Research Papers 2007

AUTHORS (in alph. order): M. E. García, A. Ramos, Miguel A. Ruiz, M. Lanfranchi, L. Marchio.

TITLE:  Structure and Bonding in the Unsaturated Hydride- and Hydrocarbyl-Bridged Complexes [Mo2(h5-C5H5)2(m-X)(m-PCy2)(CO)2] (X= H, CH3, CH2Ph, Ph). Evidence for the presence of a-Agostic and p-Bonding Interactions.

JOURNAL: Organometallics 2007, 26, 6197-6212

AUTHORS (in alph. order): M. E. García, D. García-Vivó, Miguel A. Ruiz, S. Alvarez, G. Aullón.

TITLE: Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 2. Synthesis, Structure and Bonding of 32- and 34-Electron Complexes.

JOURNAL: Organometallics 2007, 26, 5912-5921.

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, A. Ramos, Miguel A. Ruiz, M. Lanfranchi, A. Tiripicchio.

TITLE:  Alkenyl Derivatives of the Unsaturated Dimolybdenum Hydride Complex [Mo2(h5-C5H5)2(m-H)(m-PCy2)(CO)2].

JOURNAL: Organometallics 2007, 26, 5454-5467.

AUTHORS (in alph. order): M. E. García, D. García-Vivó, Miguel A. Ruiz, S. Alvarez, G. Aullón.

TITLE:Chemistry of Unsaturated Group 6 Metal Complexes with Bridging Hydroxy and Methoxycarbyne Ligands. 1. Synthesis, Structure and Bonding of 30-Electron Complexes.

JOURNAL: Organometallics 2007, 26, 4930-4941.

AUTHORS (in alph. order): M. A. Alvarez, I. Amor, M. E. García, D. García-Vivó, Miguel A. Ruiz.

TITLE: Carbene- and Carbyne-like Behavior of the Mo-P Multiple Bond in a Dimolybdenum Complex Inducing Trigonal Pyramidal Coordination of a Phosphinidene Ligand.

JOURNAL: Inorg. Chem. 2007, 46, 6230-6232.

AUTHORS (in alph. order): M. A. Alvarez, M. E. García, A. Ramos, Miguel A. Ruiz.

TITLE: Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward P-donor Bidentate Ligands and some Unsaturated N-containing Organic Molecules

JOURNAL: Organometallics 2007, 26, 1461-1472.

AUTHORS (in alph. order): I. Amor, D. García-Vivó, M. E. García, Miguel A. Ruiz, D. Sáez, H. Hamidov, J. C. Jeffery.

TITLE: Formation of P-H, P-C, and C-H Bonds by Hydride Attack on a Electrophilic Phosphide-Bridged Dimolybdenum Complex. Trapping the Phosphinidene Ligand with Borane.

JOURNAL: Organometallics 2007, 26, 466-468.

AUTHORS (in alph. order): M. A. Alvarez, Y. Anaya, M. E. García, Miguel A. Ruiz.

TITLE: Chemistry of Highly Electrophilic Binuclear Cations. 6. Synthesis of the Alkyne-Bridged Complexes [Mo2(η5-C5H5)2{µ-η2:η2-HC2(p-tol)}(CO)2(µ-L2)][B{3,5-C6H3(CF3)2}4]2 and their Isocyanide Derivatives (L2= Ph2PCH2PPh2, Me2PCH2PMe2).

JOURNAL: J. Organomet. Chem. 2007, 692, 983-990.

AUTHORS (in alph. order): C. M. Alvarez, M. A. Alvarez, M. E. García, A. Ramos, Miguel A. Ruiz, C. Graiff, A.Tiripicchio.

TITLE: Reactivity of the Unsaturated Hydride [Mo2(η5-C5H5)2(μ-H)(μ-PCy2)(CO)2] toward 17- and 16-electron Metal Carbonyl Fragments: Rational Synthesis of Electron-Deficient Heterometallic Clusters.

JOURNAL: Organometallics 2007, 26, 321-331

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