2017
100. Amido-Pincer Complexes of Cu(II): Synthesis, Coordination Chemistry and Applications in Catalysis
M. Taghvaee, M. J. Rodríguez-Álvarez, J. García-Álvarez, I. del Río, A. J. Lough, R. A. Gossage J. Organomet. Chem. 2017, 845, 107-114
2014
99. Interaction between Anions and Cationic Metal Complexes Containing Tridentate Ligands with exo-C-H Groups: Complex Stability and Hydrogen Bonding
H. Martínez-García, D. Morales, M. Puerto, J. Pérez, I. del Río Chem. Eur. J. 2014, 20, 5821-5834.
2012
98. Interaction between Anions and Molybdenum Allyl Dicarbonyl Complexes of 1,4,7-Trithiacyclononane
D. Morales, M. Puerto, I. del Río, J. Pérez, R. López, Chem. Eur. J. 2012, 18, 16186-16195.
2011
97. Reactivity of cationic triruthenium carbonyl clusters: From pyrimidinium ligands to N-heterocyclic carbenes
J. A. Cabeza, I. del Río, E. Pérez-Carreño, V. Pruneda, Organometallics 2011, 30, 1148-1156.
96. Hydrogen-bonded adducts between neutral molecules and [Mo(h3-methallyl)(CO)2(HOC(py)3)]+: snapshots of a deprotonation
D. Morales, J. Pérez, H. Martínez-García, M. Puerto, I. del Río, Cryst. Eng. Comm. 2011, 13, 60-62.
2010
95. From allenes to edge-bridging allyl ligands or face-capping alkenyl ligands on a triruthenium hydrido carbonyl cluster: An experimental and DFT computational study
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, E. Pérez-Carreño, D. Vázquez-García, Organometallics 2010, 29, 4818-4828.
94. Trapping of pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated pyrid-2-ylidenes in triruthenium clusters
J. A. Cabeza, I. del Río, E. Pérez-Carreño, M. G. Sánchez-Vega, D. Vázquez-García, Organometallics 2010, 29, 4464-4471.
93. Reactivity of [Os3(µ-H)2(CO)10] with N-heterocyclic carbenes: A combined experimental and DFT computational study
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, E. Pérez-Carreño, M. G. Sánchez-Vega, D. Vázquez-García, Organometallics 2010, 29, 3828-3836.
92. Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands
J. A. Cabeza, I. del Río, E. Pérez-Carreño, V. Pruneda, Chem. Eur. J. 2010, 16, 5425-5436.
2009
91. Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands
J. A. Cabeza, I. del Río, M. C. Goite, E. Pérez-Carreño, V. Pruneda, Chem. Eur. J. 2009, 15, 7339-7349.
90. Reactivity of [Ru4(µ-H)4(CO)12] with N-heterocyclic carbenes
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, E. Pérez-Carreño, M. G. Sánchez-Vega, D. Vázquez-García, Organometallics 2009, 28, 1832-1837.
89. Reactivity of protons, tertiary stannanes, and alkynes with a triruthenium dihydrido cluster containing a face-capping NHC ligand
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, M. G. Sánchez-Vega, Organometallics 2009, 28, 1243-1247.
88. The first oxazoline adduct of Zn(acac)2: bis(acetylacetonato-k2-O,O’)(2-phenyl-2-oxazoline-k-N)zinc(II)
I. del Río, R. Gossage, Acta Crystallogr. 2009, E65, m103-m104.
87. A simple preparation of pyridine-derived N-heterocyclic carbenes and their transformation into bridging ligands by orthometalation
J. A. Cabeza, I. del Río, E. Pérez-Carreño, M.G. Sánchez-Vega, D. Vázquez-García, Angew. Chem. Int. Ed. 2009, 48, 555-558.
2008
86. Activation of two C-H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters
J. A. Cabeza, I. del Río, D. Miguel, E. Pérez-Carreño, M.G. Sánchez-Vega, Dalton Trans. 2008, 1937-1942.
85. Reactions of Conjugated Dienes with a Triruthenium Hydrido Carbonyl Cluster: Synthesis and Reactivity of Trinuclear Derivatives Having an Edge-Bridging Allyl Ligand
J. A. Cabeza, I. del Río, M. Gille, M. C. Goite, E. Pérez-Carreño, Organometallics 2008, 27, 609-616.
84. From an N-Methyl N-Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple C-H and C-N Bond Activations
J. A. Cabeza, I. del Río, M. G. Sánchez-Vega, D. Miguel, Angew. Chem. Int. Ed. 2008, 120, 1946-1948.
83. Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects
J. A. Cabeza, I. del Río, M. G. Sánchez-Vega, D. Miguel, E. Pérez-Carreño, Organometallics 2008, 27, 211-217.
82. Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes: Coupling of two diyne molecules via a face-capping diyne intermediate
J. A. Cabeza, I. del Río, L. Martínez-Méndez, D. Miguel, J. Organomet. Chem. 2008, 693, 97-102.
2007
81. Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N’-dipyrid-2-ylurea
J. A. Cabeza, I. del Río, L. Martínez-Méndez, D. Miguel, J. Organomet. Chem. 2007, 692, 4407-4410.
80. Mononuclear ruthenium complexes containing chiral aminooxazolines. Syntheses, X-ray studies and catalytic activity
J. A. Cabeza, I. da Silva, I. del Río, R. Gossage, L. Martínez-Méndez, D. Miguel, J. Organomet. Chem. 2007, 692, 4346-4352.
79. A new coordination mode for (pyrid-2-yl)thiolate (L) ligands. Synthesis and characterization of [Ru6(µ3-H)(µ5-k2-L)(µ-CO)(CO)15]
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, J. Organomet. Chem. 2007, 692, 3583-3587.
78. High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, Organometallics 2007, 26, 3212-3216.
77. Ruthenium Cluster-Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)-H bonds of 1-Octene, 1-Nonene, and 1-Decene
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, Organometallics 2007, 26, 2482-2484.
76. Reactivity of indene, fluorene, azulene, and acenaphthylene with a basal edge-bridged square pyramidal hexaruthenium dihydride
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, P. García-Álvarez, D. Miguel, Organometallics 2007, 26, 1414-1423.
2006
75. Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton. Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, Organometallics 2006, 25, 5672-5675.
74. Reactions of µ3-alkenyl triruthenium cluster complexes with alkynes: Synthesis of trinuclear µ-//-alkyne, µ-vinylidene, and µ-dienoyl derivatives
J. A. Cabeza, I. del Río, L. Martínez-Méndez, E. Pérez-Carreño Chem. Eur. J. 2006, 12, 7694-7705.
73. Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole
J. A. Cabeza, I. da Silva, I. del Río, M. G. Sánchez-Vega, Dalton Trans. 2006, 3966-3971.
72. High-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: Synthesis of nonanuclear derivatives containing µ4- and µ5-oxo ligands
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, Inorg. Chem. 2006, 45, 6020-6027.
71. Triruthenium carbonyl clusters derived from chiral aminooxazolines: Synthesis and catalytic activity
J. A. Cabeza, I. da Silva, I. del Río, R. A. Gossage, M. Suárez, D. Miguel Dalton Trans. 2006, 2450-2455.
70. Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, Organometallics 2006, 25, 2683-2692.
69. Methyl Levamisolium Triflate as a Precursor to a Chiral Bifunctional N Heterocyclic Carbene Thiolate Ligand: Palladium(II) Complexes
J. A. Cabeza, I. del Río, M. G. Sánchez-Vega, M. Suárez, Organometallics 2006, 25, 1831-1834.
68. Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine. Novel coordination modes for 2-imidopyridines
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel Can. J. Chem. 2006, 84, 105-110.
67. Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride Cluster. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, P. García-Álvarez, D. Miguel Organometallics 2006, 25, 1492-1499.
66. Ruthenium-Cluster-Mediated Activation of All Bonds of a Methyl Group of 6,6′-Dimethyl-2,2′-bipyridine and 2,9-Dimethyl-1,10-phenanthroline: Transformation of the Latter into a 2-Alkenyl-9-methyl-1,10-phenanthroline Ligand
J. A. Cabeza, I. del Río, L. Martínez-Méndez, D. Miguel Chem. Eur. J. 2006, 12, 1529-1538.
2005
65. Reactivity of Alkynes Containing a-Hydrogen Atoms with a Triruthenium Hydrido Carbonyl Cluster. Alkenyl versus Allyl Cluster Derivatives
J. A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez, E. Pérez-Carreño Chem. Eur. J. 2005, 11, 6040-6052.
64. Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenyl-imidazo[2,1-b]thiazole]nickel(II)
J. A. Cabeza, I. del Río, M. G. Sánchez-Vega, S. García-Granda Acta Crystallogr., Sect. E 2005, E61, m1984-m1985.
63. Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group
J. A. Cabeza, I. del Río, D. Miguel, M. G. Sánchez-Vega Chem. Commun. 2005, 24, 3956-3958.
62. h2-Edge-Bridging and h3-Face-Capping Coordination of Conjugated Ynenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from 1,1-Dimethylhydrazine
J. A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez, E. Pérez-Carreño Organometallics 2005, 24, 831-835.
61. Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel Organometallics 2005, 24, 665-674.
60. [N,N’-bis-(3-methyl-2-pyridynium)-(1R,2R)-1,2-diaminocyclohexane]-bis-[(p-cymmene)trichlororuthenate(II)]
J. A. Cabeza, I. da Silva, I. del Río, S. García-Granda App. Organomet. Chem. 2005, 19, 209-210.
2004
59. h3-Edge-Bridging versus h3-Face-Capping Coordination of a Conjugated Ynenyl Ligand on a Triruthenium Cluster Core
J. A. Cabeza, I. del Río, S. García-Granda, M. Moreno, E. Pérez-Carreño, V. Riera, M. Suárez Organometallics 2004, 23, 5849-5855.
58. Edge-Bridging and Face-Capping Coordination of Alkenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from Hydrazines: Synthetic, Structural, Theoretical and Kinetic Studies
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, S. García-Granda, L. Martínez-Méndez, E. Pérez-Carreño, V. Riera Chem. Eur. J. 2004, 10, 6265-6278.
57. Hexaruthenium Carbonyl Cluster Complexes with Basal Edge-Bridged Square Pyramidal Metallic Skeleton: Efficient Synthesis of 2-Imidopyridine Derivatives and Determination of their Reactive Sites in Carbonyl Substitution Reactions
J. A. Cabeza, I. del Río, P. García-Álvarez, D. Miguel, V. Riera Inorg. Chem. 2004, 43, 5450-5458.
56. Reactivity of a Triruthenium Cluster Complex Containing a µ3-_3-C,N2 Ligand Derived from 2-Amino-7,8-benzoquinoline. Coupling of This Ligand with C3 Fragments and Characterization of µ3-Vinylidene and µ-Stannylene Derivatives
J. A. Cabeza, I. del Río, V. Riera, M. Suárez, S. García-Granda Organometallics 2004, 23, 3501-3511.
55. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment
J. A. Cabeza, I. da Silva, I. del Río, L. Martínez-Méndez, D. Miguel, V. Riera Angew. Chem. Int. Ed. 2004, 43, 3464-3467.
54. Reactivity of Molybdenum and Rhenium Hydroxo Carbonyl Complexes Toward Organic Electrophiles
L. Cuesta, D. C. Gerbino, E. Hevia, D. Morales, M. E. Navarro-Clemente, J. Pérez, L. Riera, V. Riera, D. Miguel, I. del Río, S. García-Granda Chem. Eur. J. 2004, 10, 1765-1777.
53. Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine
J. A. Cabeza, I. del Río, V. Riera, M. Suárez, S. García-Granda Organometallics 2004, 23, 1107-1115.
2003
52. Oxazoline Chemistry Part IV: Synthesis and Characterisation of Oxazoline Complexes of the Zinc Halides
T. M. Barclay, I. del Río, R. A. Gossage, S. M. Jackson Can. J. Chem. 2003, 81, 1482-1491.
51. Di- and Trinuclear Ruthenium and Osmium Di-(2-pyridyl)ketone Oximate Derivatives
J. A. Cabeza, I. del Río, V. Riera, M. Suárez, C. Álvarez-Rúa, S. García-Granda, S.-H. Chuang, J.-R. Hwu Eur. J. Inorg. Chem. 2003, 4159-4165.
50. Hexaruthenium Cluster Complexes of Basal Edge-Bridged Square Pyramidal Metallic Skeleton. Efficient Synthesis and First Reactivity Studies
J. A. Cabeza, I. del Río, P. García-Álvarez, S. García-Granda, V. Riera, M. Suárez J. Chem. Soc., Dalton Trans. 2003, 2808-2809.
49. Influence of the Bridging Ligand on the Substitution Chemistry of Neutral and Cationic Triruthenium Carbonyl Cluster Complexes Derived from 1,2-Dimethylhydrazine
J. A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez, V. Riera Inorg. Chim. Acta 2003, 350, 93-100.
48. Methylidyne-Diyne Coupling Reactions onto a Triruthenium Cluster Core
J. A. Cabeza, I. da Silva, I. del Río, S. García-Granda, V. Riera Inorg. Chim. Acta 2003, 347, 107-113.
47. Reactivity of Triosmium and Triruthenium Carbonyls with 2,2′-Diamino-1,1′-binaphthalene. Synthesis of C- and N-Metalated Derivatives
J. A. Cabeza, I. da Silva, I. del Río, S. García-Granda, V. Riera, M. G. Sánchez-Vega Organometallics 2003, 22, 1519-1525.
46. Formation of a Highly Functionalized Azulene Ligand by Metal Cluster-Mediated Coupling of Three Conjugated Diynes
J. A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez, M. Moreno, V. Riera, Organometallics 2003, 22, 1164-1166.
2002
45. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Bridging Ligands Derived from 2-Amino-7,8-benzoquinoline
J. A. Cabeza, I. del Río, S. García-Granda, V. Riera, M. Suárez Organometallics 2002, 21, 5055-5059.
44. Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine. Incorporation of two and three phosphane ligands
J. A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez, V. Riera J. Organomet. Chem. 2002, 663, 227-234.
43. Reactivity of a Triruthenium Ynenyl Cluster Complex with Diynes. Cluster-Mediated Combination of up to Three Substituted Butadiyne Molecules into a Carbon-Rich Hydrocarbyl Ligand
J. A. Cabeza, I. del Río, S. García-Granda, M. Moreno, M. Pérez-Priede, V. Riera Eur. J. Inorg. Chem. 2002, 3204-3209.
42. Insertion of Unsaturated Organic Electrophiles into Molybdenum-Alkoxide and Rhenium-Alkoxide Bonds of Neutral, Stable Carbonyl Complexes
E. Hevia, J. Pérez, L. Riera, V. Riera, I. del Río, S. García-Granda, D. Miguel Chem. Eur. J. 2002, 8, 4510-4521.
41. S-C Bond Activation of Levamisole Hydrochloride on a Triruthenium Cluster Core. Characterization of the First Non-mononuclear Derivative of Levamisole
J. A. Cabeza, I. del Río, S. García-Granda, V. Riera, M. G. Sánchez-Vega Eur. J. Inorg. Chem. 2002, 2561-2564.
40. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Deprotonated Di-(2-pyridyl)amine in Unusual Coordination Modes
J. A. Cabeza, I. del Río, S. García-Granda, V. Riera, M. Suárez Organometallics 2002, 21, 2540-2543.
39. Benzophenone Iminium Tetrafluoroborate
J. A. Cabeza, I. del Río, M. Suárez, S. García-Granda, Acta Crystallogr. 2002, E58, o429-o430.
2001
38. [mer,trans-(N,N’N)RuCl2(NC5H5)].C7H8 (NN’N = 2,6-Bis-[(dimethylamino)-methyl]pyridine)
S. Back, G. Rheinwald, I. del Río, G. van Koten, H. Lang Acta Crystallogr. 2001, E57, m444-m445.
37. Formation of Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn-4-en-4-yl Ligands onto a Triruthenium Cluster
J. A. Cabeza, I. del Río, S. García-Granda, M. Moreno, V. Riera Organometallics 2001, 20, 4973-4976.
36. Reactivity of [Ru3(µ3-NPh)(µ3-CO)(CO)9] towards Activated Alkynes and Diynes. Isolation of a Trinuclear Intermediate During the Formation of Bi- and Tetranuclear Products
J. A. Cabeza, I. del Río, S. García-Granda, M. Moreno, V. Riera, M. de J. Rosales-Hoz, M. Suárez Eur. J. Inorg. Chem. 2001, 2899-2906.
35. Reactivity of [Ru2(µ-h1:h2-N=CPh2)(µ-h1:h2-PhC=CHPh)(CO)6] with alkynes. Insertion Reactions of Non-Activated Alkynes Into Ru-C and Ru-N Bonds
J. A. Cabeza, I. del Río, F. Grepioni, M. Moreno, V. Riera, M. Suárez Organometallics 2001, 20, 4190-4197.
34. Formation of Cyclopentadienyl and Ruthenacyclopentadienyl Derivatives through Ynenyl-Diyne and Ynenyl-Alkyne Coupling onto a Tri-ruthenium Cluster Core
J. A. Cabeza, I. del Río, S. García-Granda, G. Lavigne, N. Lugan, M. Moreno, P. Nombel, M. Pérez-Priede, V. Riera, A. Rodríguez, M. Suárez, J. F. van der Maelen Chem. Eur. J. 2001, 7, 2370-2381.
33. (Benzylamine-N)(h5-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate
J. A. Cabeza, I. del Río, M. E. Navarro, S. García-Granda Acta Crystallogr. 2001, E57, m162-m163.
32. (Benzophenone imine-N)nonacarbonyldirhenium(0)(Re-Re)
J. A. Cabeza, I. del Río, N. Zúñiga-Villarreal, S. García-Granda Acta Crystallogr. 2001, E57, m130-m131.
2000
31. Synthesis and characterisation of two novel «pincer» complexes of zinc (II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{(2,6-R2NCH2)2C5H3N}] (R = n-Bu or Me)
I. del Río, R. A. Gossage, M. S. Hannu, M. Lutz, A. L. Spek, G. van Koten Can. J. Chem. 2000, 78, 1620-1626.
30. Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Imido and Orthometalated Imino Derivatives
J. A. Cabeza, I. del Río, F. Grepioni, V. Riera Organometallics 2000, 19, 4643-4646.
29. Bis-ortho-chelated Diaminoaryl Platinum Compounds with s-Acetylene Substituents. Investigations into their Stability and Subsequent Construction of Multimetallic Systems. The Crystal Structure of [(µ2-[(h2-NCN)Pt(h1-CO)CCSiMe3])Co2(CO)6] (NCN = 2,6-Bis-[(dimethylamino)methyl]phenyl)
S. Back, R. A. Gossage, M. Lutz, I. del Río, A. L. Spek, H. Lang, G. van Koten Organometallics 2000, 19, 3296-3304.
28. Reactivity of the Binuclear Ruthenium «Pincer» Complex [{RuCl2(h3-NN’N)}2(µ-N2)] Towards N-Donor Ligands. The X-ray Crystal Structure of [RuCl2(h3-NN’N)(NCPh)] (NN’N = 2,6-bis[(dimethylamino)methyl]pyridine
I. del Río, S. Back, M. S. Hannu, G. Rheinwald, H. Lang, G. van Koten Inorg. Chim. Acta 2000, 300-302, 1094-1098.
27. Haloalkanes C-X Bond Activation by a Ru(II) complex: X-ray Characterization of a Ru(III) Intermediate Species in the Atom Transfer Radical Polymerization of Methyl Methacrylate
I. del Río, G. van Koten, M. Lutz, A. L. Spek Organometallics 2000, 19, 361-364.
1999
26. An Easy Entry to Novel Early-Late Oligonuclear Transition Metal Complexes Containing π-conjugated Systems
S. Back, W. Frosch, I. del Río, G. van Koten, H. Lang Inorg. Chem. Commun. 1999, 2, 584-586.
25. Reactivity of a Binuclear Ru(II) N2-Bridged Complex Towards Phosphines: Facile Access to Novel Mono- and Binuclear Phosphorous Derivatives. X-Ray Structural Characterization of two Unusual Binuclear Complexes Containing «Pincer» Ligands: [{RuCl2(_3-NN’N)}2(µ-_2-P2)] (NN’N = 2,6-bis[(dimethylamino)methyl]pyridine; P2 = 1,3-bis[(diphenylphosphino)methyl]benzene or 1,3-bis(diphenylphosphino)propane)
I. del Río, R. A. Gossage, M. Lutz, A. L. Spek, G. van Koten J. Organomet. Chem. 1999, 583, 69-79.
24. Titanium s-acetylides as building blocks for heterobimetallic transition metal complexes: synthesis and redox behaviour of π-conjugated organometallic systems
S. Back, R. A. Gossage, G. Rheinwald, I. del Río, H. Lang, G. van Koten J. Organomet. Chem. 1999, 582, 126-138.
23. Synthesis and Characterisation of Ruthenium «Pincer» Complexes containing Sulphur Atom Donor Ligands. The X-ray Crystal Structure of [RuCl2(h3-NN’N)(SMe2)] (NN’N = {2,6-(Me2NCH2)2C5H3N})
I. del Río, R. A. Gossage, M. Lutz, A. L. Spek, G. van Koten Inorg. Chim. Acta 1999, 287, 113-116.
22. Alkene and Alkyne Reactivity Towards a bis-Ruthenium(II) µ2-Dinitrogen Complex Containing the «Pincer» Ligand 2,6-bis[(dimethylamino)methyl]pyridine (NN’N). The X-ray Crystal Structures of [Ru(=C=CHPh)Cl2(NN’N)] and [Ru(=C=CHPh)(OTf)(NN’N)(PPh3)][OTf] (OTf = trifluoromethane sulfonate)
I. del Río, R. A. Gossage, M. S. Hannu, M. Lutz, A. L. Spek, G. van Koten Organometallics 1999, 18, 1097-1105.
21. Ring-Opening Metathesis Polymerization of Norbornene Catalyzed by a Ru(II)-Vinylidene Complex
I. del Río, G. van Koten Tetrahedron Lett. 1999, 40, 1401-1404.
1998
20. Reactivity of a 1-Azavinilidene-bridged Triruthenium Carbonyl Cluster with Alkynes. Synthesis of Binuclear Derivatives Containing New C-H or C-N and C-C Bonds Formed by Alkyne Insertion into M-H or M-N and M-C Bonds
J. A. Cabeza, I. del Río, M. Moreno, V. Riera Organometallics 1998, 17, 3027-3033.
19. 16- and 18-Electron Ruthenium(II) Complexes of the Neutral, Potentially Tridentate Triamine Ligand 2,6-[Bis(dimethylamino)methyl]pyridine (NN’N)
R. A. T. M. Abbenhuis, I. del Río, M. M. Bergshoef, J. Boersma, N. Veldman, A. L. Spek, G. van Koten Inorg. Chem. 1998, 37, 1749-1758.
18. Protonation of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand. Experimental Results and EHMO calculations
J. A. Cabeza, I. del Río, V. Riera, D. Ardura J. Organomet. Chem. 1998, 554, 117-121.
17. Reactivity Studies on Cationic Non-hydridic Triruthenium Carbonyl Clusters. Reactions of [Ru3(µ3-ampy)(CO)10][BF4] with Hydrogen, Triethylsilane and Triphenylstannane
J. A. Cabeza, I. del Río, V. Riera Inorg. Chim. Acta 1998, 268, 131-133.
1997
16. Neutral and Cationic Diphenylphosphine and Diphenylphosphido Derivatives of a Trinuclear Ruthenium Carbonyl Cluster Containing a Bridging 1-Azavinylidene Ligand
J. A. Cabeza, I. del Río, V. Riera J. Organomet. Chem. 1997, 548, 255-261.
15. Carbonyl Metal Clusters with Mixed O,N-Donor Ligands: Reactivity of the Ureato Cluster [Ru3(µ-H)(µ3-HNCONMe2)(CO)9] with Phosphines. Structural Characterization of a Triphenylphosphine Derivative and of a Bis(diphenylphosphido) Derivative which Also Contains a Bridging h1-Phenyl Ligand
J. A. Cabeza, I. del Río, V. Riera Organometallics 1997, 16, 3914-3920.
14. Reactivity of a 1-Azavinylidene Ligand with Diphenylacetylene on a Ruthenium Carbonyl Cluster. A Remarkable Alkyne Insertion into a Metal-Nitrogen Bond
J. A. Cabeza, I. del Río, R. J. Franco, F. Grepioni, V. Riera Organometallics 1997, 16, 2763-2764.
13. Reversible Thermal Activation of a Triphenylphosphine P-C Bond on a Cationic Non-hydridic Triruthenium Carbonyl Cluster Complex. Structural Characterization of a µ-h1:h2-Benzoyl Derivative
J. A. Cabeza, I. del Río, V. Riera, S. B. Sanni and S. García Granda Organometallics 1997, 16, 1743-1748.
12. Reactivity of a Cationic Non-hydridic Triruthenium Carbonyl Cluster Complex with Anionic Reagents. Synthesis of New Tri- and Hexanuclear Derivatives
J. A. Cabeza, I. del Río, V. Riera, F. Grepioni Organometallics 1997, 16, 812-815.
1996
11. Synthesis and Reactivity of New Fischer Type Enynylcarbene Tungsten Complexes via 1,4-Diyn-3-ols
C. Cosset, I. del Río, V. Péron, B. Windmüller, H. Le Bozec Synlett 1996, 435-436.
10. Synthesis and Reactivity of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand Derived from Benzophenone Imine
P. L. Andreu, J. A. Cabeza, I. del Río, V. Riera, C. Bois Organometallics 1996, 15, 3004-3010.
9. Neutral and Anionic Pyrazolyl-Bridged Triruthenium Carbonyl Cluster Complexes. Reactions with Bis(diphenylphosphino)methane, Triphenylphosphine and Diphenylphosphine
J. A. Cabeza, I. del Río, V. Riera J. Organomet. Chem. 1996, 523, 127-131.
8. Reactivity of a Cationic Triruthenium Hydrido-Alkenyl Carbonyl Cluster Complex Toward Nucleophilic Reagents. Carbonyl Substitution Versus Alkene Elimination Reactions
J. A. Cabeza, I. del Río, A. Llamazares, V. Riera J. Organomet. Chem. 1996, 511, 103-109.
7. Homogeneous Hydrogenation of Diphenylacetylene Promoted by a Cationic Hydridoalkenyl Triruthenium Cluster Complex. Kinetic Evidence for Cluster-Catalysis
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, V. Riera Organometallics 1996, 15, 449-451.
1995
6. Derivative Chemistry of Cationic Triruthenium Carbonyl Cluster Compounds. Reactions Leading to a Neutral Hexanuclear Complex Consisting of Two Vertex-Linked Metal Triangles
J. A. Cabeza, I. del Río, V. Riera, F. Grepioni Organometallics 1995, 14, 3124-3126.
5. Activation of Prop-2-yn-1-ols by Metal Carbonyls: Synthesis of Alkoxy Alkenylcarbene and Amino Alkenylcarbene Chromium and Tungsten Complexes
C. Cosset, I. del Río, H. Le Bozec Organometallics 1995, 14, 1938-1944.
4. Cationic Trinuclear 48-Electron Ruthenium Carbonyl Cluster Complexes Containing No Hydride Ligands
J. A. Cabeza, I. del Río, A. Llamazares, V. Riera, S. García Granda, J. F. van der Maelen Inorg. Chem. 1995, 34, 1620-1623.
3. Synthesis, Characterization, Reactivity, and Hydrogenation Catalytic Activity of the Hexanuclear Hexahydrido Carbonyl Cluster Compound [Ru6(µ-H)6(µ3,h2-ampy)2(CO)14] (Hampy = 2-amino-6-methylpyridine)
J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, A. Llamazares, V. Riera J. Organomet. Chem. 1995, 494, 169-177.
1994
2. Tricyclohexylphosphine- versus Triphenylphosphine-substituted Derivatives of a Face-bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of their Synthesis, Structure and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylacetylene
S. Alvarez, P. Briard, J. A. Cabeza, I. del Río, J. M. Fernández-Colinas, F. Mulla, L. Ouahab, V. Riera Organometallics 1994, 13, 4360-4366.
1. Crystal Structure of [RuCl2(PH2Cy)(h6-p-cymene)]
J. F. van der Maelen, S. García Granda, J. A. Cabeza, I. del Río Acta Crystallogr., Sect. C 1994, 50, 1064-1065.