Artículos de Investigación Año 2010

AUTORES (p.o. de firma): M. Alonso, M. A. Alvarez, M. E. García, Miguel A. Ruiz, H. Hamidov, J. C. Jeffery.

TITULO: Chemistry of the Oxophosphinidene Ligand. 2. Reactivity of the Anionic Complexes [MCp{P(O)R*}(CO)2]- (M= Mo, W; R* = 2,4,6-C6H2tBu3) Toward Electrophiles Based on Elements Different from Carbon.

REF. REVISTA: Inorg. Chem. 2010, 49, 11595-11605.

AUTORES (p.o. de firma): M. A. Alvarez, I. Amor, M. E. García, D. García-Vivó, Miguel A. Ruiz, J. Suarez.

TITULO: Structure, Bonding and Reactivity of Binuclear Complexes having Asymmetric Trigonal Phosphinidene Bridges: Addition of 16-electron Metal Carbonyl Fragments to the Dimolybdenum Compounds [Mo2Cp(m-k1:k1,h5-PC5H4)(CO)2L] and [Mo2Cp2(m-PH)(CO)2L] (L = h6-1,3,5-C6H3tBu3).

REF. REVISTA: Organometallics 2010, 29, 4384-4395.

AUTORES (p.o. de firma): M. Alonso, M. A. Alvarez, M. E. García, D. García-Vivó, Miguel A. Ruiz.

TITULO: Chemistry of the Oxophosphinidene Ligand. 1. Electronic Structure of the Anionic Complexes [MCp{P(O)R*}(CO)2]- (M= Mo, W; R* = 2,4,6-C6H2tBu3) and their Reactions with H+ and C-based Electrophiles.

REF. REVISTA: Inorg. Chem. 2010, 49, 8962-8976.

AUTORES (p.o. de firma): M. A. Alvarez, M. E. García, R. González, Miguel A. Ruiz.

TITULO: Reactions of the Phosphinidene-Bridged Complexes [Fe2(h5-C5H5)2(m-PR)(m-CO)(CO)2] (R = Cy, Ph, 2,4,6-C6H2tBu3) with Diazoalkanes. Formation and Rearrangements of Phosphadiazadiene-Bridged Derivatives.

REF. REVISTA: Organometallics 2010, 29, 5140-5153.

AUTORES (p.o. de firma): M. E. García, D. García-Vivó, Miguel A. Ruiz.

TITULO: Alkyne to carbyne coupling reactions of the unsaturated methoxycarbyne-bridged complex [Mo2(h5-C5H5)2(m-COMe)(m-PCy2)(CO)2].

REF. REVISTA: J. Organomet. Chem. 2010, 695, 1592-1597.

AUTORES (p.o. de firma): M. E. García, D. García-Vivó, Miguel A. Ruiz.

TITULO: Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 6. C-E Bond Formation and C-O Bond Cleavage Processes in the Reactions of [Mo2(h5-C5H5)2(m-COMe)(m-PCy2)(m-CO)] with several p-Block Elements (E) and their Hydride Derivatives.

REF. REVISTA: Organometallics 2010, 29, 2157-2165.

AUTORES (p.o. de firma): M. A. Alvarez, M. E. García, R. González, A. Ramos, Miguel A. Ruiz.

TITULO: Chemical and Structural Effects of Bulkness on Bent-Phosphinidene Bridges: Synthesis and Reactivity of the Diiron Complex [Fe2Cp2{m-P(2,4,6-C6H2tBu3)}(m-CO)(CO)2]

REF. REVISTA: Organometallics 2010, 29, 1875-1878.

AUTORES (p.o. de firma): M. A. Alvarez, M. E. García, M. E. Martínez, S. Menéndez, Miguel A. Ruiz.

TITULO: Dehydrogenative formation and reactivity of the unsaturated benzylidyne-bridged complex [Mo2Cp2(m-CPh)(m-PCy2)(m-CO)]: C-C and C-P coupling reactions.

REF. REVISTA: Organometallics 2010, 29, 710-713.

AUTORES (p.o. de firma): M. A. Alvarez, M. E. García, M. E. Martínez, Miguel A. Ruiz.

TITULO: Heterometallic derivatives of the unsaturated methyl-bridged complex [Mo2(h5-C5H5)2(m-CH3)(m-PCy2)(CO)2]. Photochemical generation of methylidyne clusters.

REF. REVISTA: Organometallics 2010, 29, 904-916.

AUTORES (p.o. de firma): M. A. Alvarez, M. E. García, D. García-Vivó, Miguel A. Ruiz, F. Vega.

TITULO: Synthesis and reactivity of the triply bonded binuclear anion [W2(h5-C5H5)2(m-PCy2)(m-CO)2]- : Tungsten makes a difference.

REF. REVISTA: Organometallics 2010, 29, 512-515.

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