.A. Cabeza, I. Fernández, P. García-Álvarez and C.J. Laglera-Gándara, Dalton Trans., 2019, 48, 13273-13280.
82. A germylene supported by two 2-pyrrolylphosphane groups as precursor to
PGeP pincer square-planar Group 10 metal(II) and T-shaped gold(I) complexes.
J.A. Cabeza, I. Fernández, J.M. Fernández-Colinas, P. García-Álvarez and
C.J. Laglera-Gándara, Chem. Eur. J., 2019, 25, 12423-12430.
81. Mesityl(amidinato)tetrylenes as ligands in iridium(I) and iridium(III)
complexes: Silicon versus germanium and simple κ1-coordination
versus cyclometallation.
J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, L. González-Álvarez and E. Pérez-Carreño, Dalton Trans., 2019, 48, 10996-11003.
80. Two types of σ-allenyl complexes from reactions of silylenes and
germylenes with chromium Fischer alkynyl(alkoxy)carbenes.
J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 8635-8642.
79. Unexpected zwitterionic allenyls from silylenes and a Fischer
alkynylcarbene: A remarkable silylene-promoted rearrangement.
J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 2222-2225.
78. Reversible carbene insertion into a Ge–N Bond and insights into CO- and
carbene-substitution reactions involving amidinatogermylenes and Fischer
carbene complexes.
L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 1588-1594.
2018
77. Ruthenium carbene complexes analogous to Grubbs-I catalysts featuring
germylenes as ancillary ligands.
L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2018, 37, 3399-3406.
76. Synthesis and some coordination chemistry of the PSnP pincer-type
stannylene Sn(NCH2PtBu2)2C6H4,
attempts to prepare the PSiP analogue, and effect of the E atom on the molecular
structures of E(NCH2PtBu2)2C6H4
(E = C, Si, Ge, Sn).
J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Dalton Trans., 2018, 47, 4534-4544.
75. From a PGeP pincer-type germylene to metal complexes featuring chelating
(Ir) and tripodal (Ir) PGeP germyl and bridging (Mn2) and chelating
(Ru) PGeP germylene ligands.
J. Brugos, J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2018, 37, 1507-1514.
2017
74. From a diphosphanegermylene to nickel, palladium and platinum complexes
containing germyl PGeP pincer ligands.
L. Álvarez-Rodríguez, J. Brugos, J.A.
Cabeza, P. García-Álvarez and E. Pérez-Carreño, Chem.–Eur. J., 2017,
23, 15107-15115.
73. Facile cyclometallation of a mesitylsilylene: Synthesis and preliminary
catalytic activity of iridium(III) and iridium(V) iridasilacyclopentenes.
J.A. Cabeza, P. García-Álvarez and L. González-Álvarez, Polo, Chem. Commun., 2017, 53, 10275-10278.
72. Tetrilenos pesados: Aspectos generales y aplicaciones en catálisis homogénea.
J.A. Cabeza and P. García-Álvarez, An.
Quim., 2017, 113, 77-91.
71. First insertions of carbene ligands into Ge–N and Si–N bonds.
L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2017, 23, 4287-4291.
70. Octahedral manganese(I) and ruthenium(II) complexes containing
2-(methylamido)pyridine-borane as a tripod k3N,H,H-ligand.
J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and J.F. Van der Maelen, Dalton Trans., 2017, 46, 4009-4017.
69. Synthesis and initial transition metal chemistry of the first PGeP
pincer-type germylene.
L. Álvarez-Rodríguez, J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Chem Commun., 2017, 53, 893-896.
2016
68. 2-(Methylamido)pyridine-borane:
A tripod κ3N,H,H-ligand in trigonal bipyramidal rhodium(I)
and iridium(I) complexes with an asymmetric coordination of its BH3
group.
J. Brugos, J.A. Cabeza, P.
García-Álvarez, A.R. Kennedy, E. Pérez-Carreño and J.F. van der Maelen Inorg.
Chem., 2016, 55, 8905-8912.
67. Amidinatogermylene
metal complexes as homogeneous catalysts in alcoholic media.
L. Álvarez-Rodríguez, J.A. Cabeza, J.M Fernández-Colinas, P. García-Álvarez and D. Polo, Organometallics, 2016, 35, 2516-2523.
66. [MnBrL(CO)4]
(L = amidinatogermylene): Reductive dimerization, carbonyl substitution, and
hydrolysis reactions.
J.A. Cabeza, P. García-Álvarez, R. Gobetto, L. González-Álvarez, C. Nervi, E. Pérez-Carreño and D. Polo, Organometallics, 2016, 35, 1761-1770.
65. Fully
borylated methane and ethane by ruthenium-mediated cleavage and coupling of CO.
A.S. Batsanov, J.A. Cabeza, M.G. Crestani,
M.R. Fructos, P. García-Álvarez, M. Gille, Z. Lin and T.B. Marder, Angew. Chem.
Int. Ed., 2016, 55, 4707-4710; Angew. Chem.,
2016, 128, 4785-4788.
64. Intramolecularly stabilized
heavier tetrylenes: From monodentate to bidentate ligands.
J.A. Cabeza, P. García-Álvarez and D.
Polo., Eur. J. Inorg. Chem., 2016, 10-22
(invited review).
2015
63. Amidinatogermylene
complexes of copper, silver, and gold.
L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and D. Polo, Organometallics, 2015, 34, 5479-5484
62. Reactivity Studies on a
Binuclear Ruthenium(0) Complex Equipped with a Bridging κ2N,Ge-Amidinatogermylene
Ligand.
J.A. Cabeza, J.M. Fernández-Colinas, P.
García-Álvarez, E. Pérez-Carreño and D. Polo., Inorg. Chem.,
2015, 54, 4850-4861.
61. The transition-metal chemistry
of amidinatosilylenes, -germylenes and -stannylenes.
L. Álvarez-Rodríguez, J.A. Cabeza, P.
García-Álvarez and D. Polo, Coord. Chem. Rev., 2015,
300, 1-28 (invited review).
60. Amidinatogermylene Derivatives
of Ruthenium Carbonyl: New Insights into the Reactivity of [Ru3(CO)12]
with 2-Electron-Donor Reagents of High Basicity.
L. Álvarez-Rodríguez, J.A. Cabeza, P.
García-Álvarez, E. Pérez-Carreño and D. Polo., Inorg. Chem.,
2015, 54, 2983-2994.
2014
59. Conversion of a Monodentate
Amidinate−Germylene Ligand into Chelating Imine−Germanate Ligands (on
Mononuclear Manganese Complexes).
J.A. Cabeza, P. García-Álvarez, E.
Pérez-Carreño and D. Polo, Inorg. Chem., 2014,
53, 8735-8741.
58. Steric effects in the reactions
of amidinate germylenes with ruthenium carbonyl: isolation of a coordinatively
unsaturated diruthenium(0) derivative.
J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez and D. Polo, RSC Adv., 2014, 4, 31503-31506.
57. Structural and reactivity
insights in Mg-Zn hybrid chemistry: Zn-I exchange and Pd-catalysed
crosscoupling applications of aromatic substrates.
T.D.
Bluemke, W. Clegg, P. García-Alvarez, A.R. Kennedy, K. Koszinowski, M.D.
McCall, L. Russo and E. Hevia, Chem. Sci., 2014, 5, 3552-3562.
56. Complexity in seemingly simple sodium magnesiate systems.
J. Francos, B.J. Fleming, P. García-Álvarez, A.R. Kennedy, K. Reilly, G.M. Robertson, S.D. Robertson and C.T. O’Hara, Dalton Trans., 2014, 14424-14431.
55. Ring Opening and Bidentate Coordination of Amidinate Germylenes and Silylenes on Carbonyl Dicobalt Complexes: The Importance of a Slight Difference in Ligand Volume.
J.A. Cabeza, P. García-Álvarez. E. Pérez-Carreño and D. Polo, Chem. Eur. J., 2014, 20, 8654-8663.
2013
54. Reactivity of a (Bis-NHC)tricarbonylruthenium(0) Complex with Methyl Triflate and Methyl Iodide. Formation of Methyl- and Acetylruthenium(II) Derivatives: Experimental Results and Mechanistic DFT Calculations.
J.A. Cabeza, M. Damonte, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2013, 32, 4382-4390.
53. Organic Amides as Suitable Precursors to Stabilize Stannylenes.
L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and D. Polo, Organometallics, 2013, 32, 3557-3561.
52. Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: Experimental and computational studies.
J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, E. Pérez-Carreño, V. Pruneda and J.F. Van der Maelen, Chem. Eur. J., 2013, 19, 9251-9260.
51. Easy abstraction of a hydride anion from an alkyl C-H bond of a coordinated bis(N-heterocyclic carbene).
J.A. Cabeza, M. Damonte, P. García-Álvarez and E. Pérez-Carreño, Chem. Commun., 2013, 2813-2815.
50. Synthesis and Reactivity of Cationic Triruthenium Clusters Derived from 2-Methyl- and 4-Methylpyrimidines: From Conventional Cyclometalated Ligands to Novel Types of N-Heterocyclic Carbenes.
J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and V. Pruneda, Chem. Eur. J., 2013, 19, 3426-3436.
49. Expanding the coordination chemistry of donor-stabilized group-14 metalenes.
J.A. Cabeza, P. García-Álvarez and D. Polo, Dalton Trans., 2013, 1329-1333.
48. Structural elucidation of homometallic anthracenolates synthesised via deprotonative metallation of anthrone.
W. Clegg, B.J. Fleming, P. García-Álvarez, L.M. Hogg, A.R. Kennedy, J. Klett, A.J. Martínez-Martínez, R.E. Mulvey, L. Russo and C.T. O’Hara, Dalton Trans., 2013, 2512-2519.
2012
47. Synthesis, Structural Elucidation, and Diffusion-Ordered NMR Studies of Homoleptic Alkyllithium Magnesiates: Donor-Controlled Structural Variations in Mixed-Metal Chemistry.
S.E. Baillie, W. Clegg, P. García-Álvarez, E. Hevia, A.R. Kennedy, J. Klett and L. Russo, Organometallics, 2012, 31, 5131-5142.
46. Reactions of SCNPh and CS2 Adducts of N-Heterocyclic Carbenes with [Ru3(CO)12]: Novel Reactivity of These Betaines Involving One or Two C-S Bond Activation Processes.
J.A. Cabeza, P. García-Álvarez and M.G. Hernández-Cruz, Eur. J. Inorg. Chem., 2012, 2928-2932.
45. Diaminogermylene and Diaminostannylene Derivatives of Gold(I): Novel AuM and AuM2 (M = Ge, Sn) Complexes.
J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez and D. Polo, Inorg. Chem., 2012, 51, 3896-3903.
44. Deprotonation of C-alkyl groups of cationic N-heterocyclic ligands.
J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and V. Pruneda, Dalton Trans., 2012, 41, 4313-4315.
43. The reaction of [Ru3(CO)12] with phenazine: Synthesis of C-Metalated derivatives that formally arise from a C-H oxidative addition or a long-distance C-to-N prototropy.
J.A. Cabeza, P. García-Álvarez and V. Pruneda, Organometallics, 2012, 31, 941-946.
42. Synthesis of mixed Tin-Ruthenium and Tin-Germanium-Ruthenium carbonyl clusters from [Ru3(CO)12] and diaminometalenes (M = Sn, Ge).
J.A. Cabeza, P. García-Álvarez and D. Polo, Inorg. Chem., 2012, 51, 2569-2576.
41. Reactivity of phosphine- and thioether-tethered N-heterocyclic carbenes with ruthenium carbonyl.
J.A. Cabeza, M. Damonte, P. García-Álvarez, M.G. Hernández-Cruz and A.R. Kennedy, Organometallics, 2012, 31, 327-324.
40. Synthesis and structural elucidation of a rare example of a tris(amido) potassium magnesiate.
B.J. Fleming, P. García-Álvarez, E. Keating, A.R. Kennedy and C.T. O′Hara, Inorg. Chim, Acta, 2012, 384, 154-157.
2011
39. “LiZn(TMP)3”, a zincate or a Turbo-lithium amide reagent? DOSY NMR spectroscopic evidence.
P. García-Álvarez, R.E. Mulvey and J.A. Parkinson, Angew. Chem. Int. Ed., 2011, 50, 9668-9671.
38. Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: Experimental and DFT evidence for alkali metal-Zinc synergistic effects.
R. Campbell, D. Cannon, P. García-Álvarez, A.R. Kennedy, R.E. Mulvey, S.D. Robertson, J. Saßmannshausen and T. Tuttle, J. Am. Chem. Soc., 2011, 133, 13706-13717.
37. Reactivity of diaminogermylenes with Ruthenium carbonyl: Ru3Ge3 and RuGe2 derivatives.
J.A. Cabeza, P. García-Álvarez and D. Polo, Inorg. Chem., 2011, 50, 6195-6199.
36. The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters.
J.A. Cabeza and P. García-Álvarez, Chem. Soc. Rev., 2011, 40, 5389-5405.
35. Expanding Mg-Zn hybrid chemistry: Inorganic salt effects in addition reactions of organozinc reagents to trifluoromethyl acetophenone and implications for a synergistic lithium-magnesium-zinc activation.
D.R. Armstrong, W. Clegg, P. García-Álvarez, A.R. Kennedy, M.D. McCall, L. Russo and E. Hevia, Chem. Eur. J., 2011, 17, 8333-8341.
34. Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: X-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic studies.
D. R. Armstrong, P. García-Álvarez, A.R. Kennedy, R.E. Mulvey and S.D. Robertson, Chem. Eur. J., 2011, 17, 6725-6730.
33. Different reactivities of pyrid-2-yl- and 6-picol-2-yl-functionalized NHC ligands with [Ru3(CO)12]: C(sp2)-H and double C(sp3)-H bond activation reactions.
J.A. Cabeza, M. Damonte and P. García-Álvarez, Organometallics, 2011, 30, 2371-2376.
32. Synthesis and structural chemistry of alkali metal tris(HMDS) magnesiates containing chiral diamine donor ligands.
P. García-Álvarez, A.R. Kennedy, C.T. O’Hara, K. Reilly and G.M. Robertson, Dalton Trans., 2011, 40, 5332-5341.
31. Reactivity of [Ru3(CO)12] with a phosphine-functionalized imidazol-2-ylidene and its imidazolium salt.
J.A. Cabeza, M. Damonte, P. García-Álvarez, A.R. Kennedy and E. Pérez-Carreño, Organometallics, 2011, 30, 826-833.
30. Shedding new light on ZnCl2-mediated addition reactions of Grignard reagents to ketones: Structural authentication of key Intermediates and diffusion-ordered NMR studies
D.R. Armstrong, W. Clegg, P. García-Álvarez, M.D. McCall, L. Nuttall, A.R. Kennedy, L. Russo and E. Hevia, Chem. Eur. J., 2011, 17, 4470-4479.
29. Synthesis and characterization of an infinite sheet of metal-alkyl bonds: unfolding the elusive structure of an unsolvated alkali-metal trisalkylmagnesiate
S.E. Baillie, W. Clegg, P. García-Álvarez, E. Hevia, A.R. Kennedy, J. Klett and L. Russo, Chem. Commun., 2011, 47, 388-390.
2010
E. Crosbie, P. García-Álvarez, A.R. Kennedy, J. Klett, R.E. Mulvey y S.D. Robertson, Angew. Chem. Int. Ed., 2010, 49, 9388-9391.
27. Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture
R. Campbell, P. García-Álvarez, A.R. Kennedy y R.E. Mulvey, Chem. Eur. J., 2010, 16, 9964-9968.
26. Structural insights into mono-amido tris-alkyl potassium aluminates
B. Conway, P. García-Álvarez, A.R. Kennedy, J. Klett, R.E. Mulvey S.D. Robertson, New J. Chem., 2010, 34, 1707-1712.
25. Diisopropylamide and TMP Turbo-Grignard reagents: A structural rationale for their contrasting reactivities
D.R. Armstrong, P. García-Álvarez, A.R. Kennedy, R.E. Mulvey and J.A. Parkinson, Angew. Chem. Int. Ed., 2010, 49, 3185-3188.
24. Exposing the hidden complexity of stoichiometric and catalytic metathesis reactions: Elucidation and applications of Mg-Zn hybrids
E. Hevia, J.Z. Chua, P. García-Álvarez, A.R. Kennedy and M.D. McCall, P.N.A.S., 2010, 107, 5294-5299.
23. cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?
R. Campbell, B. Conway, G.S. Fairweather, P. García-Álvarez, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O’Hara y G.M. Robertson, Dalton Trans., 2010, 39, 511-519.
22. Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations.
W. Clegg, B. Conway, P. García-Álvarez, A.R. Kennedy, J. Klett, R.E. Mulvey and L. Russo, Dalton Trans., 2010, 39, 62-65.
2009
21. Reactions of (−)-sparteine with alkali metal HMDS complexes: conventional meets the unconventional.
N.M. Clark, P. García-Álvarez, A.R. Kennedy, C.T. O’Hara y G.M. Robertson, Chem. Commun., 2009, 5835-5837.
20. Structural tracking of the potassium-mediated magnesiation of anisole.
W. Clegg, B. Conway, P. García-Álvarez, A.R. Kennedy, R.E. Mulvey, L. Russo, J. Saßmannshausen and T. Tuttle, Chem. Eur. J., 2009, 15, 10702-10706.
19. Synergic synthesis of benzannulated zincabicyclic complexes, a-zincated N-ylides, through sodium-TMEDA-mediated zincation of a haloarene.
D.R. Armstrong, L. Balloch, W. Clegg, S.H. Dale, P. García-Álvarez, E. Hevia, L.M. Hogg, A.R. Kennedy, R.E. Mulvey y C.T. O´Hara, Angew. Chem. Int. Ed., 2009, 48, 8675-8678.
18. Structural variations within group 1 (LiCs)+TEMPOcomplexes made via metallic reduction of the nitroxyl radical TEMPO.
L. Balloch, A.M. Drummond, P. García-Álvarez, D.V. Graham, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O'Hara, P.J.A. Rodger y I.D. Rushworth, Inorg. Chem., 2009, 48, 6934-6944.
17. Direct C−H metalation with chromium(II) and iron(II): Transition-metal host/benzenediide guest magnetic inverse crown complexes.
P. Alborés, L.M. Carrella, W. Clegg, P. García-Álvarez, A.R. Kennedy, J. Klett, R.E. Mulvey, E. Rentschler and L. Russo, Angew. Chem. Int. Ed., 2009, 48, 3317-3321.
2008
16. Unmasking representative structures of TMP-active Hauser and Turbo Hauser bases.
P. García-Álvarez, D.V. Graham, E. Hevia, A.R. Kennedy, J. Klett, R.E. Mulvey, C.T. O’Hara y S. Weatherstone, Angew. Chem. Int. Ed., 2008, 47, 8079-8081.
15. Basal edge-bridged square pyramidal hexaruthenium carbonyl clusters: Synthesis, structure, and reactivity.
J.A. Cabeza and P. García-Álvarez, Organometallics, 2008, 27, 2877-2891.
14. Synthesis, structural authentication, and structurally defined metalation reactions of lithium and sodium DA-zincate bases (DA = diisopropylamide) with phenylacetylene.
W. Clegg, J. García-Álvarez, P. García-Álvarez, D.V. Graham, R.W. Harrington, E. Hevia, A.R. Kennedy, R.E. Mulvey and L. Russo, Organometallics, 2008, 27, 2654-2663.
2007
13. A new coordination mode for (pyrid-2-yl)thiolate (L) ligands. Synthesis and characterization of [Ru6(μ3-H)(μ5-k2-L)(μ-CO)(CO)15].
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, J. Organomet. Chem., 2007, 692, 3583-3587.
12. High-nuclearity osmium carbonyl cluster complexes containing (6-methylpyrid-2-yl)imido ligands. Synthesis of hepta-, octa-, and nonanuclear derivatives.
J.A. Cabeza, I. del Río; P. García-Álvarez and D. Miguel, Organometallics, 2007, 26, 3212-3216.
11. Ruthenium cluster mediated transformation of linear alkenes into trienyl ligands. Activation of five C(sp3)-H bonds of 1-octene, 1-nonene, and 1-decene.
J.A. Cabeza; I. del Río; P. García-Álvarez and D. Miguel, Organometallics, 2007, 26, 2482-2484.
10. Reactivity of indene, fluorene, azulene, and acenaphthylene with a basal edge-bridged square pyramidal hexaruthenium dihydride.
J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, P. García-Álvarez and D. Miguel, Organometallics, 2007, 26, 1414-1423.
2006
9. Nonanuclear ruthenium carbonyl cluster complexes with a novel metallic skeleton: Pentagonal bipyramid with two equatorial edges spanned by metal atoms.
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, Organometallics, 2006, 25, 5672-5675.
8. High-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: Synthesis of nonanuclear derivatives containing µ4- and µ5-oxo ligands.
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, Inorg. Chem., 2006, 45, 6020-6027.
7. Reactivity of arenes, cycloheptatriene, and dicyclopentadiene with a basal edge-bridged square pyramidal hexaruthenium dihydride.
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, Organometallics, 2006, 25, 2683-2692.
6. Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine. Novel coordination modes for 2-imidopyridines.
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, Can. J. Chem., 2006, 84, 105-110.
5. Reactivity of diphenylbutadiyne with a hexaruthenium dihydride. Unusual 1,1- and trans-1,2-additions of two hydrogen atoms to an internal CC triple bond.
J.A. Cabeza, I. del Río, J. M. Fernández-Colinas, P. García-Álvarez and D. Miguel, Organometallics, 2006, 25, 1492-1499.
2005
4. Can m4-alkyne and m3-alkenyl ligands be considered as six- and five-electron donors, respectively?
J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2005, 24, 2000-2003.
3. Reactivity of diphenylacetylene with a basal edge-bridged square pyramidal hexaruthenium cluster. Characterization of penta-, hexa-, and heptanuclear alkyne derivatives.
J.A. Cabeza, I. del Río, P. García-Álvarez and D. Miguel, Organometallics, 2005, 24, 665-674.
2004
2. Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions.
J.A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel and V. Riera, Inorg. Chem., 2004, 43, 5450-5458.
2003
1. Hexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studies.
J.A. Cabeza, I. del Río, P. García-Álvarez, V. Riera, M. Suárez and S. García-Granda, Dalton Trans., 2003, 2808-2809.