Research Papers in 2013

AUTHORS (in alph. order): I.G. Albuerne, M. A. Alvarez, M. E. García, D. García-Vivó, Miguel A. Ruiz..

TITLE: Novel Dimerization of Maleic Anhydride at a Mo2 Complex: Phase-Driven Keto/Enol Tautomerism in a Phosphinidenium-Ylide Complex.

JOURNAL: Organometallics 2013, 32, 6178-6181

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, R. González, Miguel A. Ruiz..

TITLE: P−C and C−C Coupling Processes in the Reactions of the Phosphinidene-Bridged Complex [Fe2(h5-C5H5)2(μ-PCy)(μ-CO)(CO)2] with Alkynes.

JOURNAL:Organometallics 2013, 32, 4601-4611

AUTHORS (in alph. order): F. Cimadevilla, M. E. García, D. García-Vivó, Miguel A. Ruiz, C. Graiff, A. Tiripicchio.

TITLE: Hydrogen Atom Transfer Reactions of the Unsaturated Hydroxycarbyne Complex [W2Cp2(μ-COH)(μ-PPh2)2][BF4].

JOURNAL: Organometallics 2013, 32, 4624−4635

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, D. García-Vivó, Miguel A. Ruiz, M. F. Vega.

TITLE: Insertion, Rearrangement, and Coupling Processes in the Reactions of the Unsaturated Hydride Complex [W2(h5-C5H5)2(H)(μ-PCy2)(CO)2] with Isocyanides.

JOURNAL: Organometallics 2013, 32, 4543-4555

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, D. García-Vivó, R. Lozano, A. Ramos, Miguel A. Ruiz.

TITLE: Reactivity of the Anionic Diphosphorus Complex [Mo2Cp2(μ-PCy2)(μ-k2:k2-P2)(CO)2]- Toward Phosphorus- and Transition Metal-Based Electrophiles.

JOURNAL: Inorg. Chem. 2013, 52, 9005−9018

AUTHORS (in alph. order): M. A. Alvarez, B. Alvarez, M. E. García, D. García-Vivó, Miguel A. Ruiz.

TITLE: Stepwise Hydrogenation of an Arylthiophosphinidene Isocyanide Complex to Give Tethered Aldimine and Aminocarbene Functions.

JOURNAL: Dalton Trans. 2013, 42, 11039-11042

AUTHORS (in alph. order): D. García-Vivó, E. Huergo, Miguel A. Ruiz, R. Travieso.

TITLE: Thermally Induced Dehydrogenation of Amine-Borane Adducts and Ammonia-Borane by Group 6 Cyclopentadienyl Complexes Having Single and Triple Metal-Metal Bonds.

JOURNAL: Eur. J. Inorg. Chem. 2013,4998-5008

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, Miguel A. Ruiz, A. Toyos, M. F. Vega.

TITLE: Heterometallic Derivatives of the Unsaturated Ditungsten Hydride [W2(h5-C5H5)2(H)(μ-PCy2)(CO)2]

JOURNAL: Inorg. Chem. 2013, 52, 7068-7077

AUTHORS (in alph. order): D. García-Vivó, A. Ramos, Miguel A. Ruiz.

TITLE: Cyclopentadienyl and related complexes of the group 6 elements having metal-metal triple bonds: synthesis, structure, bonding and reactivity.

JOURNAL: Coord. Chem. Rev. 2013, 257, 2143-2191

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, Miguel A. Ruiz, A. Toyos, M. F. Vega.

TITLE: Low-Temperature N-O Bond Cleavage and Reversible N-P Bond Formation Processes in the Reactions of the Unsaturated Anions [M2(h5-C5H5)2(μ-PCy2)(μ-CO)2]-  (M = Mo, W) with the Nitrosyl Complex [Re(h5-C5H4Me)(CO)2(NO)]+.

JOURNAL: Inorg. Chem. 2013, 52, 3942-3952

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, D. García-Vivó, S. Menéndez, Miguel A. Ruiz.

TITLE: Electronic Structure and Reactivity of the Carbyne-Bridged Dimolybdenum Radical [Mo2(h5-C5H5)2(μ-CPh)(μ-PCy2)(μ-CO)]+.

JOURNAL: Organometallics 2013, 32, 218-231

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