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                                                                                        Última actualización: 7 de Noviembre 2017

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2018  2017  2016  2015  2014  2013  Anterior     

 

 

 

Año 2018

  • The intermolecular hydro-oxycarbonylation of internal alkynes: Current state of the art. P. J. González-Liste, J. Francos, S. E. García Garrido, V. Cadierno, Arkivoc, 2018, ii, 17-39.

 

Año 2017

  • Phosphinous acid-assisted hydration of nitriles: Understanding the controversial reactivity of osmium and ruthenium catalysts. R. González-Fernández, P. Crochet, V. Cadierno, M. I. Menéndez, R. López, Chem. Eur. J., 2017, 23, 15210-15221.

  • Combination of metal-catalyzed cycloisomerizations and biocatalysis in aqueous media: asymmetric construction of chiral alcohols, lactones and g-hydroxy-carbonyl compounds. M. J. Rodríguez-Álvarez, N. Ríos-Lombardía, S. Schumacher, D. Pérez-Iglesias, F. Morís, V. Cadierno, J. García-Álvarez, J. Gonzalez-Sabin, ACS Catal., 2017, 7, 7753-7759.

  • New iminophosphorane-Au(I) complexes as efficient catalysts for the cycloisomerization of alkynyl amides under air, room temperature and in aqueous or eutectic mixture solutions. M. J. Rodríguez-Álvarez, C. Vidal, S. Schumacher, J. Borge, J. García-Álvarez, Chem. Eur. J., 2017, 23, 3425-3431.

  • Gold-catalyzed regio- and stereoselective addition of carboxylic acids to iodoalkynes: Access to (Z)-b-iodoenol esters and 1,4-disubstituted (Z)-enynyl esters. P. J. González-Liste, J. Francos, S. E. García-Garrido, V. Cadierno, J. Org. Chem., 2017, 82,1507-1516.

  • Gold(I)-catalyzed addition of carboxylic acids to internal alkynes in aqueous medium. P. J. González-Liste, S. E. García-Garrido, V. Cadierno, Org. Biomol. Chem., 2017, 15, 1670-1679.

  • Broad scope synthesis of ester precursors of nonfunctionalized chiral alcohols based on the asymmetric hydrogenation of a,b-dialkyl-, a,b-diaryl-, and a-alkyl-b-aryl-vinyl esters. F. León, P. J. González-Liste, S. E. García-Garrido, I. Arribas, M. Rubio, V. Cadierno, A. Pizzano, J. Org. Chem., 2017, 82, 5852-5867.

  • One-pot sustainable synthesis of tertiary alcohols by combining ruthenium-catalysed isomerization of allylic alcohols and chemoselective addition of polar organometallic reagents in Deep Eutectic Solvents. L. Cicco, M. J. Rodríguez-Álvarez, F. M. Perna, J. García-Álvarez, V. Capriati, Green Chem., 2017, 19, 3069-3077.

  • Water-tolerant bis(allyl)-ruthenium(IV) catalysts: An account of their applications. J. Francos, S. E. García-Garrido, J. García-Álvarez, P. Crochet, J. Gimeno, V. Cadierno, Inorg. Chim. Acta, 2017, 455, 398-414.

  • Mixed-valence μ3-oxo-centered triruthenium cluster [Ru3(II,III,III)(μ3-O)(μ-CH3CO2)6(H2O)3]·2H2O: Synthesis, structural characterization, valence-state delocalization and catalytic behavior. A. Dikhtiarenko, S. Khainakov, J. R. García, J. Gimeno, Inorg. Chim. Acta, 2017, 454,107-116.

  • Half-sandwich ruthenium(II) complexes with water-soluble Schiff base ligands: Synthesis and catalytic activity in transfer hydrogenation of carbonyl compounds. S. Azizi Talouki, G. Grivani, P. Crochet, V. Cadierno, Inorg. Chim. Acta, 2017, 456, 142-148.

  • Gold-catalyzed intermolecular formal insertion of aryldiazo esters into Cp-H bond of Cp2M (M = Fe, Ru). E. López, J. Borge, L. A. López, Chem. Eur. J., 2017, 23, 3091-3097.

  • Amido-pincer complexes of Cu(II): Synthesis, coordination chemistry and applications in catalysis. M. Taghvaee, M. J. Rodríguez-Álvarez, J. García-Álvarez, I. del Río, A. J. Lough, R. A. Gossage, J. Organomet. Chem., 2017, 845, 107-114.

  • Mononuclear ruthenium and osmium complexes with a bicyclic guanidinate ligand: Synthesis and catalytic behavior in olefin isomerization processes. S. A. Gámez-Rivera, J. Francos, J. Borge, V. Cadierno, Eur. J. Inorg. Chem., 2017, 4138-4146.

  • Metal-catalyzed intra- and intermolecular addition of carboxylic acids to alkynes in aqueous media: A review. J. Francos, V. Cadierno, Catalysts, 2017, 7, 328/1-328/23.

 

Año 2016

  • Highly stereoselective synthesis and hydrogenation of (Z)-1-alkyl-2-arylvinyl acetates: A wide scope procedure for the preparation of chiral homobenzylic esters. P. J. González-Liste, F. León, I. Arribas, M. Rubio, S. E. García-Garrido, V. Cadierno, A. Pizzano, ACS Catal., 2016, 6, 3056-3060. Available in Open-Access (Click here).

  • Exploiting deep eutectic solvents and organolithium reagent partnerships: Chemoselective Ultrafast addition to imines and quinolines under aerobic ambient temperature conditions. C. Vidal, J. García-Álvarez, A. Hernán-Gómez, A. R. Kennedy, E. Hevia, Angew. Chem. Int. Ed., 2016, 55, 16145-16148.

  • From a sequential to a concurrent reaction in aqueous medium: Ruthenium-catalyzed allylic alcohol isomerization and asymmetric bioreduction. N. Ríos-Lombardía, C. Vidal, E. Liardo, F. Morís, J. García-Álvarez, J. González-Sabín, Angew. Chem. Int. Ed., 2016, 55, 8691-8695.

  • Ruthenium-catalyzed synthesis of b-hydroxyamides from b-ketonitriles in water. R. González-Fernández, P. Crochet, V. Cadierno, Org. Lett., 2016, 18, 6164-6167. Available in Open-Access (Click here).

  • Chlorophosphines as auxiliary ligands in ruthenium-catalyzed nitrile hydration reactions: Application to the preparation of β-ketoamides. R. González-Fernández, P. J. González-Liste, J. Borge, P. Crochet, V. Cadierno, Catal. Sci. Technol., 2016, 6, 4398-4409.

  • Half-sandwich guanidinate-osmium(II) complexes: Synthesis and application in the selective dehydration of aldoximes. J. Francos, P. J. González-Liste, L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, J. Borge, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla, Eur. J. Inorg. Chem., 2016, 393-402.

  • Butadiene dyes based on 3-(dicyanomethylidene)indan-1-one and 1,3-bis(dicyanomethylidene)indane: Synthesis, characterization and solvatochromic behavior. J. Francos, S. E. García-Garrido, J. Borge, F. J. Suárez, V. Cadierno, RSC Adv., 2016, 6, 6858-6867.

  • Synthesis and catalytic applications of ruthenium(II)-phosphino-oxime complexes. J. Francos, L. Menéndez-Rodríguez, E. Tómas-Mendivil, P. Crochet, V. Cadierno, RSC Adv., 2016, 6, 39044-39052.

  • Bis(allyl)-ruthenium(IV) complexes with phosphinous acid ligands as catalysts for nitrile hydration reactions. E. Tomás-Mendivil, J. Francos, R. González-Fernández, P. J. González-Liste, J. Borge, V. Cadierno, Dalton Trans., 2016, 45, 13590-13603.

  • Editorial: Organic reactions in green solvents. J. Sperry, J. García-Álvarez, Molecules, 2016, 21,1527-1529.

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Año 2015

  • Unmasking the action of phosphinous acid ligands in nitrile hydration reactions catalyzed by arene-ruthenium(II) complexes. E. Tomás-Mendivil, V. Cadierno, M. I. Menéndez, R. López, Chem. Eur. J., 2015, 21, 16874-16886.

  • Reactivity of the dimer [{RuCl(μ-Cl)(η3:η3-C10H16)}2] (C10H16 = 2,2-dimethylocta-2,6-dine-1,8-diyl) towards guanidines: Access to ruthenium(IV) and ruthenium(II) guanidinate complexes. L. Menéndez-Rodríguez, E. Tomás-Mendivil, J. Francos, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla, Organometallics, 2015, 34, 2796-2809.

  • Deep Eutectic Solvents: biorenewable reaction media for Au(I)-catalysed cycloisomerisations and one-pot tandem cycloisomerisation/Diels-Alder reactions. C. Vidal, L. Merz, J. García-Álvarez, Green Chem., 2015, 17, 3870-3878.

  • Easy entry to donor/acceptor butadiene dyes through a MW-assisted InCl3-catalyzed coupling of propargylic alcohols with indan-1,3-dione in water. J. Francos, J. Borge, J. Díez, S. E. García-Garrido, V. Cadierno, Catal. Commun., 2015, 63, 10-14.

  • Palladium(II) complexes with a phosphino-oxime ligand: Synthesis, structure and applications to catalytic rearrangement and dehydration of aldoximes. L. Menéndez-Rodríguez, E. Tomás-Mendivil, J. Francos, C. Nájera, P. Crochet, V. Cadierno, Catal. Sci. Technol., 2015, 5, 3754-3761.

  • Chemoenzymatic one-pot synthesis in aqueous medium: Combination of metal-catalysed allylic alcohol isomerization-asymmetric bioamination. N. Ríos-Lombardía, C. Vidal, M. Cocina, F. Morís, J. García-Álvarez, J. González-Sabín, Chem. Commun., 2015, 51, 10937-10940.

  • C-H versus OH bond activation in phosphino-alcohol ligands: Synthesis of the α-hydroxy-alkyl derivatives [Ru{κ2(P,C)-Ph2PC6H4C(R)OH}(η6-arene)]. A. E. Díaz-Álvarez, C. Vidal, F. J. Suárez, J. Díez, V. Cadierno, P. Crochet, Organometallics, 2015, 34, 3670-3677. Available in Open-Access (Click here).

  • Catalytic rearrangement of aldoximes to primary amides in environmentally friendly media under thermal and microwave heating: Another application of the bis(allyl)-ruthenium(IV) dimer [{RuCl(μ-Cl)(η3:η3-C10H16)}2]. P. J. González-Liste, V. Cadierno, S. E. García-Garrido, ACS Sustainable Chem. Eng., 2015, 3, 3004-3011. Available in Open-Access (Click here).

  • Reviewing some crucial concepts of Gibbs energy in chemical equilibrium using a computer-assisted, guided-problem-solving approach. J. Borge, J. Chem. Educ., 2015, 92, 296-304.

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Año 2014

  • Exploring Rhodium(I) complexes [RhCl(COD)(PR3)] (COD = 1,5-cyclooctadiene) as catalysts for nitrile hydration reactions in water: The aminophosphines make the difference. E. Tomás-Mendivil, R. García-Álvarez, C. Vidal, P. Crochet, V. Cadierno, ACS Catal., 2014, 4, 1901-1910.

  • Asymmetric hydrogenation of 1-alkyl and 1-aryl vinyl benzoates: A broad scope procedure for the highly enantioselective synthesis of 1-substituted ethyl benzoates. P. Kleman, P. J. González-Liste, S. E. García-Garrido, V. Cadierno, A. Pizzano, ACS Catal., 2014, 4, 4398-4408

  • An efficient ruthenium(IV) catalyst for the selective hydration of nitriles to amides in water under mild conditions. E. Tomás-Mendivil, F. J. Suárez, J. Díez, V. Cadierno, Chem. Commun., 2014, 50, 9661-9664.

  • Introducing deep eutectic solvents to polar organometallic chemistry: Chemoselective addition of organolithium and Grignard reagents to ketones in air. C. Vidal, J. García-Álvarez, A. Hernán-Gómez, A. R. Kennedy, E. Hevia, Angew. Chem. Int. Ed., 2014, 53, 5969-5973. Angew. Chem., 2014, 126, 6079-6083.

  • Glycerol: A biorenewable solvent for base-free Cu(I)-catalyzed 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes. Highly efficient transformations and catalyst recycling. C. Vidal, J. García-Álvarez, Green Chem., 2014, 16, 3515-3521.

  • A stable, mononuclear, cationic Pt(III) complex stabilised by bulky N-heterocyclic carbenes. O. Rivada-Wheelaghan, M. A. Ortuño, S. E. García-Garrido, J. Díez, P. J. Alonso, A. Lledós, S. Conejero, Chem. Commun., 2014, 50, 1299-1301.

  • Deep Eutectic Solvents (DES) as green reaction media for the redox isomerization of allylic alcohols into carbonyl compounds catalyzed by the ruthenium complex [Ru(η3:η3-C10H16)Cl2(benzimidazole)]. C. Vidal, F. J. Súarez, J. García-Álvarez, Catal. Commun., 2014, 44, 76-79.

  • Redox isomerization of allylic alcohols to carbonyl compounds catalyzed by ruthenium(IV) complexes containing N-heterocyclic ligands in ionic liquids. F. J. Suárez, C. Vidal, J. García-Álvarez, Curr. Green Chem., 2014, 1, 121-127.

  • A catalytic system for estragole to anethole isomerization based on [{RuCl(μ-Cl)(η6-p-cymene)}2]. L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, Curr. Green Chem., 2014, 1, 128-135.

  • Introducing deep eutectic solvents as biorenewable media for Au(I)-catalysed cycloisomerisation of γ-alkynoic acids: an unprecedented catalytic system. M. J. Rodríguez-Álvarez, C. Vidal, J. Díez, J. García-Álvarez, Chem. Commun., 2014, 50, 12927-12929.

  • Tethered η5-oxocyclohexadienyl piano stool Ru(II) complexes: A new class of catalysts? M. Kechaou-Perrot, L. Vendier, S. Bastin, J.-M. Sotiropoulos, K. Miqueu, L. Menéndez-Rodríguez, L.; P. Crochet, V. Cadierno, A. Igau, Organometallics, 2014, 33, 6294-6297.

  • Investigation of Binap-based hydroxyphosphine arene-ruthenium(II) complexes as catalysts for nitrile. E. Tomás-Mendivil, L. Menéndez-Rodríguez, J. Francos, P. Crochet, V. Cadierno, RSC Adv., 2014, 4, 63466-63474.

  • Ion association versus ion interaction models in examining electrolyte solutions. M. I. Menéndez Rodríguez, J. Borge, J. Chem. Educ., 2014, 91, 91-95.

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Año 2013

  • Highly enantioselective hydrogenation of 1-alkylvinyl benzoates: a simple, nonenzymetic access to chiral 2-alkanols. P. Kleman, P. J. González-Liste, S. E. García-Garrido, V. Cadierno, A. Pizzano, Chem. Eur. J., 2013, 19, 16209-16212.

  • Thiazolyl-phosphine hydrochloride salts: effective auxiliary ligands for ruthenium-catalyzed nitrile hydration reactions and related amide bond forming processes in water. R. García-Álvarez, M. Zablocka, P. Crochet, C. Duhayon, J.-P. Majoral, V. Cadierno, Green Chem., 2013, 15, 2447-2456.

  • Catalytic isomerization of allylic alcohols promoted by complexes [RuCl2(η6-arene)(PTA-Me)] under homogeneous conditions and supported on Montmorillonite K-10. L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, J. Mol. Catal. A: Chem., 2013, 366, 390-399.

  • Facile transmetalation of a pyridyl-phosphine ligand from ruthenium to gold and silver. E. Tomás-Mendivil, R. García-Álvarez, S. E. García-Garrido, J. Díez, P. Crochet, V. Cadierno, J. Organomet. Chem., 2013, 727, 1-9.

  • Functionalized arene-ruthenium(II) complexes: dangling vs. tethering side chain. B. Lastra-Barreira, J. Díez, P. Crochet, I. Fernández, Dalton Trans., 2013, 42, 5412-5420.

  • Ruthenium-catalyzed one-pot synthesis of primary amides from aldehydes in water. R. García-Álvarez, A. E. Díaz-Álvarez, P. Crochet, V. Cadierno, RSC Adv., 2013, 3, 5889-5894.

  • Series of 2D heterometallic coordination polymers based on ruthenium(III) oxalate building units: synthesis, structure, and catalytic and magnetic properties. A. Dikhtiarenko, S. A. Khainakov, I. de Pedro, J. A. Blanco, J. R. García, J. Gimeno, Inorg. Chem., 2013, 52, 3933-3941.

  • Synthesis and reactivity of new rhenium(I) complexes containing iminophosphorane-phosphine ligands: application to the catalytic isomerization of propargylic alcohols in ionic liquids. J. García-Álvarez, J. Díez, J. Gimeno, C. M. Seifried, C. Vidal, Inorg. Chem., 2013, 52, 5428-5437.

  • Palladium(II) complexes with symmetrical dihydroxy-2,2'-bipyridine ligands: Exploring their inter- and intramolecular interactions in solid-state. E. Tomás-Mendivil, J. Díez, V. Cadierno, Polyhedron, 2013, 59, 69-75.

  • New Ag(I)-iminophosphorane coordination polymers as efficient catalysts precursors for the MW-assisted Meyer-Schuster rearrangement of propargylic alcohols in water. J. García-Álvarez, J. Díez, C. Vidal, C. Vicent, Inorg. Chem., 2013, 52, 6533-6542.

  • One-pot direct C-H arylation of arenes in water catalysed by RuCl3nH2O/NaOAc in the presence of Zn. L. A. Adrio, J. Gimeno, C. Vicent, Chem. Commun., 2013, 49, 8320-8322.

  • Eugenol isomerization promoted by arene-ruthenium(II) complexes in aqueous media: influence of the pH on the catalytic activity. B. Lastra-Barreira, A. E. Díaz-Álvarez, L. Menéndez-Rodríguez, P. Crochet, RSC Adv., 2013, 3, 19985-19990.

  • Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn-H exchange reactions and structural authentication of dinuclear Au(I) complex with NHC anion. D. R. Armstrong, S. E. Baillie, V. L. Blair, N. G. Chabloz, J. Díez, J. García-Álvarez, A. R. Kennedy, S. D. Robertson, E. Hevia, Chem. Sci., 2013, 4, 4259-4266.

  • Donor-activated lithiation and sodiation of trifluoromethylbenzene: structural, spectroscopic, and theoretical insights. J. A. Garden, D. R. Armstrong, W. Clegg, J. García-Álvarez, E. Hevia, A. R. Kennedy, R. E. Mulvey, S. D. Robertson, L. Russo, Organometallics, 2013, 32, 5481-5490.

  • Water-soluble gold(I) and gold(III) complexes with sulfonated NHC ligands: synthesis, characterization and application in catalytic cycloisomerization of γ-alkynoic acids into enol-lactones. E. Tomás-Mendivil, P. Y. Toullec, J. Borge, S. Conejero, V. Michelet, V. Cadierno, ACS Catal., 2013, 3, 3086-3098.

  • The Belousov-Zhabotinskii reaction: improving model with the Arrhenius equation. M. Aller Pellitero, C. Álvarez Lamsfus, J. Borge, J. Chem. Educ., 2013, 90, 82-89.

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Año 2012

  • Ruthenium(II) arene complexes with asymmetrical guanidinate ligands: synthesis, characterization and application in the base-free catalytic isomerization of allylic alcohols. R. García-Álvarez, F. J. Suárez, J. Díez, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla, Organometallics, 2012, 31, 8301-8311.

  • Iminophosphorane-copper(I) complexes as highly efficient catalysts for 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: one-pot multi-component reaction from alkynes and in situ generated azides. J. García-Álvarez, J. Díez, J. Gimeno, F. J. Suárez, C. Vincent, Eur. J. Inorg. Chem., 2012, 5854-5863.

  • Selective hydration of nitriles to amides promoted by an Os-NHC catalyst: formation and X-ray characterization of κ2-amidate intermediates. M. L. Buil, V. Cadierno, M. A. Esteruelas, J. Gimeno, J. Herrero, S. Izquierdo, E. Oñate, Organometallics, 2012, 31, 6861-6867.

  • Pd(II)-catalyzed cycloisomerization of γ-alkynoic acids and one-pot tandem cycloisomerization/CuAAC reactions in water. J. García-Álvarez, J. Díez, C. Vidal, Green Chem., 2012, 14, 3190-3196.

  • Characterization of a paramagnetic, mononuclear Pt(III)-alkyl complex intermediate in carbon-halogen bond coupling reactions. O. Rivada-Wheelaghan, M. A. Ortuño, J. Díez, S. E. García-Garrido, C. Maya, A. Lledós, S. Conejero, J. Am. Chem. Soc.,  2012, 134, 15261-15264.

  • Imidazole based ruthenium(IV) complexes as highly efficient bifunctional catalysts for the redox isomerization of allylic alcohols in aqueous medium: water as cooperating ligand. J. Díez, J. Gimeno, A. Lledós, F. J. Suárez, C. Vicent, ACS Catal., 2012, 2, 2087-2099.

  • Ruthenium-catalyzed rearrangement of aldoximes to primary amides in water. R. García-Álvarez, A. E. Díaz-Álvarez, J. Borge, P. Crochet, V. Cadierno, Organometallics, 2012, 31, 6482-6490.

  • Bis(2,2'-bipyridyl-κ2N,N')dichlorido-rhodium(III) perchlorate. A. Dikhtiarenko, L. Torre-Fernández, S. García-Granda, J. R. García, J. Gimeno, Acta Cryst., 2012, E68, m713-m714.

  • Arene-ruthenium(II) and bis(allyl)-ruthenium(IV) complexes containing 2-diphenylphosphanylpyridine ligands: potential catalysts for nitrile hydration reactions? R. García-Álvarez, S. E. García-Garrido, J. Díez, P. Crochet, V. Cadierno, Eur. J. Inorg. Chem., 2012, 4218-4230.

  • Highly efficient redox isomerisation of allylic alcohols catalysed by pyrazole based ruthenium(IV) complexes in water: Mechanisms of bifunctional catalysis in water. L. Bellarosa, J. Díez, J. Gimeno, A. Lledós, F. J. Suárez, G. Ujaque, C. Vincent, Chem. Eur. J., 2012, 18, 7749-7765.

  • Cycloisomerization vs hydration reactions in aqueous media: a gold(III)-NHC catalyst that makes the difference. E. Tomás-Mendivil, P. Y. Toullec, J. Díez, S. Conejero, V. Michelet, V. Cadierno, Org. Lett., 2012, 14, 2520-2523.

  • Synthesis, characterization and reactivity of ruthenium bis-allyl complexes with chiral phosphine-phosphite ligands. M. Vaquero, S. Vargas, A. Suárez, S, E. García-Garrido, E. Álvarez, M. Mancera, A. Pizzano, Organometallics, 2012, 31, 3551-3564.

  • MW-assisted Meyer-Schuster rearrangement of propargylic alcohols catalyzed by the oxovanadate complex [V(O)Cl(OEt)2]. A. Antiñolo, F. Carrillo-Hermosilla, V. Cadierno, J. García-Álvarez, A. Otero, ChemCatChem, 2012, 4, 123-128.

  • Dimerization of terminal arylalkynes in aqueous medium by ruthenium and acid promoted (RAP) catalysis: Acetate assisted (sp)C-(sp2)C bond formation. A. Coniglio, M. Bassetti, S. E. García-Garrido, J. Gimeno, Adv. Synth. Catal., 2012, 354, 148-158.

  • Hydrothermal synthesis and physicochemical properties of ruthenium(0) nanoparticles. A. Dikhtiarenko, S. A. Khainakov, J. R. García, J. Gimeno, I. de Pedro, J. Rodríguez Fernández, J. A. Blanco, J. Alloys Compd., 2012, 536S, S437-S440.

  • A general route for the stereoselective synthesis of (E)-(1-propenyl)phenyl esters by catalytic C=C bond isomerization. A. E. Díaz-Álvarez, P. Crochet, V. Cadierno, Tetrahedron, 2012, 68, 2611-2620.

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Año 2011

  • Ruthenium(IV) catalysts for the selective estragole to trans-anethole isomerization in environmentally friendly media. B. Lastra-Barreira, J. Francos, P. Crochet, V. Cadierno, Green Chem., 2011, 13, 307-313.

  • Ruthenium-catalyzed intermolecular [2+2+2] alkyne cyclotrimerization in aqueous media under microwave-irradiation. V. Cadierno, J. Francos, S. E. García-Garrido, J. Gimeno, Green Chem. Lett. Rev., 2011, 4, 55-61.

  • Chemistry by nano-catalysis: first example of a solid-supported RAPTA complex for organic reactions in aqueous medium. S. E. García-Garrido, J. Francos, V. Cadierno, J. M. Basset, V. Polshettiwar, ChemSusChem, 2011, 4, 104-111.

  • Ruthenium(IV)-catalyzed Markovnikov addition of carboxylic acids to terminal alkynes in aqueous medium. V. Cadierno, J. Francos, J. Gimeno, Organometallics, 2011, 30, 852-862.

  • Redox isomerization of allylic alcohols into carbonyl compounds catalyzed by the ruthenium(IV) complex [Ru(η3:η3-C10H16)Cl(κ2O,O-CH3CO2)] in water and ionic liquids: highly efficient transformations and catalyst recycling. J. García-Álvarez, J. Gimeno, F. J. Suárez, Organometallics, 2011, 30, 2893-2896.

  • Novel rhenium(I) catalysts for the isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds: an unprecedented recyclable catalytic system in ionic liquids. J. García-Álvarez, J. Díez, J. Gimeno, C. M. Seifried, Chem. Commun., 2011, 47, 6470-6472.

  • Synthesis and structure of ruthenium(IV) complexes featuring N-heterocyclic ligands with an N-H group as the hydrogen-bond donor: hydrogen interactions in solution and in the solid state. J. Díez, J. Gimeno, I. Merino, E. Rubio, F. J. Suárez, Inorg. Chem., 2011, 50, 4868-4881.

  • Access to unusual polycyclic spiro enones from 2,2'-bis(allyloxy)-1,1'-binaphthyls using Grubbs' catalysts: an unprecedented one-pot RCM/Claisen sequence. E. Piedra, J. Francos, N. Nebra, F. J. Suárez, J. Díez, V. Cadierno, Chem. Commun., 2011, 47, 7866-7868.

  • Ruthenium(IV)-catalyzed isomerization of the C=C bond of O-allylic substrates: a combined theoretical and experimental study. A. Varela-Álvarez, J. A. Sordo, E. Piedra, N. Nebra, V. Cadierno, J. Gimeno, Chem. Eur. J., 2011, 17, 10583-10599.

  • Ibuprofenamide: a convenient method of synthesis by catalytic hydration of 2-(4-isobutylphenyl)propionitrile in pure aqueous medium. R. García-Álvarez, J. Francos, P. Crochet, V. Cadierno, Tetrahedron Lett., 2011, 52, 4218-4220.

  • Ruthenium-catalyzed reduction of allylic alcohols using glycerol as solvent and hydrogen donor. A. E. Díaz-Álvarez, P. Crochet, V. Cadierno, Catal. Commun., 2011, 13, 91-96.

  • Conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds in aqueous medium using Pd(II) complexes with dihydroxy-2,2'-bipyridine ligands: homogeneous or heterogeneous nano-catalysis? E. Tomás-Mendivil, J. Díez, V. Cadierno, Catal. Sci. Technol., 2011, 1, 1605-1615.

  • Expeditious entry to novel 2-methylene-2,3-dihydrofuro[3,2-c]chromen-2-ones from 6-chloro-4-hydroxychromen-2-one and propargylic alcohols. N. Nebra, A. E. Díaz-Álvarez, J. Díez, V. Cadierno, Molecules, 2011, 16, 6470-6480.

  • Arene-ruthenium(II) complexes containing inexpensive tris(dimethylamino)phosphine: highly efficient catalysts for the selective hydration of nitriles into amides. R. García-Álvarez, J. Díez, P. Crochet, V. Cadierno, Organometallics, 2011, 30, 5442-5451.

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Año 2010

  • Ruthenium-catalyzed synthesis of β-oxo esters in aqueous medium: scope and limitations. V. Cadierno, J. Francos, J. Gimeno, Green Chem., 2010, 12, 135-143.

  • One-pot three-component synthesis of tetrasubstituted N-H pyrroles from secondary propargylic alcohols, 1,3-dicarbonyl compounds and tert-butyl carbamate. V. Cadierno, J. Gimeno, N. Nebra, J. Heterocycl. Chem., 2010, 47, 233-236.

  • Access to the first (iminophosphoranyl)(selenophosphoranyl)methane ligands Ph2P(=Se)CH2P(=NR)Ph2: coordination of their methanide and methandiide anions to ruthenium. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Dalton Trans., 2010, 39, 941-956.

  • Novel push-pull butadienes derived from 1,1-diaryl-2-propyn-1-ols and 1,1,1,5,5,5-hexafluoro-2,4-pentanedione: synthesis, absorption spectral properties and solvatochromic behaviour. J. Borge, V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Dyes Pigm., 2010, 87, 209-217.

  • One-pot synthesis of bicyclic fused cyclopentenone derivatives from 1-ethynylcycloalkanols and aldehydes. V. Cadierno, J. Gimeno, N. Nebra, ChemCatChem, 2010, 2, 519-522.

  • Ruthenium/TFA-catalyzed regioselective C-3-alkylation of indoles with terminal alkynes in water. Efficient and unprecedented access to 3-(1-methyl-alkyl)-1H-indoles. V. Cadierno, J. Francos, J. Gimeno, Chem. Commun., 2010, 46, 4175-4177.

  • Ruthenium-catalyzed estragole isomerization: high trans-selective formation of anethole. B. Lastra-Barreira, P. Crochet, Green Chem., 2010, 12, 1311-1314.

  • Chiral phosphonite, phosphite and phosphoramidite η6-arene-ruthenium(II) complexes: application to kinetic resolution of allylic alcohols. M. A. Fernández-Zúmel, B. Lastra-Barreira, M. Scheele, J. Díez, P. Crochet, J. Gimeno, Dalton Trans., 2010, 39, 7780-7785.

  • Bis(allyl)-ruthenium(IV) complexes containing water-soluble phosphane ligands: synthesis, structure and application as catalysts in the selective hydration of organonitriles into amides. V. Cadierno, J. Díez, J. Francos, J. Gimeno, Chem. Eur. J., 2010, 16, 9808-9817.

  • Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs water. V. Cadierno, J. Francos, Green Chem., 2010, 12, 1552-1555.

  • Arene-ruthenium(II) complexes containing amino-phosphine ligands as catalysts for nitrile hydration reactions. R. García-Álvarez, J. Díez, P. Crochet, V. Cadierno, Organometallics, 2010, 29, 3955-3965.

  • Iridium(I)-catalyzed coupling of (Z)-2-en-4-yn-1-ols with activated alkynes: a new synthetic route of 7-oxanorbornadienes. A. E. Díaz-Álvarez, P. Crochet, V. Cadierno, Adv. Synth. Catal., 2010, 352, 2427-2431.

  • Cationic rhodium(I)-diolefin complexes containing an optically active C2-symmetric bis(sulfoximine) ligand: synthesis and catalytic activity. V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, A. Pizzano, Polyhedron, 2010, 29, 3380-3386.

  • A highly efficient copper(I) catalyst for the 1,3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1,4-disubstituted and 1,4,5-trisubstituted 1,2,3-triazoles. J. García-Álvarez, J. Díez, J. Gimeno, Green Chem., 2010, 12, 2127-2130.

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Año 2009

  • Microwave-assisted InCl3 catalyzed Meyer-Schuster rearrangement of propargylic aryl carbinols in aqueous media: a green approach to α,β-unsaturated carbonyl compounds. V. Cadierno, J. Francos, J. Gimeno, Tetrahedron Lett., 2009, 50, 4773-4776.

  • Highly water-soluble arene-ruthenium(II) complexes: application to catalytic isomerization of allylic alcohols in aqueous medium. B. Lastra-Barreira, J. Díez, P. Crochet, Green Chem., 2009, 11, 1681-1686.

  • Ruthenium-catalyzed redox isomerization/transfer hydrogenation in organic and aqueous media: a one-pot tandem process for the reduction of allylic alcohols. V. Cadierno, P. Crochet, J. Francos, S. E. García-Garrido, J. Gimeno, N. Nebra, Green Chem., 2009, 11, 1992-2000.

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Año 2008

  • (η6-Arene)-ruthenium(II) complexes containing methanide and methandiide anions of Ph2P(=S)CH2P(=NR)Ph2: unprecedent insertion of isocyanide into a ruthenium-carbene bond. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2008, 27, 1809-1822.

  • Developing the Kharasch reaction in aqueous media: dinuclear group 8 and 9 catalyst containing the bridging cage ligand tris(1,2.dimethylhydrazino)-diphosphane. A. E. Díaz-Álvarez, P. Crochet, M. Zablocka, C. Duhayon, V. Cadierno, J.-P. Mayoral, Eur. J. Inorg. Chem., 2008, 786-794.

  • Asymmetric transfer hydrogenation of ketones catalyzed by ruthenium(II) complexes bearing a chiral phosphinoferrocenyloxazoline ligand. C. A. Madrigal, A. García-Fernández, J. Gimeno, E. Lastra, J. Organomet. Chem., 2008, 693, 2535-2540.

  • Selective ruthenium-catalyzed hydration of nitriles to amides in pure aqueous media under neutral conditions. V. Cadierno, J. Francos, J. Gimeno, Chem. Eur. J., 2008, 14, 6601-6605.

  • Ruthenium/TFA catalyzed coupling of activated secondary propargylic alcohols with cyclic 1,3-diones: furan vs pyran ring formation. V. Cadierno, J. Diez, J. Gimeno, N. Nebra, J. Org. Chem., 2008, 73, 5852-5858.

  • Rate studies on the release of terminal alkynes from indenyl-ruthenium(II) vinylidene complexes. Implications on the mechanism of the η1-vinylidene into η2-alkyne isomerization. M. Bassetti, V. Cadierno, J. Gimeno, C. Pasquini, Organometallics, 2008, 27, 5009-5016.

  • Novel ruthenium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligand Ph2PCH2P{=NP(=O)(OEt)2}Ph2: a new coordination mode of its methanide anion. V. Cadierno, J. Diez, J. García-Álvarez, J. Gimeno, J. Rubio-García, Dalton Trans., 2008, 5737-5748.

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Año 2007

  • One-pot three-component catalytic synthesis of fully substituted pyrroles from readily available propargylic alcohols, 1,3-dicarbonyl compounds and primary amines. V. Cadierno, J. Gimeno, N. Nebra, Chem. Eur. J., 2007, 9973-9981.

  • Octahedral ruthenium(II) complexes cis,cis-[RuX2(CNR)(CO)(P^P)] and cis,cis-[RuX2(CO)2(P^P)] (X = Cl, Br; P^P =1,1´-bis(diphenylphosphino)ferrocene, 1,1´-bis(diisopropylphosphino)ferrocene): Synthesis and catalytic applications in transfer hydrogenation of acetophenone and cycloisomerization of (Z)-3-methylpent-2-en-4-yn-1-ol. J. Albers, V. Cadierno, P. Crochet, S. E. García-Garrido, J. Gimeno, J. Organomet. Chem., 2007, 692, 5234-5244.

  • Efficient tandem process for the catalytic deprotection of N-allylamides and lactams in aqueous media: a novel application of the bis(allyl)-ruthenium(IV) catalysts [Ru(η3:η2:η3-C12H18)Cl2] and [{Ru(η3:η3-C12H16)(μ-Cl)Cl}2]. V. Cadierno, J. Gimeno, N. Nebra, Chem. Eur. J., 2007, 13, 6590-6594.

  • Silver(I) complexes of N-thiophosphorylated bis(iminophosphorane) ligands: from monomers to polymers. V. Cadierno, J. Diez, J. García-Álvarez, J. Gimeno, Dalton Trans., 2007, 2760-2769.

  • Ruthenium-catalyzed reduction of allylic alcohols: an efficient isomerization/transfer hydrogenation tandem process. V. Cadierno, J. Francos, J. Gimeno, N. Nebra, Chem. Commun., 2007, 2536-2538.

  • Half-sandwich ruthenium(II) complexes containing a tricyclic β-iminophosphine ligand: catalytic activity in Diels-Alder reactions. A. E. Díaz-Álvarez, P. Crochet, M. Zablocka, V. Cadierno, L. Vendier, J. Gimeno, J.-P. Majoral, Polyhedron, 2007, 26, 933-940.

  • Half-sandwich η5-indenyl- and η6-areneruthenium(II) complexes bearing the chiral ligand (4S)-2[(Sp)-2-(diphenylphosphanyl)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). A. García-Fernández, J. Gimeno, E. Lastra, C. A. Madrigal, C. Graiff, A. Tiripicchio, Eur. J. Inorg. Chem., 2007, 732-741.

  • A novel propargylation/cycloisomerization tandem process catalyzed by a ruthenium(II)/trifluoroacetic acid system: one-pot entry to fully substituted furans from readily available secondary propargylic alcohols and 1,3-dicarbonyl compounds. V. Cadierno, J. Gimeno, N. Nebra, Adv. Synth. Catal., 2007, 349, 382-394.

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Año 2006

  • Synthesis and reactivity studies of palladium(II) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R = Et, Ph): application to the catalytic synthesis of 2,3-dimethylfuran. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, N. Nebra, J. Rubio-García, Dalton Trans., 2006, 5593-5604.

  • Efficient intramolecular [2+2+2] alkyne cyclotrimerization in aqueous medium using a ruthenium(IV) precatalyst. V. Cadierno, S. E. García-Garrido, J. Gimeno, J. Am. Chem. Soc., 2006, 128, 15094-15095.

  • Efficient access to conjugated dienones and diene-diones from propargylic alcohols and enolizable ketones: a tandem isomerization/condensation process catalyzed by the sixteen-electron allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]. V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, N. Nebra, Adv. Synth. Catal., 2006, 348, 2125-2132.

  • Efficient redox isomerization of allylic alcohols under mild conditions catalyzed by arene-ruthenium(II) complexes. P. Crochet, M. A. Fernández-Zúmel, J. Gimeno, M. Scheele, Organometallics, 2006, 25, 4846-4849.

  • From alkenylphosphane aminoallenylidene ruthenium(II) complexes to highly unsaturated ruthenaphosphabicycloheptene complexes. J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, J. Organomet. Chem., 2006, 691, 4092-4099.

  • Imination reactions of free and coordinated 2-diphenylphosphino-1-phenyl-phospholane: access to regioisomeric ruthenium(II) complexes containing novel iminophosphorane-phosphine ligands. A. E. Díaz-Álvarez, P. Crochet, M. Zablocka, V. Cadierno, C. Duhayon, J. Gimeno, J. P. Majoral, New J. Chem., 2006, 30, 1295-1306.

  • Water-soluble group 8 and 9 transition metal complexes containing a trihydrazinophosphaadamantane ligand: catalytic applications in isomerization of allylic alcohols and cycloisomerization of (Z)-enynols in aqueous medium. A. E. Díaz-Álvarez, P. Crochet, M. Zablocka, C. Duhayon, V. Cadierno, J. Gimeno, J. P. Majoral, Adv. Synth. Catal., 2006, 348, 1671-1679.

  • Rhodium(III) complexes containing the ligand 2,6-bis[(4’-(S)-isopropyloxazolin-2’-yl]pyridine ((S,S)-iPr-pybox): efficient catalysts for asymmetric hydrosilylation of acetophenone. D. Cuervo, M. P. Gamasa, J. Gimeno, J. Mol. Catal. A: Chem., 2006, 249, 60-64.

  • Novel carbonyliridium and -rhodium complexes containing 2,6-bis[(4’S)-4’-isopropyloxazolin-2’-yl]pyridine (iPr-pybox) and 2,6-bis[(4’R)-4’-phenyloxazolin-2’-yl]pyridine (Ph-pybox) ligands. D. Cuervo, J. Díez, M. P. Gamasa, J. Gimeno, P. Paredes, Eur. J. Inorg. Chem., 2006, 599-608.

  • Synthesis of new half-sandwich ruthenium(II) complexes bearing alkenyl- and alkynylphosphane ligands. J. Díez, M. P. Gamasa, J. Gimeno, E. Lastra, A. Villar, Eur. J. Inorg. Chem., 2006, 78-87.

  • Catalytic isomerization of allylic alcohols by (η6-p-cymene)-ruthenium(II) complexes in organic and aqueous media: new recyclable and highly efficient catalysts in water containing ammonium-functionalized ligands. P. Crochet, J. Díez, M. A. Fernández-Zúmel, J. Gimeno, Adv. Synth. Catal., 2006, 348, 93-100.

  • Bis(allyl)-ruthenium(IV) complexes as highly efficient catalysts for the redox isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media: scope, limitations, and theoretical analysis of the mechanism. V. Cadierno, S. E. García-Garrido, J. Gimeno, A. Varela-Álvarez, J. A. Sordo, J. Am. Chem. Soc., 2006, 128, 1360-1370.

  • Isomerization of propargylic alcohols into α,β-unsaturated carbonyl compounds catalyzed by the sixteen-electron allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]. V. Cadierno, S. E. García-Garrido, J. Gimeno, Adv. Synth. Catal., 2006, 348, 101-110.

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Año 2005

  • Reaction of isocyanides with iminophosphorane-based carbene ligands: synthesis of unprecedented ketenimine–ruthenium complexes. V. Cadierno, J. García-Álvarez, J. Gimeno, J. Rubio-García, J. Organomet. Chem., 2005, 690, 5856-5862.

  • Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines. V. Cadierno, S. E. García-Garrido, J. Gimeno, N. Nebra, Chem. Commun., 2005, 4086-4088.

  • Efficient one-pot synthesis of α,β-unsaturated carbyne complexes fac-[RuX3{≡CC(H)=CR2}(dppf)] (X = Cl, Br; R = aryl, alkyl; dppf = 1,1'-bis(diphenylphosphino)ferrocene). V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2005, 24, 3111-3117.

  • Iminophosphorane-based nucleophilic ruthenium(II) carbene complexes: unusual C-C coupling and C-H activation promoted by the addition of alkynes to the Ru=C bond. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2005, 24, 2801-2810.

  • One-pot stereoselective synthesis of organorhodium(III) complexes containing the chiral ligand 2,6-bis[4’-(S)-isopropyloxazolin-2’-yl]pyridine (iPr-pybox). D. Cuervo, J. Díez, M. P. Gamasa, J. Gimeno, Organometallics, 2005, 24, 2224-2232.

  • Novel (η6-arene)-ruthenium(II) complexes containing bis(iminophosphorano)methanide and methandiide ligands. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, J. Organomet. Chem., 2005, 690, 2087-2096.

  • Novel iridium complexes containing 2,6-bis(oxazoline)pyridine ligands: synthesis and reactivity of the diolefin iridium(I) complex [Ir(η2-C2H4)2{κ3-N,N,N-(S,S)-iPr-pybox}][PF6] ((S,S)-iPr-pybox = 2,6-bis(4'-(S)-isopropyloxazolin-2'-yl)pyridine). J. Díez, M. P. Gamasa, J. Gimeno, P. Paredes, Organometallics, 2005, 24, 1799-1802.

  • Intramolecular [2+2] cycloaddition of allyl C=C and allenylidene Cα=Cβ bonds: formation and deprotonation of cyclobutylidene rings. J. Díez, M. P. Gamasa, E. Lastra, J. Gimeno, A. Villar, Organometallics, 2005, 24, 1410-1418.

 

  

Año 2004

  • Water-soluble ruthenium(II) catalysts [RuCl2(η6-arene){P(CH2OH)3}] for isomerization of allylic alcohols and alkyne hydration. V. Cadierno, P. Crochet, S. E. García-Garrido, J. Gimeno, Dalton Trans., 2004, 3635-3641.

  • Indenyl ruthenium(II) aminoallenylidenes: a new building-block for the synthesis of highly unsaturated alkynyl and allenylidene complexes. S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, Organometallics, 2004, 23, 6299-6310.

  • Base-assisted cyclometalation and phosphorus-carbon bond cleavage in (arene)ruthenium(II) complexes containing functionalized iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=X)(OR)2}Ph2 (X = O, S; R = Et, Ph). V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Organometallics, 2004, 23, 3425-3436.

  • Five- and six-coordinate ruthenium(II) complexes containing the bidentate phosphine (-)-N,N-bis(diphenylphosphino)-(S)-1-phenylethylamine [(S)-peap]: X-ray crystal structure of the first 16 electron ruthenium complex bearing a four membered ring [RuCl{κ2-P,P-(S)-peap}2][SbF6]·C2H4Cl2. J. Díez, M. P. Gamasa, J. Gimeno, Y. Rodríguez, S. García-Granda, Eur. J. Inorg. Chem., 2004, 2078-2085.

  • Diastereoselective synthesis of the indenylruthenium(II) complexes [Ru(η5-C9H7){κ3(P,C,C)-Ph2P(CH2CR=CH2)}(PPh3)][PF6] (R = H, Me): enantiofacial coordination, hemilabile properties, and diastereoselective nucleophilic additions to κ3(P,C,C)-allylphosphine ligands. P. Álvarez, E. Lastra, J. Gimeno, P. Braña, J. A. Sordo, J. Gómez, L. R. Falvello, M. Bassetti, Organometallics, 2004, 23, 2956-2966.

  • A new class of tethered-arene ruthenium(II) complexes with pendant P and C donor atoms: synthesis of η6:η1:η1 phosphonio-azabutadienyl ruthenabicycles via allenylidene intermediates. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, Chem. Commun., 2004, 1820-1821.

  • Synthesis and catalytic activity of (η6-p-cymene) ruthenium(II) phosphine complexes supported in poly(biphenoxyphosphazene) or poly(binaphthoxyphosphazene) copolymers. G. A. Carriedo, P. Crochet, F. J. García Alonso, J. Gimeno, A. Presa-Soto, Eur. J. Inorg. Chem., 2004, 3668-3674.

  • Unusual intramolecular [2+2] cycloaddition of allyl and vinylidene C=C bonds under mild conditions: a theoretical analysis. P. Braña, J. Gimeno, J. A. Sordo, J. Org. Chem., 2004, 69, 2544-2550.

  • New chiral ruthenium(II) catalysts containing 2,6-bis(4'-(R)-phenyloxazolin-2'-yl)pyridine (Ph-pybox) ligands for highly enantioselective transfer hydrogenation of ketones. D. Cuervo, M. P. Gamasa, J. Gimeno, Chem. Eur. J., 2004, 10, 425-432.

  • Bis(iminophosphorano)methane derivatives as precursors of unusual ruthenium-carbene complexes: a synthetic and DFT study. V. Cadierno, J. Díez, J. García-Álvarez, J. Gimeno, M. J. Calhorda, L. F. Veiros, Organometallics, 2004, 23, 2421-2433.

  • Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV): highly efficient catalyst for the isomerization of allylic alcohols into carbonyl compounds in organic and aqueous media. V. Cadierno, S. E. García-Garrido, J. Gimeno, Chem. Commun., 2004, 232-233.

  • Reaction of the ruthenium(II) indenyl complex [Ru(η5-C9H7){κ3(P,C,C)-PPh2(CH2CH=CH2)}(PPh3)][PF6] with terminal alkynes. Mechanisms of 1-alkyne to η1-vinylidene transformation and kinetic detection of hemilability of the allylphosphine ligand. M. Bassetti, P. Álvarez, J. Gimeno, E. Lastra, Organometallics, 2004, 23, 5127-5134.

  • Efficient transfer hydrogenation of ketones catalyzed by the bis(isocyanide)-ruthenium(II) complexes trans,cis,cis-[RuX2(CNR)2(dppf)] (X = Cl, Br; dppf = 1,1'-bis(diphenylphosphino)ferrocene): isolation of active mono- and dihydride intermediates. V. Cadierno, P, Crochet, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2004, 23, 4836-4845.

  • [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16 e- ruthenium(II) catalyst for propargylic substitution and isomerization of HC≡CCPh2(OH). V. Cadierno, J. Díez, S. E. García-Garrido, J. Gimeno, Chem. Commun., 2004, 2716-2717.

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Año 2003

  • An easy entry to dimers [{RuX(μ-X)(CO)(P^P)}2] (X = Cl; Br; P^P = 1,1'-bis(diphenylphosphino)ferrocene, 1,1'-bis(diisopropylphosphino)ferrocene) from η3-allyl-ruthenium(II) derivatives [RuX(η3-2-C3H4R)(CO)(P^P)] (R = H, Me): efficient catalyst precursors in transfer hydrogenation of ketones. V. Cadierno, P. Crochet, J. Díez, S. E. García-Garrido, J. Gimeno, Organometallics, 2003, 22, 5226-5234.

  • Synthesis, reactivity and catalytic activity in transfer hydrogenation of ketones of ruthenium(II) and ruthenium(IV) complexes containing the novel N-thiophosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=S)(OR)2}Ph2 (R = Et, Ph). V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E. García-Garrido, S. García-Granda, J. Gimeno,  M. A. Rodriguez, Dalton Trans., 2003, 3240-3249.

  • Ruthenium(II) complexes containing 2-diphenylphosphinobenzaldehyde: synthesis and catalytic activity in transfer hydrogenation. P. Crochet, M. A. Fernández-Zumel, C. Beauquis, J. Gimeno, Inorg. Chim. Acta, 2003, 356, 114-120.

  • Indenyl-ruthenium(II) allenylidene complexes containing terpenic substituents as precursors of optically active terminal alkynes: scope and limitation. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, J. Chem. Soc., Dalton Trans., 2003, 3060-3066.

  • Formation of a cyclobutylidene ring: intramolecular [2+2] cycloaddition of allyl and vinylidene C=C bonds under mild conditions. P. Álvarez, E.  Lastra, J. Gimeno, M. Bassetti, L. R. Falvello, J. Am. Chem. Soc., 2003, 125, 2386-2387.

  • Unexpected coupling between an η5-indenyl ligand and alkenylvinylidene fragments: synthesis of unprecedented (η6-indene)ruthenium(II) metallacycles. V. Cadierno, S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S. García-Granda, Chem. Comm., 2003, 840-841.

  • Synthesis of indenyl-ruthenium(II) σ–alkynyl complexes via nucleophilic addition of the (1R)-(+)- and (1S)-(-)-camphor enolates on the allenylidene group of [Ru(=C=C=CPh2)(η5-C9H7)(PPh3)2][PF6]: efficient synthesis of novel optically pure vinylidene derivatives. V. Cadierno, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño, S. García-Granda, J. Organomet. Chem., 2003, 670, 75-83.

  • η5-Indenylruthenium(II) hydride complexes: synthesis and protonation reactions. M. P. Gamasa, J. Gimeno, C. González-Bernardo, B. M. Martín-Vaca, J. Borge, S. García-Granda, Inorg. Chim. Acta, 2003, 347, 181-188.

  • Reactivity of the dimer [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] towards diphosphines and diphosphine-monoxides: synthesis and characterization of novel (2,7-dimethylocta-2,6-diene-1,8-diyl)-ruthenium(IV) complexes. V. Cadierno, S. E. García-Garrido, J. Gimeno, Inorg. Chim. Acta, 2003, 347, 41-48.

  • Novel indenyl half-sandwich osmium(II) complexes. X-ray structure of [Os{=C=C(H)But}(η5-C9H7)(PPh3)2][PF6].OEt2. J. Gimeno, M. González-Cueva, E. Lastra, E. Pérez-Carreño, S. García-Granda, Inorg. Chim. Acta, 2003, 347, 99-106.

  • Ruthenium(II) and ruthenium(IV) complexes containing κ1-P-, κ2-P,O- and κ3-P,N,O-iminophosphorane-phosphine ligands Ph2PCH2P{=NP(=O)(OR)2}Ph2 (R = Et, Ph): synthesis, reactivity, theoretical studies and catalytic activity in transfer hydrogenation of cyclohexanone. V. Cadierno, P. Crochet, J. Díez, J. García-Álvarez, S. E. García-Garrido, J. Gimeno, S. García-Granda, M. A. Rodríguez, Inorg. Chem., 2003, 42, 3293-3307.

  • Novel ruthenium(II) complexes containing imino or aminophosphine ligands for catalytic transfer hydrogenation. P. Crochet, J. Gimeno, J. Borge, S. García-Granda, New J. Chem., 2003, 27, 414-420.

  • VER TAMBIÉN LA SECCIÓN DE CAPITULOS DE LIBRO.

 

 

Año 2002

  • Neutral and cationic (η6-arene)-ruthenium(II) complexes containing the iminophosphorane-phosphine ligand Ph2PCH2P(=N-p-C5F4N)Ph2: influence of the arene ring in catalytic transfer hydrogenation of cyclohexanone. V. Cadierno, P. Crochet, J. García-Álvarez, S. E. García-Garrido, J. Gimeno, J. Organomet. Chem., 2002, 663, 32-39.

  • New ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). X-ray structures of mer,trans-[RuCl2(dppm)(FcPN)] (dppm = bis(diphenylphosphino)methane) and cis-[RuCl2(CO)(py)(FcPN)]. J. Gimeno, E. Lastra, C. Madrigal, C. Graiff, A. Tiripicchio, J. Organomet. Chem., 2002, 663, 204-212.

  • Synthesis and properties of the indenyl ruthenium(II) complex [Ru(E)-η1-C(C≡CPh)=CHPh)(η5-C9H7)(κ2-P,P-dppm)] (dppm = bis(diphenylphoshino)methane. An organometallic intermediate in the catalytic dimerization of phenylacetylene. M. Bassetti, S. Marini, J. Díez, M. P. Gamasa, J. Gimeno, Y. Rodríguez-Álvarez, S. García-Granda, Organometallics, 2002, 21, 4815-4822.

  • Catalytic synthesis of polynorbornene and polynorbornadiene of low polydispersity index by [Ru(η5-C9H7)Cl(COD)] (COD = 1,5-cyclooctadiene). P. Álvarez, J. Gimeno, E. Lastra, Organometallics, 2002, 21, 5678-5680.

  • Rhodium(I) and rhodium(III) complexes containing the chiral ligand 2,6-bis[4'(S)-iPr-oxazolin-2'-yl]pyridine (pybox): an unprecedented monohapto coordination of pybox. D. Cuervo, J. Díez, M. P. Gamasa, S. García-Granda, J. Gimeno, Inorg. Chem., 2002, 41, 4999-5001.

  • Generation of polyunsaturated cumulene chains by unprecedented insertions of the ynamine MeCCNEt2 in ruthenium(II) allenylidene complexes. S. Conejero, J. Díez, M. P. Gamasa, J. Gimeno, S. García-Granda, Angew. Chem. Int. Ed., 2002, 41, 3439-3442.

  • Synthesis and characterization of 2-oxacycloalkylideneruthenium(II) complexes: X-ray crystal structure of the 2-oxacycloheptylidene complex [Ru{=COCH2(CH2)3CH2}(η5-C9H7)(PPh3)2][PF6]·CH2Cl2. M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca, R. Isea, A. Vegas, J. Organomet. Chem., 2002, 651, 22-33.

  • (Alkenylalkylidene)(indenyl)ruthenium(II) complexes: synthesis by protonation of alkenyl derivatives. K. Bieger, J. Díez, M. P. Gamasa, J. Gimeno, M. Pavlista, Y. Rodríguez-Álvarez, S. García-Granda, R. Santiago-García, Eur. J. Inorg. Chem., 2002, 1647-1656.

  • Easy entry to terminal 1,5- and 1,6-enynes from (indenyl)ruthenium(II) allenylidenes and Grignard reagents. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, Organometallics, 2002, 21, 3837-3840.

  • In search of optically active γ-keto acetylenes via regioselective coupling of allenylidene groups and cyclic enolates. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, L. R. Falvello, R. M. Llusar, Organometallics, 2002, 21, 3716-3726.

  • Ruthenium(II) and ruthenium(IV) complexes containing hemilabile heterodifunctional iminophosphorane-phosphine ligands Ph2PCH2P(=NR)Ph2. V. Cadierno, J. Díez, S. E. García-Garrido, S. García-Granda, J. Gimeno, J. Chem. Soc., Dalton Trans., 2002, 1465-1472.

  • Activation of propargylic alcohols derived from hormonal steroids by the indenyl-ruthenium(II) complex [RuCl(η5-C9H7)(PPh3)2]: experimental and theoretical evidence of an allenylidene-vinylvinylidene equilibrium. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, M. A. Rodríguez, Organometallics, 2002, 21, 203-209.

 

 

Año 2001

  • Five and six-coordinate ruthenium(II) complexes containing 2-Ph2PC6H4CH=NtBu and 2-Ph2PC6H4CH2NHtBu as chelate ligands: synthesis, characterization and catalytic activity in transfer hydrogenation of ketones. P. Crochet, J. Gimeno, S. García-Granda, J. Borge, Organometallics, 2001, 20, 4369-4377.

  • Hydration of terminal alkynes to aldehydes in aqueous micellar solutions by ruthenium(II) catalysis: first anti-Markovnikov addition of water to propargylic alcohols. P. Álvarez, M. Bassetti, J. Gimeno, G. Mancini, Tetrahedron Lett., 2001, 42, 8467-8470.

  • Synthesis and electrochemical and theoretical studies of Fischer-type alkenyl-carbyne tungsten complexes [(dppe)(CO)2(RNC)W{CCH=CCH2CH2(CH2)nCH2}][BF4] (R = alkyl, aryl). L. Zhang, M. F. C. Guedes da Silva, M. L. Kuznetsov, M. P. Gamasa, J. Gimeno, J. J. R. Fraústo da Silva, A. J. L. Pombeiro, Organometallics, 2001, 20, 2782-2793.

  • Octahedral ruthenium(II) complexes containing the chiral ligand (4S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-(methylethyl)oxazoline (FcPN). X-ray crystal structures of fac-[RuCl2(PMe3)2(FcPN)] and fac-[RuCl2(dppm)(FcPN)] (dppm = bis(diphenylphosphino)methane). J. Gimeno, E. Lastra, C. Madrigal, C. Graiff, A. Tiripicchio, J. Organomet. Chem., 2001, 637-639, 463-468.

  • Copper(I) complexes containing 1,1'-bis(diphenylphosphino)ferrocene (dppf) as chelate ligand. X-ray crystal structures of [Cu2(μ-Cl)2(κ2-P,P-dppf)2] and [Cu(CNtBu)2(κ2-P,P-dppf)][BF4]. J. Díez, P. Gamasa, J. Gimeno, M. Lanfranchi, A.Tiripicchio, J. Organomet. Chem., 2001, 637-639, 677-682.

  • Synthesis and reactivity of indenyl ruthenium(II) complexes containing the labile ligand 1,5-cyclooctadiene (COD): catalytic activity of  [Ru(η5-C9H7)Cl(COD)]. P. Álvarez, J. Gimeno, E. Lastra, S. García-Granda, J. F. Van der Maelen,  M. Bassetti, Organometallics, 2001, 20, 3762-3771.

  • Reactivity of indenyl-ruthenium(II) vinylidene complexes: selective synthesis of alkenyl-phosphonio derivatives via nucleophilic addition of triphenylphosphine on their η2-alkyne tautomers. Theoretical study of the η1-vinylidene-η2-alkyne tautomerization. V. Cadierno, M. P. Gamasa, J. Gimeno, C. González-Bernardo, E. Pérez-Carreño, S. García-Granda, Organometallics, 2001, 20, 5177-5188.

  • Efficient synthetic routes to terminal γ–keto-alkynes and unsaturated cyclic carbene complexes based on regio- and diastereoselective nucleophilic additions of enolates on ruthenium(II) indenyl allenylidenes. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, E. Pérez-Carreño, S. García-Granda, Organometallics, 2001, 20, 3175-3189.

  • Reactivity of the bis(allyl)-ruthenium(IV) dimer [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] (C10H16 = 2,7-dimethylocta-2,6-diene-1,8-diyl) towards dppf (dppf = [Fe(η5-C5H4PPh2)2]) and dppfO (dppfO = [Fe(η5-C5H4PPh2)(η5-C5H4P(=O)Ph2)]). V. Cadierno, S. E. García-Garrido, J. Gimeno, J. Organomet. Chem., 2001, 637-639, 767-771.

  • Stereoselective synthesis of chiral terminal (E)-1,3-enynes derived from the aldehydes (1R)-(-)-myrtenal and (S)-(-)-perillaldehyde using the alkynyl-phosphonio complex [Ru{CCCH2(PPh3)}(η5-C9H7)(PPh3)2][PF6] as synthon. V. Cadierno, M. P. Gamasa, J. Gimeno, J. Organomet. Chem., 2001, 621, 39-45.

  • Intramolecular carbon-carbon coupling reactions of a κ2(P,P)-bis(diphenylphosphino)methanide ligand with unsaturated carbene moieties in indenyl-ruthenium(II) complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, B. M. Martín-Vaca, J. Organomet. Chem., 2001, 617-618, 261-268.

  • VER TAMBIÉN LA SECCIÓN DE REVISIONES.

 

 

Año 2000

  • Synthesis, structural characterisation and electrochemical studies of neutral alkenylcarbyne tungsten complexes bearing chelating bidentate and tridentate phosphanes. L. Zhang, M. P. Gamasa, J. Gimeno, M. F. C. Guedes da Silva, A. J. L. Pombeiro, C. Graiff, M. Lanfranchi, A. Tiripicchio, Eur. J. Inorg. Chem., 2000, 1707-1715.

  • Mono and dinuclear tungsten alkenyl-carbyne complexes bridged by cyanide and diisocyanide ligands: synthesis, electrochemical- and 183W-NMR studies. L. Zhang, M. P. Gamasa, J. Gimeno, R. J. Carbajo, F. López-Ortiz, M. F. Guedes da Silva, A. J. L. Pombeiro, Eur. J. Inorg. Chem., 2000, 341-350.

  • Nucleophilic additions of anionic Group 6 carbene complexes on cationic indenyl-ruthenium(II) allenylidene derivatives: an easy entry to bimetallic complexes containing σ–alkynyl-carbene and vinylidene-carbene bridges. V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno, J. Chem. Soc., Dalton Trans., 2000, 451-457.

  • Dimerization of terminal alkynes catalyzed by indenyl ruthenium(II) complexes. M. Bassetti, S. Marini, F. Tortorella, V. Cadierno, J. Díez, M. P. Gamasa, J. Gimeno, J. Organomet. Chem., 2000, 593-594, 292-298.

 

 

 

Revisiones bibliográficas

  • Aplicaciones en catálisis homogénea de derivados bis(alilo) de rutenio(IV). J. Francos, V. Cadierno, An. Quím., 2016, 112, 24-34. Available in Open-Access (Click here).

  • Catalytic synthesis of amides via aldoximes rearrangement. P. Crochet, V. Cadierno, Chem. Commun., 2015, 51, 2495-2505.

  • Reactivity of polar organometallic compounds in unconventional reaction media: challenges and opportunities. J. García-Álvarez, E. Hevia, V. Capriati, Eur. J. Org. Chem., 2015, 6779-6799.

  • Deep eutectic mixtures: Promising sustainable solvents for metal-catalysed and metal-mediated organic reactions. J. García-Álvarez, Eur. J. Inorg. Chem., 2015, 5147-5157.

  • Synthetic applications of the Parkins nitrile hydration catalyst [PtH{(PMe2O)2H}(PMe2OH)]: A review. V. Cadierno, Appl. Sci. 2015, 5, 380-401. Available in Open-Access (Click here).

  • Iminophosphorane-phosphines: versatile ligands for homogeneous catalysis. J. García-Álvarez, S. E. García-Garrido, V. Cadierno, J. Organomet. Chem., 2014, 751, 792-808.

  • Metal-catalyzed nitrile hydration reactions: The specific contribution of ruthenium. R. García-Álvarez, J. Francos, E. Tomás-Mendivil, P. Crochet, V. Cadierno, J. Organomet. Chem., 2014, 771, 93-104.

  • Recent advances in the use of glycerol as green solvent for synthetic organic chemistry. A. E. Díaz-Álvarez, J. Francos, P. Crochet, V. Cadierno, Curr. Green Chem., 2014, 1, 51-65. Available in Open-Access (Click here).

  • Ruthenium-catalyzed amide-bond formation. P. Crochet, V. Cadierno, Top. Organomet. Chem., 2014, 48, 81-118.

  • Arene-ruthenium(II) complexes with hydrophilic P-donor ligands: Versatile catalysts in aqueous media. P. Crochet, V. Cadierno, Dalton Trans., 2014, 43, 12447-12462.

  • Metal-catalyzed amide bond forming reactions in environmentally friendly aqueous medium: Nitrile hydrations and beyond. R. García-Álvarez, P. Crochet, V. Cadierno, Green Chem., 2013, 15, 46-66.

  • Glycerol: A promising green solvent and reducing agent for metal-catalyzed transfer hydrogenation reactions and nanoparticles formation. A. E. Díaz-Álvarez, V. Cadierno, Appl. Sci., 2013, 3, 55-69. Available in Open-Access (Click here).

  • Patented routes for the preparation of morphinan derivatives hydromorphone and hydrocodone via catalytic isomerization. A. E. Díaz-Álvarez, V. Cadierno, Recent Patents Catal., 2012, 1, 43-50.

  • Metal-catalyzed isomerization of allylic and propargylic alcohols in aqueous media. J. García-Álvarez, S. E. García-Garrido, P. Crochet, V. Cadierno, Curr. Top. Catal., 2012, 10, 35-56. Available in Open-Access (Click here).

  • Glycerol and derived solvents: new sustainable reaction media for organic synthesis. A. E. Díaz-Álvarez, J. Francos, B. Lastra-Barreira, P. Crochet, V. Cadierno, Chem. Commun., 2011, 47, 6208-6227.

  • Atom-economic transformations of propargylic alcohols catalyzed by the 16-electron allyl-ruthenium(II) complex [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6] (dppf = 1,1´-bis(diphenylphosphino)ferrocene). V. Cadierno, S. E. García-Garrido, J. Gimeno, N. Nebra, Inorg. Chim. Acta, 2010, 363, 1912-1934.

  • Metal-catalyzed transformations of propargylic alcohols into α,β-unsaturated carbonyl compounds: from the Meyer-Schuster and Rupe rearrangements to redox isomerizations. V. Cadierno, P. Crochet, S. E. García-Garrido, J. Gimeno, Dalton Trans., 2010, 39, 4015-4031.

  • Allenylidene and higher cumulenylidene complexes. V. Cadierno, J. Gimeno, Chem. Rev., 2009, 109, 3512-3560.

  • Ruthenium-catalyzed isomerization of allylic and propargylic alcohols: applications in synthesis. V. Cadierno, P. Crochet, J. Gimeno, Synlett, 2008, 1105-1124.

  • Ruthenium-catalyzed furan- and pyrrole-ring formation. V. Cadierno, P. Crochet, Curr. Org. Synth., 2008, 5, 343-364.

  • Bis(allyl)-ruthenium(IV) complexes: promising precursors for catalytic organic synthesis. V. Cadierno, P. Crochet, S. E. García-Garrido, J. Gimeno, Curr. Org. Chem., 2006, 10, 165-183.

  • Synthesis and reactivity of α,β-unsaturated alkylidene and cumulenylidene group 8 half sandwich complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, Coord. Chem. Rev., 2004, 248, 1627-1657.

  • Recent developments in the reactivity of allenylidene and cumulenylidene complexes. V. Cadierno, M. P. Gamasa, J. Gimeno, Eur. J. Inorg. Chem., 2001, 571-591.

 

 

 

Patentes

   
  • Procedimiento de síntesis enantioselectiva de ésteres quirales, producto obtenido y utilización. A. Pizzano, P. Kleman, V. Cadierno, S. E. García-Garrido, P. J. González-Liste. Número de solicitud: P201330935 (21/6/2013). Patente española.

  • Procedimiento de síntesis enantioselectiva de ésteres quirales, producto obtenido y utilización. A. Pizzano, P. Kleman, V. Cadierno, S. E. García-Garrido, P. J. González-Liste. Registration number: PCT/ES2014/070508 (20/06/2014). Patente internacional.

 

 

 

Capítulos de libro

 

     

 

Phosphorus ylides and related compounds, en Organophosphorous Chemistry: From Molecules to Application.

Autores: M. A. Presa-Soto, J. García-Álvarez

Editorial: John Wiley and Sons (Ed. V. Iaroshenko)

Año: 2018

Páginas: in press

ISBN: 978-3-527-33572-5

 

     

 

Deep eutectic and low-melting mixtures, en Bio-Based Solvents.

Autores: K. de Oliveira, J. García-Álvarez

Editorial: Wiley Series in Renewable Resources (Eds. F. Jérôme, R. Luque)

Año: 2017

Páginas: 83-114

ISBN: 978-1-119-06539-5

 

     

 

Catalytic dimerization of alkynes, en Modern Alkyne Chemistry - Catalytic and Atom-Economic Transformations.

Autor: S. E. García-Garrido

Editorial: Wiley-VCH (Eds. B. M. Trost, C.-J. Li)

Año: 2015

Páginas: 301-363

ISBN: 978-3-527-33505-3

 

      Comentarios sobre este libro en:

• M. M. Haley, Angew. Chem. Int. Ed., 2015, 54, 8332.

 

   

 

 

Deep eutectic solvents: Environmentally-friendly media for metal-catalyzed organic reactions, en Green Technologies for the Environment.

Autor: J. García-Álvarez

Editorial: ACS Symposium Series (Eds. R. Luque, S. O. Obare)

Año: 2015

Páginas: 37-52

ISBN: 978-0-8412-3018-7

     

 

Metal-catalyzed routes for the synthesis of furocoumarins and coumestans, en Green Synthetic Approaches for Biologically Relevant Heterocycles.

Autor: V. Cadierno

Editorial: Elsevier (Ed. G. Brahmachari)

Año: 2015

Páginas: 77-100

ISBN: 978-0-12-800070-0

 

     

 

Ruthenium-catalyzed isomerization of allylic and propargylic alcohols in non-conventional solvents, en Ruthenium: Synthesis, Physicochemical Properties and Applications.

Autores: N. Nebra, J. García-Álvarez

Editorial: Nova Science Publishers (Ed. G. P. Keeler)

Año: 2014

Páginas: 166-206

ISBN: 978-1-63321-657-0

 

 

   

 

 

Deep Eutectic Solvents and their Applications as New Green and Biorenewable Reaction Media, en Handbook of Solvents, Volume 2, Second Edition: Use, Health, and Environment.

Autor: J. García-Álvarez

Editorial: ChemTec Publishing (Ed. G. Wypych)

Año: 2014

Páginas: 813-844

ISBN: 9781895198652

     

 

 

"Click" Copper Catalyzed Azide-alkyne Cycloaddition (CuAAC) in Aqueous Medium, en Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book.

Autores: J. García-Álvarez, J. Gimeno

Editorial: Wiley-VCH (Ed. A. J. L. Pombeiro)

Año: 2014

Páginas: 199-206

ISBN: 978-1-118-51014-8

     

 

 

Nanocatalysts for Rearrangement Reactions, en Nanocatalysis: Synthesis and Applications.

Autores: J. García-Álvarez, S. E. García-Garrido, V. Cadierno

Editorial: Wiley-VCH (Eds. V. Polshettiwar, T. Asefa)

Año: 2013

Páginas: 251-285

ISBN: 978-1-1181-4886-0

 

   

 

Catalytic rearrangements and allylation reactions in water, en Metal-Catalyzed Reactions in Water.

Autores: V. Cadierno, J. García-Álvarez, S. E. García-Garrido

Editorial: Wiley-VCH (Eds. P. H. Dixneuf, V. Cadierno)

Año: 2013

Páginas: 243-289

ISBN: 978352733188

eISBN: 9783527656790

 

Comentarios sobre este libro en: • B. Cornils, Angew. Chem. Int. Ed., 2013, 52, 9079.
     

 

Ruthenium-catalyzed furan- and pyrrole-ring formation, en Advances in Organic Synthesis (Vol. 3).

Autores: V. Cadierno, P. Crochet

Editorial: Bentham (Ed. Atta-ur-Rahman)

Año: 2013

Páginas: 36-80

ISBN: 9780-1-60805-587-6

eISBN: 9780-1-6085-468-8

 

     

 

Ruthenium-catalyzed nitrile hydration reactions using glycerol as solvent, en Glycerol: Production, Structure and Applications.

Autores: A. E. Díaz-Álvarez, R. García-Álvarez, P. Crochet, V. Cadierno

Editorial: Nova Science Publishers (Eds. M. De Santos Silva, P. Costa Ferreira)

Año: 2012

Páginas: 249-262

ISBN: 978-1-62081-120-7

 

 

 

   

 

 

Ruthenium complexes containing iminophosphorane ligands: Synthesis, structure, reactivity and applications, en Ruthenium: Properties, Production and Applications.

Autores: V. Cadierno, J. García-Álvarez

Editorial: Nova Science Publishers (Ed. D. B. Watson)

Año: 2011

Páginas: 189-220

ISBN: 978-1-61761-550-4

     

 

Metal-catalyzed reactions in water under MW irradiation, en Aqueous Microwave Assisted Chemistry: Synthesis and Catalysis.

Autores: V. Cadierno, P. Crochet, S. E. García-Garrido

Editorial: RSC Publishing (Eds. V. Polshettiwar, R. S. Varma)

Año: 2010

Páginas: 10-54

ISBN: 978-1-84973-038-9

Comentarios sobre este libro en:

• C. O. Kappe, ChemSusChem, 2010, 3, 1085.

• E. V. Van der Eycken, Angew. Chem. Int. Ed., 2010, 49, 10039.

• N. E. Leadbeater, J. Am. Chem. Soc., 2011, 133, 2011.

     

 

Heteroatom-conjugated allenylidene and related cumulenylidene ligands, en Transition Metal Complexes of Neutral η1-Carbon Ligands.

Autores: V. Cadierno, S. E. García-Garrido

Editorial: Springer-Verlag (Eds. R. Chauvin, Y. Canac)

Año: 2010

Páginas: 219-252

ISBN: 978-3-642-04721-3

 

 

   

 

 

All carbon-substituted allenylidene and related cumulenylidene ligand, en Transition Metal Complexes of Neutral η1-Carbon Ligands.

Autores: V. Cadierno,  S. E. García-Garrido

Editorial: Springer-Verlag (Eds. R. Chauvin, Y. Canac)

Año: 2010

Páginas: 151-218

ISBN:  978-3-642-04721-3

     

 

 

Alkyne cyclotrimerizations in environmentally benign media: current state of the art, en Green Chemistry Research Trends.

Autores: V. Cadierno, P. Crochet, S. E. García-Garrido

Editorial: Nova Science Publishers (Ed. J. T. Pearlman)

Año: 2009

Páginas: 97-130

ISBN: 978-1-60692-092-3

 
     

 

 

Preparation and stoichiometric reactivity of metal allenylidene complexes, en Metal Vinylidenes and Allenylidenes in Catalysis: From reactivity to Applications in Synthesis.

Autores: V. Cadierno, P. Crochet, J. Gimeno

Editorial: Wiley-VCH (Eds. P. Dixneuf, C. Bruneau)

Año: 2008

Páginas: 61-98

ISBN: 978-3-527-31892-6

 

Comentarios sobre este libro en:

• J. Lynam, Appl. Organometal. Chem., 2010, 24, 346.

• R. Sarpong, J. Am. Chem. Soc., 2008, 130, 14901.

 

   

 

 

Half-sandwich ruthenium complexes containing water-soluble phosphine ligands: catalytic applications, en Advances in Organometallic Chemistry Research.

Autores: V. Cadierno, P. Crochet

Editorial: Nova Science Publishers (Ed. K. Yamamoto)

Año: 2007

Páginas: 37-65

ISBN: 978-1-60021-799-1

 
     

 

Mononuclear Ru/Os compounds with η1 and cyclic C5-C6 ligands, en Comprehensive Organometallic Chemistry III.

Autores: V. Cadierno, J. Gimeno

Editorial: Elsevier (Eds. R. H. Crabtree, D. M. P. Mingos)

Año: 2006

Páginas: 551-628 (Vol. 6)

ISBN: 978-0-0804-4590-8

 

 

     

 

 

Mononuclear Ru/Os compounds with cyclic C5-C6 ligands (except compounds containing monohapto ligands), en Comprehensive Organometallic Chemistry III.

Autores: V. Cadierno, P. Crochet, J. Gimeno

Editorial: Elsevier (Eds. R. H. Crabtree, D. M. P. Mingos)

Año: 2006

Páginas: 465-550 (Vol. 6)

ISBN: 978-0-0804-4590-8

 

 

   

 

 

In search of asymmetric propargylic substitution reactions mediated by optically active indenyl-ruthenium(II) allenylidene complexes, en Perspectives in Organometallic Chemistry.

Autores: V. Cadierno, S. Conejero, M. P. Gamasa, J. Gimeno

Editorial: RSC Editions (Eds. C. G. Screttas, B. R. Steele)

Año: 2003

Páginas: 285-296

ISBN: 0-85404-876-6

 

 

Revisión de libros

 

   
  • Book review: Sustainable Catalysis. Challenges and Practices for the Pharmaceutical and Fine Chemical Industries. Edited by Peter J. Dunn, K. K. (Mimi) Hii, Michael J. Krische and Michael T. Williams (John Wiley & Sons, Hoboken, 2013. ISBN 9878-1118155424). V. Cadierno, Angew. Chem. Int. Ed., 2014, 53, 7398-7399. Angew. Chem., 2014, 126, 7526-7527.

 
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