{"id":120,"date":"2021-02-20T23:34:27","date_gmt":"2021-02-20T22:34:27","guid":{"rendered":"https:\/\/www.unioviedo.es\/idelrio\/?page_id=120"},"modified":"2025-11-11T09:26:34","modified_gmt":"2025-11-11T08:26:34","slug":"publicaciones","status":"publish","type":"page","link":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/publicaciones\/","title":{"rendered":"Publicaciones"},"content":{"rendered":"\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2025<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">101. One-Pot Morita-Baylis-Hillman\/Allylic Substitution in Deep Eutectic Solvents. Access to \u03b3-Hydroxy Derivatives via Sequential C\u2013C and C\u2013X (X = P, N, S, B, Si) Bond Formation<\/span><\/strong><\/p>\n\n\n\n<p><span class=\"has-inline-color has-black-color\">M. Ramos,<strong> I. del R\u00edo<\/strong>, J. Garc\u00eda-\u00c1lvarez, <\/span>A. <span class=\"has-inline-color has-black-color\">Presa, <strong>Chem. Sus. Chem. 2025<\/strong>, en prensa, doi.org\/10.1002\/cssc.202501674.<\/span><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2017<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">100. Amido-Pincer Complexes of Cu(II): Synthesis, Coordination Chemistry and Applications in Catalysis<\/span><\/strong><\/p>\n\n\n\n<p><span class=\"has-inline-color has-black-color\">M. Taghvaee, M. J. Rodr\u00edguez-\u00c1lvarez, J. Garc\u00eda-\u00c1lvarez,<strong> I. del R\u00edo<\/strong>, A. J. Lough, R. A. Gossage <strong>J. Organomet. Chem. 2017<\/strong>, <strong>845<\/strong>, 107-114<\/span><\/p>\n\n\n\n<p style=\"line-height:1.5\"><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2014<\/span><\/strong><\/p>\n\n\n\n<p><span style=\"color:#00847d\" class=\"has-inline-color\"><strong>99. Interaction between Anions and Cationic Metal Complexes Containing Tridentate Ligands with exo-C-H Groups: Complex Stability and Hydrogen Bonding<\/strong><\/span><\/p>\n\n\n\n<p><span class=\"has-inline-color has-black-color\">H. Mart\u00ednez-Garc\u00eda, D. Morales, M. Puerto, J. P\u00e9rez,&nbsp;<strong>I. del R\u00edo<\/strong>&nbsp;<strong>Chem. Eur. J.<\/strong>&nbsp;<strong>2014<\/strong>,&nbsp;<strong>20<\/strong>, 5821-5834.<\/span><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2012<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">98. Interaction between Anions and Molybdenum Allyl Dicarbonyl Complexes of 1,4,7-Trithiacyclononane<\/span><\/strong><\/p>\n\n\n\n<p>D. Morales, M. Puerto,&nbsp;<strong>I. del R\u00edo<\/strong>, J. P\u00e9rez, R. L\u00f3pez,&nbsp;<strong>Chem. Eur. J.<\/strong>&nbsp;<strong>2012<\/strong>,&nbsp;<strong>18<\/strong>, 16186-16195.<\/p>\n\n\n\n<p><span style=\"color:#00847d\" class=\"has-inline-color\"><strong>2011<\/strong><\/span><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">97. Reactivity of cationic triruthenium carbonyl clusters: From pyrimidinium ligands to N-heterocyclic carbenes<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, E. P\u00e9rez-Carre\u00f1o, V. Pruneda,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2011<\/strong>,&nbsp;<strong>30<\/strong>, 1148-1156.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">96. Hydrogen-bonded adducts between neutral molecules and [Mo(h3-methallyl)(CO)2(HOC(py)3)]+: snapshots of a deprotonation<\/span><\/strong><\/p>\n\n\n\n<p>D. Morales, J. P\u00e9rez, H. Mart\u00ednez-Garc\u00eda, M. Puerto,&nbsp;<strong>I. del R\u00edo<\/strong>,&nbsp;<strong>Cryst. Eng. Comm.<\/strong>&nbsp;<strong>2011<\/strong>,&nbsp;<strong>13<\/strong>, 60-62.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2010<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">95. From allenes to edge-bridging allyl ligands or face-capping alkenyl ligands on a triruthenium hydrido carbonyl cluster: An experimental and DFT computational study<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, E. P\u00e9rez-Carre\u00f1o, D. V\u00e1zquez-Garc\u00eda,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2010<\/strong>,&nbsp;<strong>29<\/strong>, 4818-4828.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">94. Trapping of pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated pyrid-2-ylidenes in triruthenium clusters<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, E. P\u00e9rez-Carre\u00f1o, M. G. S\u00e1nchez-Vega, D. V\u00e1zquez-Garc\u00eda,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2010<\/strong>,&nbsp;<strong>29<\/strong>, 4464-4471.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">93. Reactivity of [Os3(\u00b5-H)2(CO)10] with N-heterocyclic carbenes: A combined experimental and DFT computational study<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, E. P\u00e9rez-Carre\u00f1o, M. G. S\u00e1nchez-Vega, D. V\u00e1zquez-Garc\u00eda,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2010<\/strong>,&nbsp;<strong>29<\/strong>, 3828-3836.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">92. Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, E. P\u00e9rez-Carre\u00f1o, V. Pruneda,&nbsp;<strong>Chem. Eur. J.<\/strong>&nbsp;<strong>2010<\/strong>,&nbsp;<strong>16<\/strong>, 5425-5436.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2009<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">91. Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. C. Goite, E. P\u00e9rez-Carre\u00f1o, V. Pruneda,&nbsp;<strong>Chem. Eur. J.<\/strong>&nbsp;<strong>2009<\/strong>,&nbsp;<strong>15<\/strong>, 7339-7349.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">90. Reactivity of [Ru4(\u00b5-H)4(CO)12] with N-heterocyclic carbenes<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, E. P\u00e9rez-Carre\u00f1o, M. G. S\u00e1nchez-Vega, D. V\u00e1zquez-Garc\u00eda,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2009<\/strong>,&nbsp;<strong>28<\/strong>, 1832-1837.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">89. Reactivity of protons, tertiary stannanes, and alkynes with a triruthenium dihydrido cluster containing a face-capping NHC ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, M. G. S\u00e1nchez-Vega,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2009<\/strong>,&nbsp;<strong>28<\/strong>, 1243-1247.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">88. The first oxazoline adduct of Zn(acac)2: bis(acetylacetonato-k2-O,O&#8217;)(2-phenyl-2-oxazoline-k-N)zinc(II)<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, R. Gossage, <strong>Acta Crystallogr.&nbsp;2009, E65<\/strong>, m103-m104.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">87. A simple preparation of pyridine-derived N-heterocyclic carbenes and their transformation into bridging ligands by orthometalation<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, E. P\u00e9rez-Carre\u00f1o, M.G. S\u00e1nchez-Vega, D. V\u00e1zquez-Garc\u00eda,&nbsp;<strong>Angew. Chem. Int. Ed.<\/strong>&nbsp;<strong>2009<\/strong>,&nbsp;<strong>48<\/strong>, 555-558.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2008<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">86. Activation of two C-H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, D. Miguel, E. P\u00e9rez-Carre\u00f1o, M.G. S\u00e1nchez-Vega,&nbsp;<strong>Dalton Trans<\/strong>.&nbsp;<strong>2008<\/strong>, 1937-1942.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">85. Reactions of Conjugated Dienes with a Triruthenium Hydrido Carbonyl Cluster: Synthesis and Reactivity of Trinuclear Derivatives Having an Edge-Bridging Allyl Ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, M. Gille, M. C. Goite, E. P\u00e9rez-Carre\u00f1o,&nbsp;<strong>Organometallics 2008<\/strong>,&nbsp;<strong>27<\/strong>, 609-616.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">84. From an N-Methyl N-Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple C-H and C-N Bond Activations<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, M. G. S\u00e1nchez-Vega, D. Miguel,&nbsp;<strong>Angew. Chem. Int. Ed. 2008<\/strong>,&nbsp;<strong>120<\/strong>, 1946-1948.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">83. Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, M. G. S\u00e1nchez-Vega, D. Miguel, E. P\u00e9rez-Carre\u00f1o,&nbsp;<strong>Organometallics 2008<\/strong>,&nbsp;<strong>27<\/strong>, 211-217.<\/p>\n\n\n\n<p><span style=\"color:#00847d\" class=\"has-inline-color\"><strong>82. Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes: Coupling of two diyne molecules via a face-capping diyne intermediate<\/strong><\/span><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, L. Mart\u00ednez-M\u00e9ndez, D. Miguel,&nbsp;<strong>J. Organomet. Chem. 2008<\/strong>,&nbsp;<strong>693<\/strong>, 97-102.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2007<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">81. Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N&#8217;-dipyrid-2-ylurea<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, L. Mart\u00ednez-M\u00e9ndez, D. Miguel,&nbsp;<strong>J. Organomet. Chem. 2007<\/strong>,&nbsp;<strong>692<\/strong>, 4407-4410.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">80. Mononuclear ruthenium complexes containing chiral aminooxazolines. Syntheses, X-ray studies and catalytic activity<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, R. Gossage, L. Mart\u00ednez-M\u00e9ndez, D. Miguel,&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>2007<\/strong>,&nbsp;<strong>692<\/strong>, 4346-4352.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">79. A new coordination mode for (pyrid-2-yl)thiolate (L) ligands. Synthesis and characterization of [Ru6(\u00b53-H)(\u00b55-k2-L)(\u00b5-CO)(CO)15]<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>J. Organomet. Chem. 2007<\/strong>,&nbsp;<strong>692<\/strong>, 3583-3587.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">78. High-Nuclearity Osmium Carbonyl Cluster Complexes Containing (6-Methylpyrid-2-yl)imido Ligands. Synthesis of Hepta-, Octa-, and Nonanuclear Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Organometallics 2007<\/strong>,&nbsp;<strong>26<\/strong>, 3212-3216.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">77. Ruthenium Cluster-Mediated Transformation of Linear Alkenes into Trienyl Ligands. Activation of Five C(sp3)-H bonds of 1-Octene, 1-Nonene, and 1-Decene<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Organometallics 2007<\/strong>,&nbsp;<strong>26<\/strong>, 2482-2484.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">76. Reactivity of indene, fluorene, azulene, and acenaphthylene with a basal edge-bridged square pyramidal hexaruthenium dihydride<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Organometallics 2007<\/strong>,&nbsp;<strong>26<\/strong>, 1414-1423.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2006<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">75. Nonanuclear Ruthenium Carbonyl Cluster Complexes with a Novel Metallic Skeleton. Pentagonal Bipyramid with Two Equatorial Edges Spanned by Metal Atoms<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Organometallics 2006<\/strong>,&nbsp;<strong>25<\/strong>, 5672-5675.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">74. Reactions of \u00b53-alkenyl triruthenium cluster complexes with alkynes: Synthesis of trinuclear \u00b5-\/\/-alkyne, \u00b5-vinylidene, and \u00b5-dienoyl derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, L. Mart\u00ednez-M\u00e9ndez, E. P\u00e9rez-Carre\u00f1o&nbsp;<strong>Chem. Eur. J. 2006<\/strong>,&nbsp;<strong>12<\/strong>, 7694-7705.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">73. Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, M. G. S\u00e1nchez-Vega,&nbsp;<strong>Dalton Trans. 2006<\/strong>, 3966-3971.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">72. High-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: Synthesis of nonanuclear derivatives containing \u00b54- and \u00b55-oxo ligands<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Inorg. Chem. 2006<\/strong>,&nbsp;<strong>45<\/strong>, 6020-6027.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">71. Triruthenium carbonyl clusters derived from chiral aminooxazolines: Synthesis and catalytic activity<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, R. A. Gossage, M. Su\u00e1rez, D. Miguel&nbsp;<strong>Dalton Trans. 2006<\/strong>, 2450-2455.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">70. Reactivity of Arenes, Cycloheptatriene, and Dicyclopentadiene with a Basal Edge-Bridged Square Pyramidal Hexaruthenium Dihydride<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel,&nbsp;<strong>Organometallics 2006<\/strong>,&nbsp;<strong>25<\/strong>, 2683-2692.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">69. Methyl Levamisolium Triflate as a Precursor to a Chiral Bifunctional N Heterocyclic Carbene Thiolate Ligand: Palladium(II) Complexes<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. G. S\u00e1nchez-Vega, M. Su\u00e1rez,&nbsp;<strong>Organometallics 2006<\/strong>,&nbsp;<strong>25<\/strong>, 1831-1834.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">68. Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine. Novel coordination modes for 2-imidopyridines<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel&nbsp;<strong>Can. J. Chem. 2006<\/strong>,&nbsp;<strong>84<\/strong>, 105-110.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">67. Reactivity of Diphenylbutadiyne with a Hexaruthenium Dihydride Cluster. Unusual 1,1- and trans-1,2-Additions of Two Hydrogen Atoms to an Internal CC Triple Bond<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, P. Garc\u00eda-\u00c1lvarez, D. Miguel&nbsp;<strong>Organometallics 2006<\/strong>,&nbsp;<strong>25<\/strong>, 1492-1499.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">66. Ruthenium-Cluster-Mediated Activation of All Bonds of a Methyl Group of 6,6&#8242;-Dimethyl-2,2&#8242;-bipyridine and 2,9-Dimethyl-1,10-phenanthroline: Transformation of the Latter into a 2-Alkenyl-9-methyl-1,10-phenanthroline Ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, L. Mart\u00ednez-M\u00e9ndez, D. Miguel&nbsp;<strong>Chem. Eur. J. 2006<\/strong>,&nbsp;<strong>12<\/strong>, 1529-1538.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2005<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">65. Reactivity of Alkynes Containing a-Hydrogen Atoms with a Triruthenium Hydrido Carbonyl Cluster. Alkenyl versus Allyl Cluster Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, E. P\u00e9rez-Carre\u00f1o&nbsp;<strong>Chem. Eur. J. 2005<\/strong>,&nbsp;<strong>11<\/strong>, 6040-6052.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">64. Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenyl-imidazo[2,1-b]thiazole]nickel(II)<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. G. S\u00e1nchez-Vega, S. Garc\u00eda-Granda&nbsp;<strong>Acta Crystallogr., Sect. E<\/strong>&nbsp;<strong>2005<\/strong>,&nbsp;<strong>E61<\/strong>, m1984-m1985.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">63. Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, D. Miguel, M. G. S\u00e1nchez-Vega&nbsp;<strong>Chem. Commun.<\/strong>&nbsp;<strong>2005<\/strong>,&nbsp;<strong>24<\/strong>, 3956-3958.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">62. h2-Edge-Bridging and h3-Face-Capping Coordination of Conjugated Ynenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from 1,1-Dimethylhydrazine<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, E. P\u00e9rez-Carre\u00f1o&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2005<\/strong>,&nbsp;<strong>24<\/strong>, 831-835.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">61. Reactivity of Diphenylacetylene with a Basal Edge-Bridged Square-Pyramidal Hexaruthenium Cluster. Characterization of Penta-, Hexa-, and Heptanuclear Alkyne Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2005<\/strong>,&nbsp;<strong>24<\/strong>, 665-674.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">60. [N,N&#8217;-bis-(3-methyl-2-pyridynium)-(1R,2R)-1,2-diaminocyclohexane]-bis-[(p-cymmene)trichlororuthenate(II)]<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda&nbsp;<strong>App. Organomet. Chem.<\/strong>&nbsp;<strong>2005<\/strong>,&nbsp;<strong>19<\/strong>, 209-210.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2004<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">59. h3-Edge-Bridging versus h3-Face-Capping Coordination of a Conjugated Ynenyl Ligand on a Triruthenium Cluster Core<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, M. Moreno, E. P\u00e9rez-Carre\u00f1o, V. Riera, M. Su\u00e1rez&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2004<\/strong>,&nbsp;<strong>23<\/strong>, 5849-5855.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">58. Edge-Bridging and Face-Capping Coordination of Alkenyl Ligands in Triruthenium Carbonyl Cluster Complexes Derived from Hydrazines: Synthetic, Structural, Theoretical and Kinetic Studies<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, E. P\u00e9rez-Carre\u00f1o, V. Riera&nbsp;<strong>Chem. Eur. J. 2004<\/strong>,&nbsp;<strong>10<\/strong>, 6265-6278.<\/p>\n\n\n\n<p><strong>57. Hexaruthenium Carbonyl Cluster Complexes with Basal Edge-Bridged Square Pyramidal Metallic Skeleton: Efficient Synthesis of 2-Imidopyridine Derivatives and Determination of their Reactive Sites in Carbonyl Substitution Reactions<\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, D. Miguel, V. Riera&nbsp;<strong>Inorg. Chem.<\/strong>&nbsp;<strong>2004<\/strong>,&nbsp;<strong>43<\/strong>, 5450-5458.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">56. Reactivity of a Triruthenium Cluster Complex Containing a \u00b53-_3-C,N2 Ligand Derived from 2-Amino-7,8-benzoquinoline. Coupling of This Ligand with C3 Fragments and Characterization of \u00b53-Vinylidene and \u00b5-Stannylene Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, M. Su\u00e1rez, S. Garc\u00eda-Granda&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2004<\/strong>,&nbsp;<strong>23<\/strong>, 3501-3511.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">55. Activation of All Bonds of a Methyl Group Attached to an Organic Fragment<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, L. Mart\u00ednez-M\u00e9ndez, D. Miguel, V. Riera&nbsp;<strong>Angew. Chem. Int. Ed.<\/strong>&nbsp;<strong>2004<\/strong>,&nbsp;<strong>43<\/strong>, 3464-3467.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">54. Reactivity of Molybdenum and Rhenium Hydroxo Carbonyl Complexes Toward Organic Electrophiles<\/span><\/strong><\/p>\n\n\n\n<p>L. Cuesta, D. C. Gerbino, E. Hevia, D. Morales, M. E. Navarro-Clemente, J. P\u00e9rez, L. Riera, V. Riera, D. Miguel,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda&nbsp;<strong>Chem. Eur. J.<\/strong>&nbsp;<strong>2004<\/strong>,&nbsp;<strong>10<\/strong>, 1765-1777.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">53. Triruthenium, Hexaruthenium, and Triosmium Carbonyl Derivatives of 2-Amino-6-phenylpyridine<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, M. Su\u00e1rez, S. Garc\u00eda-Granda&nbsp;<strong>Organometallics 2004<\/strong>,&nbsp;<strong>23<\/strong>, 1107-1115.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2003<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">52. Oxazoline Chemistry Part IV: Synthesis and Characterisation of Oxazoline Complexes of the Zinc Halides<\/span><\/strong><\/p>\n\n\n\n<p>T. M. Barclay,&nbsp;<strong>I. del R\u00edo<\/strong>, R. A. Gossage, S. M. Jackson&nbsp;<strong>Can. J. Chem. 2003<\/strong>,&nbsp;<strong>81<\/strong>, 1482-1491.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">51. Di- and Trinuclear Ruthenium and Osmium Di-(2-pyridyl)ketone Oximate Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, M. Su\u00e1rez, C. \u00c1lvarez-R\u00faa, S. Garc\u00eda-Granda, S.-H. Chuang, J.-R. Hwu&nbsp;<strong>Eur. J. Inorg. Chem. 2003<\/strong>, 4159-4165.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">50. Hexaruthenium Cluster Complexes of Basal Edge-Bridged Square Pyramidal Metallic Skeleton. Efficient Synthesis and First Reactivity Studies<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, P. Garc\u00eda-\u00c1lvarez, S. Garc\u00eda-Granda, V. Riera, M. Su\u00e1rez&nbsp;<strong>J. Chem. Soc., Dalton Trans. 2003<\/strong>, 2808-2809.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">49. Influence of the Bridging Ligand on the Substitution Chemistry of Neutral and Cationic Triruthenium Carbonyl Cluster Complexes Derived from 1,2-Dimethylhydrazine<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, V. Riera&nbsp;<strong>Inorg. Chim. Acta 2003<\/strong>,&nbsp;<strong>350<\/strong>, 93-100.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">48. Methylidyne-Diyne Coupling Reactions onto a Triruthenium Cluster Core<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, V. Riera&nbsp;<strong>Inorg. Chim. Acta 2003<\/strong>,&nbsp;<strong>347<\/strong>, 107-113.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">47. Reactivity of Triosmium and Triruthenium Carbonyls with 2,2&#8242;-Diamino-1,1&#8242;-binaphthalene. Synthesis of C- and N-Metalated Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza, I. da Silva,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, V. Riera, M. G. S\u00e1nchez-Vega&nbsp;<strong>Organometallics 2003, 22<\/strong>, 1519-1525.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">46. Formation of a Highly Functionalized Azulene Ligand by Metal Cluster-Mediated Coupling of Three Conjugated Diynes<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, M. Moreno, V. Riera,&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2003<\/strong>,&nbsp;<strong>22<\/strong>, 1164-1166.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2002<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">45. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Bridging Ligands Derived from 2-Amino-7,8-benzoquinoline<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,<strong>&nbsp;I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, V. Riera, M. Su\u00e1rez&nbsp;<strong>Organometallics 2002<\/strong>,&nbsp;<strong>21<\/strong>, 5055-5059.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">44. Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine. Incorporation of two and three phosphane ligands<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, L. Mart\u00ednez-M\u00e9ndez, V. Riera&nbsp;<strong>J. Organomet. Chem. 2002<\/strong>,&nbsp;<strong>663<\/strong>, 227-234.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">43. Reactivity of a Triruthenium Ynenyl Cluster Complex with Diynes. Cluster-Mediated Combination of up to Three Substituted Butadiyne Molecules into a Carbon-Rich Hydrocarbyl Ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, M. Moreno, M. P\u00e9rez-Priede, V. Riera&nbsp;<strong>Eur. J. Inorg. Chem. 2002<\/strong>, 3204-3209.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">42. Insertion of Unsaturated Organic Electrophiles into Molybdenum-Alkoxide and Rhenium-Alkoxide Bonds of Neutral, Stable Carbonyl Complexes<\/span><\/strong><\/p>\n\n\n\n<p>E. Hevia, J. P\u00e9rez, L. Riera, V. Riera,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, D. Miguel&nbsp;<strong>Chem. Eur. J. 2002<\/strong>,&nbsp;<strong>8<\/strong>, 4510-4521.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">41. S-C Bond Activation of Levamisole Hydrochloride on a Triruthenium Cluster Core. Characterization of the First Non-mononuclear Derivative of Levamisole<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, V. Riera, M. G. S\u00e1nchez-Vega&nbsp;<strong>Eur. J. Inorg. Chem. 2002<\/strong>, 2561-2564.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">40. Triruthenium and Triosmium Carbonyl Cluster Complexes Containing Deprotonated Di-(2-pyridyl)amine in Unusual Coordination Modes<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, V. Riera, M. Su\u00e1rez&nbsp;<strong>Organometallics 2002<\/strong>,&nbsp;<strong>21<\/strong>, 2540-2543.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">39. Benzophenone Iminium Tetrafluoroborate<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. Su\u00e1rez, S. Garc\u00eda-Granda,&nbsp;<strong>Acta Crystallogr.<\/strong>&nbsp;<strong>2002<\/strong>,&nbsp;<strong>E58<\/strong>, o429-o430.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2001<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">38. [mer,trans-(N,N&#8217;N)RuCl2(NC5H5)].C7H8 (NN&#8217;N = 2,6-Bis-[(dimethylamino)-methyl]pyridine)<\/span><\/strong><\/p>\n\n\n\n<p>S. Back, G. Rheinwald,&nbsp;<strong>I. del R\u00edo<\/strong>, G. van Koten, H. Lang&nbsp;<strong>Acta Crystallogr.<\/strong>&nbsp;<strong>2001<\/strong>,&nbsp;<strong>E57<\/strong>, m444-m445.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">37. Formation of Diynedienyl Ligand by Coupling of Hexa-2,4-diyne and Hex-2-yn-4-en-4-yl Ligands onto a Triruthenium Cluster<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, M. Moreno, V. Riera&nbsp;<strong>Organometallics 2001<\/strong>,&nbsp;<strong>20<\/strong>, 4973-4976.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">36. Reactivity of [Ru3(\u00b53-NPh)(\u00b53-CO)(CO)9] towards Activated Alkynes and Diynes. Isolation of a Trinuclear Intermediate During the Formation of Bi- and Tetranuclear Products<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, M. Moreno, V. Riera, M. de J. Rosales-Hoz, M. Su\u00e1rez&nbsp;<strong>Eur. J. Inorg. Chem. 2001<\/strong>, 2899-2906.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">35. Reactivity of [Ru2(\u00b5-h1:h2-N=CPh2)(\u00b5-h1:h2-PhC=CHPh)(CO)6] with alkynes. Insertion Reactions of Non-Activated Alkynes Into Ru-C and Ru-N Bonds<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, F. Grepioni, M. Moreno, V. Riera, M. Su\u00e1rez&nbsp;<strong>Organometallics 2001<\/strong>,&nbsp;<strong>20<\/strong>, 4190-4197.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">34. Formation of Cyclopentadienyl and Ruthenacyclopentadienyl Derivatives through Ynenyl-Diyne and Ynenyl-Alkyne Coupling onto a Tri-ruthenium Cluster Core<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, S. Garc\u00eda-Granda, G. Lavigne, N. Lugan, M. Moreno, P. Nombel, M. P\u00e9rez-Priede, V. Riera, A. Rodr\u00edguez, M. Su\u00e1rez, J. F. van der Maelen&nbsp;<strong>Chem. Eur. J. 2001<\/strong>,&nbsp;<strong>7<\/strong>, 2370-2381.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">33. (Benzylamine-N)(h5-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. E. Navarro, S. Garc\u00eda-Granda&nbsp;<strong>Acta Crystallogr. 2001<\/strong>,&nbsp;<strong>E57<\/strong>, m162-m163.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">32. (Benzophenone imine-N)nonacarbonyldirhenium(0)(Re-Re)<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, N. Z\u00fa\u00f1iga-Villarreal, S. Garc\u00eda-Granda&nbsp;<strong>Acta Crystallogr. 2001<\/strong>,&nbsp;<strong>E57<\/strong>, m130-m131.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2000<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">31. Synthesis and characterisation of two novel \u00abpincer\u00bb complexes of zinc (II). The X-ray crystal structures of the five coordinate complexes [ZnCl2{(2,6-R2NCH2)2C5H3N}] (R = n-Bu or Me)<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, R. A. Gossage, M. S. Hannu, M. Lutz, A. L. Spek, G. van Koten&nbsp;<strong>Can. J. Chem.<\/strong>&nbsp;<strong>2000<\/strong>,&nbsp;<strong>78<\/strong>, 1620-1626.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">30. Approaches to Triosmium Carbonyl Cluster Compounds Derived from Benzophenone Imine. Characterization of Terminal Imino, Bridging Imido and Orthometalated Imino Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, F. Grepioni, V. Riera&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2000<\/strong>,&nbsp;<strong>19<\/strong>, 4643-4646.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">29. Bis-ortho-chelated Diaminoaryl Platinum Compounds with s-Acetylene Substituents. Investigations into their Stability and Subsequent Construction of Multimetallic Systems. The Crystal Structure of [(\u00b52-[(h2-NCN)Pt(h1-CO)CCSiMe3])Co2(CO)6] (NCN = 2,6-Bis-[(dimethylamino)methyl]phenyl)<\/span><\/strong><\/p>\n\n\n\n<p>S. Back, R. A. Gossage, M. Lutz,&nbsp;<strong>I. del R\u00edo<\/strong>, A. L. Spek, H. Lang, G. van Koten&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2000<\/strong>,&nbsp;<strong>19<\/strong>, 3296-3304.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">28. Reactivity of the Binuclear Ruthenium \u00abPincer\u00bb Complex [{RuCl2(h3-NN&#8217;N)}2(\u00b5-N2)] Towards N-Donor Ligands. The X-ray Crystal Structure of [RuCl2(h3-NN&#8217;N)(NCPh)] (NN&#8217;N = 2,6-bis[(dimethylamino)methyl]pyridine<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, S. Back, M. S. Hannu, G. Rheinwald, H. Lang, G. van Koten&nbsp;<strong>Inorg. Chim. Acta<\/strong>&nbsp;<strong>2000<\/strong>,&nbsp;<strong>300-302<\/strong>, 1094-1098.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">27. Haloalkanes C-X Bond Activation by a Ru(II) complex: X-ray Characterization of a Ru(III) Intermediate Species in the Atom Transfer Radical Polymerization of Methyl Methacrylate<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, G. van Koten, M. Lutz, A. L. Spek&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>2000<\/strong>,&nbsp;<strong>19<\/strong>, 361-364.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1999<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">26. An Easy Entry to Novel Early-Late Oligonuclear Transition Metal Complexes Containing \u03c0-conjugated Systems<\/span><\/strong><\/p>\n\n\n\n<p>S. Back, W. Frosch,<strong>&nbsp;I. del R\u00edo<\/strong>, G. van Koten, H. Lang&nbsp;<strong>Inorg. Chem. Commun.<\/strong>&nbsp;<strong>1999<\/strong>,&nbsp;<strong>2<\/strong>, 584-586.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">25. Reactivity of a Binuclear Ru(II) N2-Bridged Complex Towards Phosphines: Facile Access to Novel Mono- and Binuclear Phosphorous Derivatives. X-Ray Structural Characterization of two Unusual Binuclear Complexes Containing \u00abPincer\u00bb Ligands: [{RuCl2(_3-NN&#8217;N)}2(\u00b5-_2-P2)] (NN&#8217;N = 2,6-bis[(dimethylamino)methyl]pyridine; P2 = 1,3-bis[(diphenylphosphino)methyl]benzene or 1,3-bis(diphenylphosphino)propane)<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, R. A. Gossage, M. Lutz, A. L. Spek, G. van Koten&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>1999<\/strong>,&nbsp;<strong>583<\/strong>, 69-79.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">24. Titanium s-acetylides as building blocks for heterobimetallic transition metal complexes: synthesis and redox behaviour of \u03c0-conjugated organometallic systems<\/span><\/strong><\/p>\n\n\n\n<p>S. Back, R. A. Gossage, G. Rheinwald,&nbsp;<strong>I. del R\u00edo<\/strong>, H. Lang, G. van Koten&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>1999<\/strong>,&nbsp;<strong>582<\/strong>, 126-138.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">23. Synthesis and Characterisation of Ruthenium \u00abPincer\u00bb Complexes containing Sulphur Atom Donor Ligands. The X-ray Crystal Structure of [RuCl2(h3-NN&#8217;N)(SMe2)] (NN&#8217;N = {2,6-(Me2NCH2)2C5H3N})<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, R. A. Gossage, M. Lutz, A. L. Spek, G. van Koten&nbsp;<strong>Inorg. Chim. Acta 1999<\/strong>,&nbsp;<strong>287<\/strong>, 113-116.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">22. Alkene and Alkyne Reactivity Towards a bis-Ruthenium(II) \u00b52-Dinitrogen Complex Containing the \u00abPincer\u00bb Ligand 2,6-bis[(dimethylamino)methyl]pyridine (NN&#8217;N). The X-ray Crystal Structures of [Ru(=C=CHPh)Cl2(NN&#8217;N)] and [Ru(=C=CHPh)(OTf)(NN&#8217;N)(PPh3)][OTf] (OTf = trifluoromethane sulfonate)<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, R. A. Gossage, M. S. Hannu, M. Lutz, A. L. Spek, G. van Koten&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1999<\/strong>,&nbsp;<strong>18<\/strong>, 1097-1105.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">21. Ring-Opening Metathesis Polymerization of Norbornene Catalyzed by a Ru(II)-Vinylidene Complex<\/span><\/strong><\/p>\n\n\n\n<p><strong>I. del R\u00edo<\/strong>, G. van Koten <strong>Tetrahedron Lett.&nbsp;1999, 40<\/strong>, 1401-1404.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1998<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">20. Reactivity of a 1-Azavinilidene-bridged Triruthenium Carbonyl Cluster with Alkynes. Synthesis of Binuclear Derivatives Containing New C-H or C-N and C-C Bonds Formed by Alkyne Insertion into M-H or M-N and M-C Bonds<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, M. Moreno, V. Riera&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1998<\/strong>,&nbsp;<strong>17<\/strong>, 3027-3033.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">19. 16- and 18-Electron Ruthenium(II) Complexes of the Neutral, Potentially Tridentate Triamine Ligand 2,6-[Bis(dimethylamino)methyl]pyridine (NN&#8217;N)<\/span><\/strong><\/p>\n\n\n\n<p>R. A. T. M. Abbenhuis,&nbsp;<strong>I. del R\u00edo<\/strong>, M. M. Bergshoef, J. Boersma, N. Veldman, A. L. Spek, G. van Koten&nbsp;<strong>Inorg. Chem.<\/strong>&nbsp;<strong>1998<\/strong>,&nbsp;<strong>37<\/strong>, 1749-1758.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">18. Protonation of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand. Experimental Results and EHMO calculations<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, D. Ardura&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>1998<\/strong>,&nbsp;<strong>554<\/strong>, 117-121.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">17. Reactivity Studies on Cationic Non-hydridic Triruthenium Carbonyl Clusters. Reactions of [Ru3(\u00b53-ampy)(CO)10][BF4] with Hydrogen, Triethylsilane and Triphenylstannane<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera <strong>Inorg. Chim. Acta&nbsp;1998, 268<\/strong>, 131-133.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1997<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">16. Neutral and Cationic Diphenylphosphine and Diphenylphosphido Derivatives of a Trinuclear Ruthenium Carbonyl Cluster Containing a Bridging 1-Azavinylidene Ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera <strong>J. Organomet. Chem.&nbsp;1997, 548<\/strong>, 255-261.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">15. Carbonyl Metal Clusters with Mixed O,N-Donor Ligands: Reactivity of the Ureato Cluster [Ru3(\u00b5-H)(\u00b53-HNCONMe2)(CO)9] with Phosphines. Structural Characterization of a Triphenylphosphine Derivative and of a Bis(diphenylphosphido) Derivative which Also Contains a Bridging h1-Phenyl Ligand<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera <strong>Organometallics&nbsp;1997, 16<\/strong>, 3914-3920.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">14. Reactivity of a 1-Azavinylidene Ligand with Diphenylacetylene on a Ruthenium Carbonyl Cluster. A Remarkable Alkyne Insertion into a Metal-Nitrogen Bond<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, R. J. Franco, F. Grepioni, V. Riera&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1997<\/strong>,&nbsp;<strong>16<\/strong>, 2763-2764.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">13. Reversible Thermal Activation of a Triphenylphosphine P-C Bond on a Cationic Non-hydridic Triruthenium Carbonyl Cluster Complex. Structural Characterization of a \u00b5-h1:h2-Benzoyl Derivative<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, S. B. Sanni and S. Garc\u00eda Granda&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1997<\/strong>,&nbsp;<strong>16<\/strong>, 1743-1748.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">12. Reactivity of a Cationic Non-hydridic Triruthenium Carbonyl Cluster Complex with Anionic Reagents. Synthesis of New Tri- and Hexanuclear Derivatives<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, F. Grepioni&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1997<\/strong>,&nbsp;<strong>16<\/strong>, 812-815.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1996<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">11. Synthesis and Reactivity of New Fischer Type Enynylcarbene Tungsten Complexes via 1,4-Diyn-3-ols<\/span><\/strong><\/p>\n\n\n\n<p>C. Cosset,&nbsp;<strong>I. del R\u00edo<\/strong>, V. P\u00e9ron, B. Windm\u00fcller, H. Le Bozec&nbsp;<strong>Synlett<\/strong>&nbsp;<strong>1996<\/strong>, 435-436.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">10. Synthesis and Reactivity of Triruthenium Carbonyl Cluster Complexes Containing a Bridging 1-Azavinylidene Ligand Derived from Benzophenone Imine<\/span><\/strong><\/p>\n\n\n\n<p>P. L. Andreu, J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, C. Bois&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1996<\/strong>,&nbsp;<strong>15<\/strong>, 3004-3010.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">9. Neutral and Anionic Pyrazolyl-Bridged Triruthenium Carbonyl Cluster Complexes. Reactions with Bis(diphenylphosphino)methane, Triphenylphosphine and Diphenylphosphine&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera <strong>J. Organomet. Chem.&nbsp;1996, 523<\/strong>, 127-131.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">8. Reactivity of a Cationic Triruthenium Hydrido-Alkenyl Carbonyl Cluster Complex Toward Nucleophilic Reagents. Carbonyl Substitution Versus Alkene Elimination Reactions&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, A. Llamazares, V. Riera&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>1996<\/strong>,&nbsp;<strong>511<\/strong>, 103-109.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">7. Homogeneous Hydrogenation of Diphenylacetylene Promoted by a Cationic Hydridoalkenyl Triruthenium Cluster Complex. Kinetic Evidence for Cluster-Catalysis&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, V. Riera&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1996<\/strong>,&nbsp;<strong>15<\/strong>, 449-451.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1995<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">6. Derivative Chemistry of Cationic Triruthenium Carbonyl Cluster Compounds. Reactions Leading to a Neutral Hexanuclear Complex Consisting of Two Vertex-Linked Metal Triangles<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, V. Riera, F. Grepioni&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1995<\/strong>,&nbsp;<strong>14<\/strong>, 3124-3126.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">5. Activation of Prop-2-yn-1-ols by Metal Carbonyls: Synthesis of Alkoxy Alkenylcarbene and Amino Alkenylcarbene Chromium and Tungsten Complexes&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>C. Cosset,&nbsp;<strong>I. del R\u00edo<\/strong>, H. Le Bozec <strong>Organometallics&nbsp;1995, 14<\/strong>, 1938-1944.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">4. Cationic Trinuclear 48-Electron Ruthenium Carbonyl Cluster Complexes Containing No Hydride Ligands&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, A. Llamazares, V. Riera, S. Garc\u00eda Granda, J. F. van der Maelen&nbsp;<strong>Inorg. Chem.<\/strong>&nbsp;<strong>1995<\/strong>,&nbsp;<strong>34<\/strong>, 1620-1623.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">3. Synthesis, Characterization, Reactivity, and Hydrogenation Catalytic Activity of the Hexanuclear Hexahydrido Carbonyl Cluster Compound [Ru6(\u00b5-H)6(\u00b53,h2-ampy)2(CO)14] (Hampy = 2-amino-6-methylpyridine)<\/span><\/strong><\/p>\n\n\n\n<p>J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, A. Llamazares, V. Riera&nbsp;<strong>J. Organomet. Chem.<\/strong>&nbsp;<strong>1995<\/strong>,&nbsp;<strong>494<\/strong>, 169-177.<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1994<\/span><\/strong><\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">2. Tricyclohexylphosphine- versus Triphenylphosphine-substituted Derivatives of a Face-bridged Triruthenium Carbonyl Cluster Complex. A Comparative Study of their Synthesis, Structure and Catalytic Activity in the Homogeneous Hydrogenation of Diphenylacetylene&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>S. Alvarez, P. Briard, J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>, J. M. Fern\u00e1ndez-Colinas, F. Mulla, L. Ouahab, V. Riera&nbsp;<strong>Organometallics<\/strong>&nbsp;<strong>1994<\/strong>,&nbsp;<strong>13<\/strong>, 4360-4366.&nbsp;<\/p>\n\n\n\n<p><strong><span style=\"color:#00847d\" class=\"has-inline-color\">1. Crystal Structure of [RuCl2(PH2Cy)(h6-p-cymene)]&nbsp;<\/span><\/strong><\/p>\n\n\n\n<p>J. F. van der Maelen, S. Garc\u00eda Granda, J. A. Cabeza,&nbsp;<strong>I. del R\u00edo<\/strong>&nbsp;<strong>Acta Crystallogr., Sect. C<\/strong>&nbsp;<strong>1994<\/strong>,&nbsp;<strong>50<\/strong>, 1064-1065.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>2025 101. One-Pot Morita-Baylis-Hillman\/Allylic Substitution in Deep Eutectic Solvents. Access to \u03b3-Hydroxy Derivatives via Sequential C\u2013C and C\u2013X (X = P, N, S, B, Si) Bond Formation M. Ramos, I. del R\u00edo, J. Garc\u00eda-\u00c1lvarez, A. Presa, Chem. Sus. Chem. 2025, en prensa, doi.org\/10.1002\/cssc.202501674. 2017 100. Amido-Pincer Complexes of Cu(II): Synthesis, Coordination Chemistry and Applications in &hellip; <\/p>\n<p class=\"link-more\"><a href=\"https:\/\/www.unioviedo.es\/idelrio\/index.php\/publicaciones\/\" class=\"more-link\">Continuar leyendo<span class=\"screen-reader-text\"> \u00abPublicaciones\u00bb<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":201,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-120","page","type-page","status-publish","has-post-thumbnail","hentry"],"_links":{"self":[{"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/pages\/120","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/comments?post=120"}],"version-history":[{"count":13,"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/pages\/120\/revisions"}],"predecessor-version":[{"id":347,"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/pages\/120\/revisions\/347"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/media\/201"}],"wp:attachment":[{"href":"https:\/\/www.unioviedo.es\/idelrio\/index.php\/wp-json\/wp\/v2\/media?parent=120"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}