Javier A. Cabeza  -  Publications

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Reviews       Articles and Communications     Book Chapters

Reviews

   14.   Polydentate amidinatosilylenes, -germylenes and -stannylenes. (PDF)

           J.A. Cabeza and P. García-Álvarez, Chem. Eur. J., 2024, 30, e202400786 (editor's invitation).

   13.   Tetrelanes versus tetrylenes as precursors to transition metal complexes featuring tridentate PEP tetryl tigands (E = Si, Ge, Sn). (PDF) (frontispiece)

           J.A. Cabeza and P. García-Álvarez, Chem. Eur. J., 2023, 29, e202203096 (editor's invitation; selected by the editorial office for the showcase of outstanding review-type articles).

   12.   Advances in the synthesis and reactivity of group 6 metal allenyls. (PDF)

           J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego and M.A. Sierra, Adv. Organomet. Chem., 2022, 77, 331-365 (editor's invitation).

   11.   Cyclometallation of heavier tetrylenes: Reported complexes and applications in catalysis. (PDF)

           J.A. Cabeza and P. García-Álvarez, Eur. J. Inorg. Chem., 2021, 3315-3326 (editor's invitation).

   10.   The transition metal chemistry of PGeP and PSnP pincer heavier tetrylenes. (PDF) (issue cover) (cover profile)

           J.A. Cabeza, P. García-Álvarez and C.J. Laglera-Gándara, Eur. J. Inorg. Chem., 2020, 784-795 (editor's invitation).

   9.     Tetrilenos pesados: Aspectos generales y aplicaciones en catálisis homogénea. (PDF) (issue cover)

           J.A. Cabeza and P. García-Álvarez, Anal. Quim., 2017, 113, 77-91 (editor's invitation).

   8.     Intramolecularly stabilized heavier tetrylenes: From monodentate to bidentate ligands. (PDF)

           J.A. Cabeza, P. García-Álvarez and D. Polo, Eur. J. Inorg. Chem., 2016, 10-22 (editor's invitation).

   7.     The transition-metal chemistry of amidinatosilylenes, -germylenes and -stannylenes. (PDF)

           L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and D. Polo, Coord. Chem. Rev., 2015, 300, 1-28 (editor's invitation).

   6.     The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters. (PDF)

           J.A. Cabeza and P. García-Álvarez, Chem. Soc. Rev., 2011, 40, 5389-5405.

   5.     Basal edge-bridged square pyramidal hexaruthenium carbonyl clusters: Synthesis, structure, and reactivity. (PDF) (issue cover) (cover profile)

           J.A. Cabeza and P. García-Álvarez, Organometallics, 2008, 27, 2878-2891 (editor's invitation).

   4.     The important role of some ancillary ligands in the chemistry of carbonyl metal cluster complexes. Selected reactivity of triruthenium clusters containing deprotonated 2-aminopyridines. (PDF)

           J.A. Cabeza, Eur. J. Inorg. Chem., 2002, 1559-1570 (editor's invitation).

   3.     Carbonyl metal clusters as homogeneous catalysts: hydrogenation of alkynes mediated by hydridotriruthenium clusters containing bridging N-donor ligands. (PDF)

           J.A. Cabeza, J.M. Fernández-Colinas and A. Llamazares, Synlett, 1995, 579-584 (editor's invitation).

   2.     Organosilicon and organotin derivatives of triruthenium carbonyl cluster complexes. (PDF)

           J.A. Cabeza, R.J. Franco and A. Llamazares, Trends Organomet. Chem.,1994, 1, 29-34 (editor's invitation).

   1.     Ruthenium(I) complexes containing bridging N-donor ligands: structure, synthesis, and reactivity patterns. (PDF)

         J.A. Cabeza and J.M. Fernández-Colinas, Coord. Chem. Rev., 1993, 126, 319-336.

Articles and Communications

2025

231.    Tetrylenes are able to discern between isomeric structures of unsaturated osmium(IV) polyhydrides. (PDF)

         J.A Cabeza, M.A. Esteruelas, S. Izquierdo and E. Oñate, Chem. Eur. J., 2025, 31, e202404629.

2024

230.    A lead μ₂-tetrylide complex with osmium(IV) terminal components. (PDF)

         J.A Cabeza, M.A. Esteruelas, I. Fernández, S. Izquierdo and E. Oñate, Inorg. Chem., 2024, 63, 15563-15567.

229.    Attaching metal-containing moieties to β-lactam antibiotics: The case of penicillin and cephalosporin. (PDF)

         M. Moreno-Latorre, M.C. de la Torre, J.A Cabeza, P. García-Álvarez and M.A. Sierra, Inorg. Chem., 2024, 63, 12593-12603.

228.    A cross-metathesis approach to polymetallic [FeFe]-hydrogenase mimics. (PDF)

         S. Aguado, P. García-Álvarez, J.A. Cabeza, L. Casarrubios and M.A: Sierra, Dalton Trans., 2024, 53, 3756-3764.

227.    Amidinatotetrylenes donor-functionalized on both N atoms: Structures and coordination chemistry. (PDF)

         C. Álvarez, J.A. Cabeza, P. García-Álvarez, R. García-Soriano and E. Pérez-Carreño, Inorg. Chem., 2024, 63, 3118-3128.

226.    Nucleobase stacking sustained by Pt–Pt interactions. (PDF) (issue cover)

         C. Lorenzo-Aparicio, P. García-Álvarez, J.A. Cabeza, M. Gómez-Gallego and M.A. Sierra, ChemistryEurope, 2024, 2, e202300065.

2023

225.    Fast and scalable solvent-free access to Lappert´s heavier tetrylenes E{N(SiMe₃)₂}₂ (E = Ge, Sn, Pb) and ECl{N(SiMe₃)₂} (E = Ge, Sn). (PDF) (Issue cover) (Correction)

         J.A. Cabeza, J.F. Reynes, F. García, P. García-Álvarez and R. García-Soriano, Chem. Sci., 2023, 14, 12477-12483 (selected by the editorial office to be included in the journal 2023 most popular inorganic chemistry articles).

224.    Synthesis and some coordination chemistry of phosphane-difunctionalized bis(amidinato)-heavier tetrylenes: A previously unknown class of PEP tetrylenes (E = Ge, Sn). (PDF)

         J.A. Cabeza, F. García, P. García-Álvarez, R. García-Soriano and E. Pérez-Carreño, Inorg. Chem., 2023, 62, 15502–15509.

223.    Synthesis, structure and photophysical properties of platinum(II) (N,C,N’) pincer complexes derived from purine nucleobases. (PDF)

         C. Lorenzo-Aparicio, S. Moreno-Blázquez, M. Oliván, M.A. Esteruelas, M. Gómez-Gallego, P. García-Álvarez, J.A. Cabeza and M.A. Sierra, Inorg. Chem., 2023, 62, 8232-8248.

2022

222.    Dipyrromethane-based PGeP germyl rhodium complexes. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, J. García-Álvarez, P. García-Álvarez, C.J. Laglera-Gándara and M. Ramos-Martín, Chem. Eur. J., 2022, 28, e202200847.

2021

221.    Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: Syntheses and behavior as precursors to palladium(II), palladium(0) and gold(I) complexes containing PSnP pincer ligands. (PDF)

         J.A. Cabeza, I. Fernández, P. García-Álvarez, R. García-Soriano, C.J. Laglera-Gándara and R. Toral, Dalton Trans., 2021, 50, 16122-16132.

220.    Alternative conceptual approach to the design of bifunctional catalysts: An osmium-germylene system for the dehydrogenation of formic acid. (PDF)

         M.L. Buil, J.A. Cabeza, M.A. Esteruelas, S. Izquierdo, C.J. Laglera-Gándara, A.I. Nicasio and E. Oñate, Inorg. Chem., 2021, 60, 16860-16870.

219.    Dipyrromethane-based PGeP pincer methylgermyl and methoxidogermyl nickel and palladium complexes. (PDF)

         J.A. Cabeza, P. García-Álvarez, C.J. Laglera-Gándara and E. Pérez-Carreño, Eur. J. Inorg. Chem., 2021, 1897-1902 (editor's invitation).

218.    Reactions of late first-row transition metal (Fe–Zn) dichlorides with a PGeP pincer germylene. (PDF)

         A. Arauzo, J.A. Cabeza, I. Fernández, P. García-Álvarez, I. García-Rubio and C.J. Laglera-Gándara, Chem. Eur. J., 2021, 27, 4985-4992.

2020

217.    A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex. (PDF)

         J.A. Cabeza, P. García-Álvarez, C.J. Laglera-Gándara and E. Pérez-Carreño, Chem. Commun., 2020, 56, 14095-14097.

216.    Phosphane-functionalized heavier tetrylenes: Synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes. (PDF)

         J.A. Cabeza, P. García-Álvarez, C.J. Laglera-Gándara and E. Pérez-Carreño, Dalton Trans., 2020, 49, 8331-8339.

215.    Reactivity of amidinatosilylenes and amidinatogermylenes with [PtMe₂(η⁴-cod)]: cis- versus trans-[PtMe₂L₂] complexes and cyclometalation reactions. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, L. González-Álvarez and E. Pérez-Carreño, Organometallics, 2020, 39, 2026-2036.

214.    Two octahedral (Mn^I and Ru^II) σ-borane complexes containing a tripod κ³N,H,H-ligand. Synthesis, structural characterization, and theoretical topological study of the charge density. (PDF)

         J.F. Van der Maelen, J. Brugos, P. García-Álvarez and J.A. Cabeza, J. Mol. Struct., 2020, 1201, 12717 (editor's invitation).

2019

213.    A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral copper(I) and T-shaped silver(I) and gold(I) PGeP pincer complexes. (PDF)

         J.A. Cabeza, I. Fernández, P. García-Álvarez and C.J. Laglera-Gándara, Dalton Trans., 2019, 48, 13273-13280.

212.    A germylene supported by two 2-pyrrolylphosphane groups as precursor to PGeP pincer square-planar Group 10 metal(II) and T-shaped gold(I) complexes. (PDF)

         J.A. Cabeza, I. Fernández, J.M. Fernández-Colinas, P. García-Álvarez and C.J. Laglera-Gándara, Chem. Eur. J., 2019, 25, 12423-12430.

211.    Mesityl(amidinato)tetrylenes as ligands in iridium(I) and iridium(III) complexes: Silicon versus germanium and simple κ¹-coordination versus cyclometallation. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, L. González-Álvarez and E. Pérez-Carreño, Dalton Trans., 2019, 48, 10996-11003.

210.    Two types of σ-allenyl complexes from reactions of silylenes and germylenes with chromium Fischer alkynyl(alkoxy)carbenes. (PDF)

         J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 8635-8642.

209.    Unexpected zwitterionic allenyls from silylenes and a Fischer alkynylcarbene: A remarkable silylene-promoted rearrangement. (PDF)

         J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 2222-2225.

208.    Reversible carbene insertion into a Ge–N Bond and insights into CO- and carbene-substitution reactions involving amidinatogermylenes and Fischer carbene complexes. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2019, 25, 1588-1594.

2018

207.    Ruthenium carbene complexes analogous to Grubbs-I catalysts featuring germylenes as ancillary ligands. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2018, 37, 3399-3406.

206.    Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH₂P^tBu₂)₂C₆H₄, attempts to prepare the PSiP analogue, and effect of the E atom on the molecular structures of E(NCH₂P^tBu₂)₂C₆H₄ (E = C, Si, Ge, Sn). (PDF)

         J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and Diego Polo, Dalton Trans., 2018, 47, 4534-4544.

205.    From a PGeP pincer-type germylene to metal complexes featuring chelating (Ir) and tripodal (Ir) PGeP germyl and bridging (Mn₂) and chelating (Ru) PGeP germylene ligands. (PDF)

         J. Brugos, J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2018, 37, 1507-1514.

2017

204.    From a diphosphanegermylene to nickel, palladium and platinum complexes containing germyl PGeP pincer ligands. (PDF)

         L. Álvarez-Rodríguez, J. Brugos, J.A. Cabeza, P. García-Álvarez and E. Pérez-Carreño, Chem. Eur. J., 2017, 23, 15107-15115.

203.    Facile cyclometallation of a mesitylsilylene: Synthesis and preliminary catalytic activity of iridium(III) and iridium(V) iridasilacyclopentenes. (PDF)

         J.A. Cabeza, P. García-Álvarez and L. González-Álvarez, Chem. Commun., 2017, 53, 10275-10278.

202.    Octahedral manganese(I) and ruthenium(II) complexes containing 2-(methylamido)pyridine-borane as a tripod κ³N,H,H-ligand. (PDF)

         J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and J.F. Van der Maelen, Dalton Trans., 2017, 46, 4009-4017.

201.    First insertions of carbene ligands into Ge–N and Si–N bonds. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, A.D. Merinero and M.A. Sierra, Chem. Eur. J., 2017, 23, 4287-4291.

200.    Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene. (PDF)

         L. Álvarez-Rodríguez, J. Brugos, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Chem. Commun., 2017, 53, 893-896.

2016

199.    2-(Methylamido)pyridine–borane: A tripod κ³N,H,H-ligand in trigonal bipyramidal rhodium(I) and iridium(I) complexes with an asymmetric coordination of its BH₃ group. (PDF)

         J. Brugos, J.A. Cabeza, P. García-Álvarez, A.R. Kennedy, E. Pérez-Carreño and J.F. van der Maelen, Inorg. Chem., 2016, 55, 8905-8912.

198.    Amidinatogermylene metal complexes as homogeneous catalysts in alcoholic media. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, J.M Fernández-Colinas, P. García-Álvarez and D. Polo, Organometallics, 2016, 35, 2516-2523.

197.    [MnBrL(CO)4] (L = amidinatogermylene): Reductive dimerization, carbonyl substitution, and hydrolysis reactions. (PDF)

         J.A. Cabeza, P. García-Álvarez, R. Gobetto, L. González-Álvarez, C. Nervi, E. Pérez-Carreño and D. Polo, Organometallics, 2016, 35, 1761-1770.

196.    Fully borylated methane and ethane by ruthenium-mediated cleavage and coupling of CO. (PDF)

         A.S. Batsanov, J.A. Cabeza, M.G. Crestani, M.R. Fructos, P. García-Álvarez, M. Gille, Z. Lin and T.B. Marder, Angew. Chem. Int. Ed., 2016, 55, 4707-4710; Angew. Chem., 2016, 128, 4785-4788.

195.    A topological analysis of the bonding in [M₂(CO)₁₀] and [M₃(µ-H)₃(CO)₁₂] complexes (M = Mn, Tc, Re). (PDF)

         J.F. Van der Maelen and J.A. Cabeza, Theor. Chem. Acc., 2016, 135, 64 (1-11).

2015

194.    Amidinatogermylene complexes of copper, silver, and gold. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and D. Polo, Organometallics, 2015, 34, 5479-5484.

193.    Reactivity studies on a binuclear ruthenium(0) complex equipped with a bridging κ²N,Ge-amidinatogermylene ligand. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Inorg. Chem., 2015, 54, 4850-4861.

192.    Amidinatogermylene derivatives of ruthenium carbonyl: New insights into the reactivity of [Ru₃(CO)₁₂] with two-electron-donor reagents of high basicity. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Inorg. Chem., 2015, 54, 2983-2994.

2014

191.    Conversion of a monodentate amidinate-germylene ligand into chelating imine-germanate ligands (on mononuclear manganese complexes). (PDF)

         J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Inorg. Chem., 2014, 53, 8735-8741.

190.    Electron density studies on the regioselectivity of deprotonation reactions. (PDF)

         J.A. Cabeza and J.F. van der Maelen, Acta Cryst., 2014, A70, C287.

189.    Steric effects in the reactions of amidinate germylenes with ruthenium carbonyl: Isolation of a coordinatively unsaturated diruthenium(0) derivative. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez and D. Polo, RSC Adv., 2014, 4, 31503-31506.

188.    Ring opening and bidentate coordination of amidinate germylenes and silylenes on carbonyl dicobalt complexes: The importance of a slight difference in ligand volume. (PDF)

         J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and D. Polo, Chem. Eur. J., 2014, 20, 8654-8663.

2013

187.    Reactivity of a (bis-NHC)tricarbonylruthenium(0) complex with methyl triflate and methyl iodide. Formation of methyl- and acetylruthenium(II) derivatives: Experimental results and mechanistic DFT calculations. (PDF)

         J.A. Cabeza, M. Damonte, P. García-Álvarez and E. Pérez-Carreño, Organometallics, 2013, 32, 4382-4390.

186.    Organic amides as suitable precursors to stabilize stannylenes. (PDF)

         L. Álvarez-Rodríguez, J.A. Cabeza, P. García-Álvarez and D. Polo, Organometallics, 2013, 32, 3557-3561.

185.    Deprotonation of C-alkyl groups of cationic triruthenium clusters containing cyclometalated C-alkylpyrazinium ligands: Experimental and computational studies. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez, E. Pérez-Carreño, V. Pruneda and J.F. Van der Maelen, Chem. Eur. J., 2013, 19, 9251-9260.

184.    Easy abstraction of a hydride anion from an alkyl C–H bond of a coordinated bis(N-heterocyclic carbene). (PDF)

         J.A. Cabeza, M. Damonte, P. García-Álvarez and E. Pérez-Carreño, Chem. Commun., 2013, 49, 2813-2815.

183.    Synthesis and reactivity of cationic triruthenium clusters derived from 2-methyl- and 4-methylpyrimidines: From conventional cyclometalated ligands to new types of N-heterocyclic carbenes. (PDF)

         J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and V. Pruneda, Chem. Eur. J., 2013, 19, 3426-3436.

182.    Expanding the coordination chemistry of donor-stabilized group-14 metalenes. (PDF)

         J.A. Cabeza, P. García-Álvarez and D. Polo, Dalton Trans., 2013, 42, 1329-1332.

2012

181.    Reactivity of a bis(N-heterocyclic carbene) with ruthenium carbonyl. Synthesis of mono- and trinuclear derivatives and carbene ligand modification via C–H bond activation. (PDF)

         J.A. Cabeza, M. Damonte and E. Pérez-Carreño, Organometallics, 2012, 31, 8355-8359.

180.    Reactivity of a quinoline-tethered N-heterocyclic carbene with polynuclear ruthenium carbonyls. (PDF)

         J.A. Cabeza, M. Damonte and E. Pérez-Carreño, Organometallics, 2012, 31, 8114-8120.

179.    QTAIM analysis of the bonding in Mo–Mo bonded dimolybdenum complexes. (PDF)

         J.F. Van der Maelen and J.A. Cabeza, Inorg. Chem., 2012, 51, 7384-7391.

178.    Reactions of phthalazine, quinazoline, 4,7-phenanthroline and 2,3’-bipyridine with ruthenium carbonyl. (PDF)

         J.A. Cabeza and V. Pruneda, Dalton Trans., 2012, 41, 7249-7257.

177.    Reactivity of [Ru₄(µ-H)₄(CO)₁₂] with bidentate ligands containing at least one N-heterocyclic carbene moiety. (PDF)

         J.A. Cabeza, M. Damonte and M.G. Hernández-Cruz, J. Organomet. Chem., 2012, 711, 68-74.

176.    Reactions of CS₂ and C(S)NPh adducts of N-heterocyclic carbenes with [Ru₃(CO)₁₂]: Remarkable reactivity of these betaines involving one or two C-S bond activation processes. (PDF)

         J.A. Cabeza, P. García-Álvarez and M.G. Hernández-Cruz, Eur. J. Inorg. Chem., 2012, 2928-2932.

175.    Diaminogermylene and diaminostannylene derivatives of gold(I): Novel AuM and AuM₂ (M = Ge, Sn) complexes. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas, P. García-Álvarez and D. Polo, Inorg. Chem., 2012, 51, 3896-3903.

174.    Deprotonation of C-alkyl groups of cationic C-alkyl N-heterocyclic ligands. (PDF)

         J.A. Cabeza, P. García-Álvarez, E. Pérez-Carreño and V. Pruneda, Dalton Trans., 2012, 41, 4313-4315.

173.    Reaction of [Ru₃(CO)₁₂] with phenazine: Synthesis of C-metalated derivatives that formally arise from a C-H oxidative addition or a long-distance C-to-N prototropy. (PDF)

         J.A. Cabeza, P. García-Álvarez and V. Pruneda, Organometallics, 2012, 31, 941-946.

172.    Synthesis of mixed tin-ruthenium and tin-germanium-ruthenium carbonyl clusters from [Ru₃(CO)₁₂] and diaminometalenes (M = Sn, Ge). (PDF)

         J.A. Cabeza, P. García-Álvarez and D. Polo, Inorg. Chem., 2012, 51, 2569-2576.

171.    Reactivity of phosphine- and thioether-tethered N-heterocyclic carbenes with ruthenium carbonyl. (PDF)

         J.A. Cabeza, M. Damonte, P. García-Álvarez, M.G. Hernández-Cruz and A.R. Kennedy, Organometallics, 2012, 31, 327-334.

2011

170.    Theoretical topological analysis of the electron density in a series of triosmium carbonyl clusters: [Os₃(CO)₁₂], [Os₃(µ-H)₂(CO)₁₀], [Os₃(µ-H)(µ-OH)(CO)₁₀], and [Os₃(µ-H)(µ-Cl)(CO)₁₀]. (PDF)

         J.F. Van der Maelen, S. García-Granda and J.A. Cabeza, Comput. Theor. Chem., 2011, 968, 55-63.

169.    Reactivity of diaminogermylenes with ruthenium carbonyl: Ru₃Ge₃ and RuGe₂ derivatives. (PDF)

         J.A. Cabeza, P. García-Álvarez and D. Polo, Inorg. Chem., 2011, 50, 6195-6199.

168.    Different reactivities of pyrid-2-yl- and 6-picol-2-yl-functionalized NHC ligands with [Ru₃(CO)₁₂]: C(sp²)-H and double C(sp³)-H bond activation reactions. (PDF)

         J.A. Cabeza, M. Damonte and P. García-Álvarez, Organometallics, 2011, 30, 2371-2376.

167.    Reactivity of cationic triruthenium carbonyl clusters: From pyrimidinium ligands to N-heterocyclic carbenes. (PDF) target="_blank"

         J.A. Cabeza, I. del Río, E. Pérez-Carreño and V. Pruneda, Organometallics, 2011, 30, 1148-1156.

166.    Reactivity of [Ru₃(CO)₁₂] with a phosphine-functionalized imidazol-2-ylidene and its imidazolium salt. (PDF)

         J.A. Cabeza, M. Damonte, P. García-Álvarez, A.R. Kennedy and E. Pérez-Carreño, Organometallics, 2011, 30, 826-833.

2010

165.    From allenes to edge-bridging allyl ligands or face-capping alkenyl ligands on a triruthenium hydrido carbonyl cluster: An experimental and DFT computational study. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, E. Pérez-Carreño and D. Vázquez-García, Organometallics, 2010, 29, 4818-4828.

164.    Trapping of pyrid-2-ylidenes by [Ru₃(CO)₁₂]: Orthometalated pyrid-2-ylidenes in triruthenium clusters. (PDF)

         J.A. Cabeza, I. del Río, E. Pérez-Carreño, M.G. Sánchez-Vega and D. Vázquez-García, Organometallics, 2010, 29, 4464-4471.

163.    The bridging acetylene to bridging vinylidene rearrangement in a triruthenium carbonyl cluster: A DFT mechanistic study. (PDF)

         J.A. Cabeza and E. Pérez-Carreño, Organometallics, 2010, 29, 3873-3978.

162.    Reactivity of [Os₃(µ-H)₂(CO)₁₀] with N-heterocyclic carbenes: A combined experimental and DFT computational study. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, E. Pérez-Carreño, M.G. Sánchez-Vega and D. Vázquez-García, Organometallics, 2010, 29, 3828-3836.

161.    Reductive dimerization of triruthenium clusters containing cationic aromatic N-heterocyclic ligands. (PDF)

         J.A. Cabeza, I. del Río, E. Pérez-Carreño and V. Pruneda, Chem. Eur. J., 2010, 16, 5425-5436.

2009

160.    Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands. (PDF)

         J.A. Cabeza, I. del Río, M.C. Goite, E. Pérez-Carreño and V. Pruneda, Chem. Eur. J., 2009, 15, 7339-7349.

159.    DFT mechanistic study of the transformation of cyclohexa-1,3-diene into a bridging allyl ligand upon reaction with a triruthenium hydrido carbonyl cluster. (PDF)

         J.A. Cabeza, J.M. Fernández-Colinas and E. Pérez-Carreño, Organometallics, 2009, 28, 4217-4220.

158.    Topological analysis of the electron density in the N-heterocyclic carbene triruthenium cluster [Ru₃(µ-H)₂(µ₃-MeImCH)(CO)₉] (Me₂Im = 1,3-dimethylimidazol-2-ylidene). (PDF)

         J.A. Cabeza, J.F. Van der Maelen and S. García-Granda, Organometallics, 2009, 28, 3666-3672.

157.    Reactivity of [Ru₄(µ-H)₄(CO)₁₂] with N-heterocyclic carbenes. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, E. Pérez-Carreño, M.G. Sánchez-Vega and D. Vázquez-García, Organometallics, 2009, 28, 1832-1837.

156.    Reactivity of protons, tertiary stannanes, and alkynes with a triruthenium dihydrido cluster containing a face-capping NHC ligand. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas and M.G. Sánchez-Vega, Organometallics, 2009, 28, 1243-1247.

155.    A simple preparation of pyridine-derived N-heterocyclic carbenes and their transformation into bridging ligands by orthometalation. (PDF)

         J.A. Cabeza, I. del Río, E. Pérez-Carreño, M.G. Sánchez-Vega and D. Vázquez-García, Angew. Chem. Int. Ed., 2009, 48, 555-558; Angew. Chem., 2009, 121, 563-566.

2008

154.    Double C–H bond activation of an NHC N-methyl group on triruthenium and triosmium carbonyl clusters: A DFT mechanistic study. (PDF)

         J.A. Cabeza and E. Pérez-Carreño, Organometallics, 2008, 27, 4697-4702.

153.    Activation of two C–H bonds of NHC N–methyl groups on triosmium and triruthenium carbonyl clusters. (PDF)

         J.A. Cabeza, I. del Río, D. Miguel, E. Pérez-Carreño and M.G. Sánchez-Vega, Dalton Trans., 2008, 1937-1942.

152.    From an N-methyl N-heterocyclic carbene to carbyne and carbide ligands via multiple C–H and C–N bond activations. (PDF)

         J.A. Cabeza, I. del Río, D. Miguel and M.G. Sánchez-Vega, Angew. Chem. Int. Ed., 2008, 47, 1920-1922; Angew. Chem., 2008, 120, 1946-1948.

151.    Reactions of conjugated dienes with a triruthenium hydrido carbonyl cluster: Synthesis and reactivity of trinuclear derivatives having an edge-bridging allyl ligand. (PDF)

         J.A. Cabeza, I. del Río, M. Gille, M.C. Goite and E. Pérez-Carreño, Organometallics, 2008, 27, 609-616.

150.    Reactivity of N-heterocyclic carbenes with [Ru₃(CO)₁₂] and [Os₃(CO)₁₂]. Influence of ligand volume and electronic effects. (PDF)

         J.A. Cabeza, I. del Río, D. Miguel, E. Pérez-Carreño and M.G. Sánchez-Vega, Organometallics, 2008, 27, 211-217.

149.    Reactivity of a triruthenium alkenyl cluster complex with conjugated diynes. Coupling of two diyne molecules via a face-capping diyne intermediate. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez and E. Pérez-Carreño, J. Organomet. Chem., 2008, 693, 97-102.

2007

148.    Synthesis and characterization of a tetraruthenium butterfly cluster containing a quadruply-bridging ligand derived from an N,N’-dipyrid-2-ylurea. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez and D. Miguel, J. Organomet. Chem., 2007, 692, 4407-4410.

147.    Mononuclear ruthenium complexes containing chiral aminooxazolines. Syntheses, X-ray studies and catalytic activity. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río, R. Gossage, L. Martínez-Méndez and D. Miguel, J. Organomet. Chem., 2007, 692, 4346-4352.

146.    A new coordination mode for (pyrid-2-yl)thiolate (L) ligands. Synthesis and characterization of [Ru₆(µ₃-H)(µ₅-κ²-L)(µ-CO)(CO)₁₅]. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, J. Organomet. Chem., 2007, 692, 3583-3587.

145.    High-nuclearity osmium carbonyl cluster complexes containing (6-methylpyrid-2-yl)imido ligands. Synthesis of hepta-, octa-, and nonanuclear derivatives. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Organometallics, 2007, 26, 3212-3216.

144.    Ruthenium cluster-mediated transformation of linear alkenes into trienyl ligands. Activation of five C(sp³)–H bonds of 1-octene, 1-nonene, and 1-decene. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Organometallics, 2007, 26, 2482-2484.

143.    Reactivity of indene, fluorene, azulene, and acenaphthylene with a basal edge-bridged square pyramidal hexaruthenium dihydride. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, P. García-Álvarez and D. Miguel, Organometallics, 2007, 26, 1414-1423.

2006

142.    Nonanuclear ruthenium carbonyl cluster complexes with a novel metallic skeleton: Pentagonal bipyramid with two equatorial edges spanned by metal atoms. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Organometallics, 2006, 25, 5672-5675.

141.    Triruthenium and triosmium carbonyl clusters containing chiral bidentate NHC-thiolate ligands derived from levamisole. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río and M.G. Sánchez-Vega, Dalton Trans., 2006, 3966-3971.

140.    Reactions of µ₃-alkenyl triruthenium carbonyl clusters with alkynes: Synthesis of trinuclear µ-//-alkyne, µ-vinylidene, and µ-dienoyl derivatives. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez and E. Pérez-Carreño, Chem. Eur. J., 2006, 12, 7694-7705.

139.    High-nuclearity ruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine: Synthesis of nonanuclear derivatives containing µ₄- and µ₅-oxo ligands. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Inorg. Chem., 2006, 45, 6020-6027.

138.    Reactivity of arenes, cycloheptatriene, and dicyclopentadiene with a basal edge-bridged square pyramidal hexaruthenium dihydride. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Organometallics, 2006, 25, 2683-2692.

137.    Triruthenium carbonyl clusters derived from chiral aminooxazolines: Synthesis and catalytic activity. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río, R.A. Gossage, D. Miguel and M. Suárez, Dalton Trans., 2006, 2450-2455.

136.    Hexaruthenium and octaruthenium carbonyl cluster complexes derived from 2-amino-6-methylpyridine. Novel coordination modes for 2-imidopyridines. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Can. J. Chem., 2006, 84, 105-110.

135.    Methyl levamisolium triflate as a precursor to a chiral bifunctional N-heterocyclic carbene-thiolate ligand: Palladium(II) complexes. (PDF)

         J.A. Cabeza, I. del Río, M. G. Sánchez-Vega and M. Suárez, Organometallics, 2006, 25, 1831-1834.

134.    Reactivity of diphenylbutadiyne with a hexaruthenium dihydride. Unusual 1,1- and trans-1,2-additions of two hydrogen atoms to an internal CC triple bond. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, P. García-Alvarez and D. Miguel, Organometallics, 2006, 25, 1492-1499.

133.    Ruthenium cluster-mediated activation of all bonds of methyl groups of 6,6'-dimethyl-2,2'-bipyridine and 2,9-dimethyl-1,10-phenanthroline. Transformation of the latter into a 2-alkenyl-9-methyl-1,10-phenanthroline ligand. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez and D. Miguel, Chem. Eur. J., 2006, 12, 1529-1538.

2005

132.    Reactivity of alkynes containing α-hydrogen atoms with a triruthenium hydrido carbonyl cluster: Alkenyl versus allyl cluster derivatives. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez, E. Pérez-Carreño and S. García-Granda, Chem. Eur. J., 2005, 11, 6040-6052.

131.    Dichlorobis[(S)-2,3,5,6-tetrahydro-6-phenylimidazo[2,1-b]thiazole]nickel(II). (PDF)

         J.A. Cabeza, I. del Río, M. G. Sánchez-Vega and S. García-Granda, Acta Crystallogr., Sect. E, 2005, 61, m1984-m1985.

130.    Easy activation of two C-H bonds of an N-heterocyclic carbene N-methyl group. (PDF)

         J.A. Cabeza, I. del Río, D. Miguel and M. G. Sánchez-Vega, Chem. Commun., 2005, 3956-3958.

129.    Can µ₄-alkyne and µ₃-alkenyl ligands be considered as 6- and 5-electron donors, respectively? (PDF)

         J.A. Cabeza, P. García-Alvarez and E. Pérez-Carreño, Organometallics, 2005, 24, 2000-2003.

128.    η²-Edge-bridging and η³-face-capping coordination of conjugated ynenyl ligands in triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine. (PDF)

         J.A. Cabeza, I. del Río, L. Martínez-Méndez, S. García-Granda and E. Pérez-Carreño, Organometallics, 2005, 24, 831-835.

127.    Reactivity of diphenylacetylene with a basal edge-bridged square pyramidal hexaruthenium cluster. Characterization of penta-, hexa-, and heptanuclear alkyne derivatives. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez and D. Miguel, Organometallics, 2005, 24, 665-674.

126.    [N,N’-Bis-(6-methylpyrid-2-ylium)-(1R,2R)-1,2-diaminocyclohexane] bis-[(p-cymene)trichlororuthenate(II)]. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río and S. García-Granda, Appl. Organomet. Chem., 2005, 19, 209-210.

2004

125.    η³-Edge-bridging versus η³-face-capping coordination of a conjugated ynenyl ligand on a triruthenium cluster core. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, M. Moreno, E. Pérez-Carreño and M. Suárez, Organometallics, 2004, 23, 5849-5855.

124.    Edge-bridging and face-capping coordination of alkenyl ligands in triruthenium carbonyl cluster complexes derived from hydrazines: synthetic, structural, theoretical and kinetic studies. (PDF)

         J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, S. García-Granda, L. Martínez-Méndez and E. Pérez-Carreño, Chem. Eur. J., 2004, 10, 6265-6278.

123.    Photolysis of diruthenium hexacarbonyl tetrahedrane compounds in Nujol glass matrices. (PDF)

         T.E. Bitterwolf and J.A. Cabeza, J. Organomet. Chem., 2004, 689, 2947-2951.

122.    Hexaruthenium carbonyl cluster complexes with basal edge-bridged square pyramidal metallic skeleton: efficient synthesis of 2-imidopyridine derivatives and determination of their reactive sites in carbonyl substitution reactions. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez, D. Miguel and V. Riera, Inorg. Chem., 2004, 43, 5450-5458.

121.    Reactivity of a triruthenium cluster complex containing a µ₃-η³-C,N₂ ligand derived from 2-amino-7,8-benzoquinoline. Coupling of this ligand with C₃ fragments and characterization of µ₃-vinylidene and µ-stannylene derivatives. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, V. Riera and M. Suárez, Organometallics, 2004, 23, 3501-3511.

120.    Activation of all bonds of a methyl group attached to an organic fragment. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río, L. Martínez-Méndez, D. Miguel and V. Riera, Angew. Chem. Int. Ed., 2004, 43, 3464-3467.

119.    Triruthenium, hexaruthenium, and triosmium carbonyl derivatives of 2-amino-6-phenylpyridine. (PDF)

         J.A. Cabeza, I. del Río, V. Riera, M. Suárez and S. García-Granda, Organometallics, 2004, 23, 1107-1115.

2003

118.    Di- and trinuclear ruthenium and osmium bis(2-pyridyl)ketone oximate derivatives. (PDF)

         J.A. Cabeza, I. del Río, V. Riera, M. Suárez, C. Alvarez-Rúa, S. García-Granda, S.H. Hsien and J. R. Hwu, Eur. J. Inorg. Chem., 2003, 4159-4165.

117.    Hexaruthenium cluster complexes of basal edge-bridged square pyramidal metallic skeleton. First efficient synthesis and reactivity studies. (PDF)

         J.A. Cabeza, I. del Río, P. García-Alvarez, V. Riera, M. Suárez and S. García-Granda, Dalton Trans., 2003, 2808-2809.

116.    Influence of the bridging ligand on the substitution chemistry of neutral and cationic triruthenium carbonyl cluster complexes derived from 1,1-dimethylhydrazine. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez and V. Riera, Inorg. Chim. Acta, 2003, 350, 93-100.

115.    Methylidyne-diyne coupling reactions onto a triruthenium cluster core. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río, S. García-Granda and V. Riera, Inorg. Chim. Acta, 2003, 347, 107-113.

114.    Reactivity of triosmium and triruthenium carbonyls with 2,2’-diamino-1,1’-binaphthalene. Synthesis of C- and N-metalated derivatives. (PDF)

         J.A. Cabeza, I. da Silva, I. del Río, S. García-Granda, V. Riera and M. G. Sánchez-Vega, Organometallics, 2003, 22, 1519-1525.

113.    Formation of a highly functionalized azulene ligand by metal cluster-mediated coupling of three conjugated diynes. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, L. Martínez- Méndez, M. Moreno and V. Riera, Organometallics, 2003, 22, 1164-1166.

2002

112.    Carbonyl substitution chemistry of neutral and cationic triruthenium cluster complexes derived from 1,1-dimethylhydrazine. Incorporation of two and three phosphane ligands. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, L. Martínez-Méndez and V. Riera, J. Organomet. Chem., 2002, 663, 227-234.

111.    Triruthenium and triosmium carbonyl cluster complexes containing bridging ligands derived from 2-amino-7,8-benzoquinoline. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, V. Riera and M. Suárez, Organometallics, 2002, 21, 5055-5059.

110.    Reactivity of a triruthenium ynenyl cluster complex with diynes: Cluster-mediated combination of up to three substituted butadiyne molecules into a carbon-rich hydrocarbyl ligand. (PDF)

         J.A. Cabeza, I. del Río, M. Moreno, S. García-Granda, M. Pérez-Priede and V. Riera, Eur. J. Inorg. Chem., 2002, 3204-3209.

109.    Facile S-C bond activation of levamisole hydrochloride on a triruthenium cluster core. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, V. Riera and M.G. Sánchez-Vega, Eur. J. Inorg. Chem., 2002, 2561-2564.

108.    Bis(µ-η²-bezene-1,2-dithiolato-κ³-S,S’:S’)bis[(η⁶-p-cymene)ruthenium(II)]. (PDF)

         J.A. Cabeza, S. García-Granda, M. Pérez-Priede and J.F. Van der Maelen, Acta Crystallogr., Sect. E, 2002, 58, m189-m190.

107.    Triruthenium and triosmium carbonyl cluster complexes containing deprotonated di-(2-pyridyl)amine in unusual coordination modes. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, V. Riera and M. Suárez, Organometallics, 2002, 21, 2540-2543.

106.    Benzophenone iminium tetrafluoroborate. (PDF)

         J.A. Cabeza, I. del Río, M. Suárez and S. García-Granda, Acta Crystallogr., Sect. E, 2002, 58, o429-o430.

2001

105.    Formation of a diynedienyl ligand by coupling of hexa-2,4-diyne and hex-2-yn-4-en-4-yl ligands onto a triruthenium cluster. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, M. Moreno and V. Riera, Organometallics, 2001, 20, 4973-4976.

104.    Reactivity of [Ru₃(µ₃-NPh)(µ₃-CO)(CO)₉] with activated alkynes and diynes. Isolation of a trinuclear intermediate during the formation of bi- and tetranuclear products. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, M. Moreno, V. Riera, M. J. Rosales-Hoz and M. Suárez, Eur. J. Inorg. Chem., 2001, 2899-2906.

103.    Reactivity of [Ru₂(µ-η¹:η¹-N=CPh₂)(µ-η¹:η²-PhC=CHPh)(CO)₆] with alkynes. Insertion reactions of internal and terminal non-activated alkynes into Ru-C and Ru-N bonds. (PDF)

         J.A. Cabeza, I. del Río, F. Grepioni, M. Moreno, V. Riera and M. Suárez, Organometallics, 2001, 20, 4190-4197.

102.    (Tert-Butylisocyanide)tetracarbonyl[N-(1,2,3,4-tetraphenylbutadienyl)benzophenone imine]diruthenium. (PDF)

         S. García-Granda, M. Pérez-Priede, J.F. Van der Maelen and J.A. Cabeza, Acta Crystallogr., Sect. E, 2001, 57, m174-m175.

101.    (Benzylamine-N)(η⁵-cyclopentadienyl)bis(triphenylphosphine-P)ruthenium(II) tetrafluoroborate. (PDF)

         J.A. Cabeza, I. del Río, M.E. Navarro and S. García-Granda, Acta Crystallogr., Sect. E, 2001, 57, m162-m163.

100.    Formation of cyclopentadienyl and ruthenacyclopentadienyl derivatives through ynenyl-diyne and ynenyl-alkyne couplings onto a triruthenium cluster core. (PDF)

         J.A. Cabeza, I. del Río, S. García-Granda, G. Lavigne, N. Lugan, M. Moreno, P. Nombel, M. Pérez-Priede, V. Riera, A. Rodríguez, M. Suárez and J.F. Van der Maelen, Chem. Eur. J., 2001, 7, 2370-2381.

99.      (Benzophenoneimine-N)nonacarbonyldirhenium(0) (Re-Re). (PDF)

         J.A. Cabeza, I. del Río, N. Zúñiga-Villarreal and S. García-Granda, Acta Crystallogr., Sect. E, 2001, 57, m130-m131.

98.      Reactivity of [Ru₃(µ-H)(µ-Me₂pz)(CO)₁₀] with 2,4-hexadiyne. Characterization of the first tetranuclear ynenyl complex. (PDF)

         J.A. Cabeza, M. Moreno, V. Riera and M.J. Rosales-Hoz, Inorg. Chem. Commun. 2001, 4, 57-59.

2000

97.      Reactivity of diynes with a 1-azavinylidene-bridged triruthenium carbonyl cluster. Insertion reactions of diynes into Ru-H, Ru-C and Ru-N bonds. (PDF)

         J.A. Cabeza, F. Grepioni, M. Moreno and V. Riera, Organometallics, 2000, 19, 5424-5430.

96.      Approaches to triosmium carbonyl cluster compounds derived from benzophenone imine. Characterization of terminal imino, bridging amido and orthometalated imino derivatives. (PDF)

         J.A. Cabeza, I. del Río, F. Grepioni and V. Riera, Organometallics, 2000, 19, 4643-4646.

95.      Reactivity of triosmium carbonyl clusters with 1,8-diaminophthalene. Synthesis and structural characterization of amido, diamido and C-metalated trinuclear derivatives. (PDF)

         J.A. Cabeza, H. Noth, M.J. Rosales-Hoz and G. Sánchez-Cabrera, Eur. J. Inorg. Chem., 2000, 2327-2332.

94.      Reactivity of the anionic trirhenium carbonyl cluster [Re₃(µ-H)₃(µ₃-ampy)(CO)₉]^-. Synthesis of neutral phosphane and alkenyl derivatives.(PDF)

         J.A. Cabeza, F. Grepioni, A. Llamazares,V. Riera and R. Trivedi, Eur. J. Inorg. Chem., 2000, 1693-1697.

93.      Reactivity of [Re₃(µ-H)₃(µ₃-ampy)(CO)₉]^-. Preparation of heteronuclear Re₃Au carbonyl cluster complexes containing face-capping and edge-bridging gold atoms. (PDF)

         J.A. Cabeza, V. Riera, R. Trivedi and F. Grepioni, Organometallics, 2000, 19, 2043-2046.

92.      Reactivity of 2-(diphenylphosphanyl)thiophenol (HSC₆H₄PPh₂) with ruthenium and osmium carbonyl complexes. Breaking of HSC₆H₄PPh₂ into sulfide, phenyl and diphenylphosphanyl ligands on a triruthenium cluster. (PDF)

         J.A. Cabeza, M.A. Martínez-García, V. Riera, D. Ardura and S. García-Granda, Eur. J. Inorg. Chem., 2000, 499-503.

1999

91.      Derivative chemistry of [Ru₂(µ-bdt)(CO)₆], a binuclear ruthenium(I) carbonyl complex containing a bridging benzene-1,2-dithiolate ligand.(PDF)

         J.A. Cabeza, M.A. Martínez-García, V. Riera, D. Ardura, S. García-Granda and J.F. Van der Maelen, Eur. J. Inorg. Chem., 1999, 1133-1139.

1998

90.      Neutral binuclear and anionic trinuclear rhenium carbonyl complexes containing bridging ligands derived from 2-amino- and 2-mercaptopyridines. (PDF)

           J.A. Cabeza, A. Llamazares, V. Riera, R. Trivedi, and F. Grepioni, Organometallics, 1998, 17, 5580-5585.

89.      Advances in the reactivity of amido-bridged binuclear ruthenium carbonyl complexes. Derivative chemistry of the cationic complex [Ru₂(µ-dan)(µ-H)(CO)₆][BF₄] (H₂dan = 1,8-diaminonaphthalene).(PDF)

         J.A. Cabeza, J. García-Díez and V. Riera, Eur. J. Inorg. Chem., 1998, 1729-1732.

88.      Reactivity of the 1-azavinylidene cluster [Ru₃(µ-H)(µ-N=CPh₂)(CO)₁₀] with hydrogen, tertiary silanes and tertiary stannanes. (PDF)

           C. Bois, J.A. Cabeza, R.J. Franco, V. Riera and E. Saborit, J. Organomet. Chem., 1998, 564, 201-207.

87.      Reactivity of a 1-azavinylidene-bridged triruthenium carbonyl cluster with alkynes. Synthesis of binuclear derivatives containing new C-H or C-N and C-C bonds formed by alkyne insertion into M-H or M-N and M–C bonds. (PDF)

           J.A. Cabeza, I. del Río, M. Moreno, V. Riera and F. Grepioni, Organometallics, 1998, 17, 3027-3033.

86.      Binuclear iron(I), ruthenium(I), and osmium(I) hexacarbonyl complexes containing a bridging benzene-1,2-dithiolate ligand. Synthesis, X-ray structures, protonation reactions, and EHMO calculations. (PDF)

           J.A. Cabeza, M.A. Martínez-García, V. Riera, D. Ardura and S. García-Granda, Organometallics, 1998, 17, 1471-1477.

85.      Protonation of triruthenium carbonyl cluster complexes containing a bridging 1-azavinylidene ligand. Experimental results and EHMO calculations. (PDF)

           J.A. Cabeza, I. del Río, V. Riera and D. Ardura, J. Organomet. Chem., 1998, 554, 117-121.

84.      Reactivity studies on cationic non-hydridic triruthenium carbonyl clusters. Reactions of [Ru₃(µ₃-ampy)(CO)₁₀][BF₄] with hydrogen, triethylsilane and triphenylstannane. (PDF)

           J.A. Cabeza, I. del Río and V. Riera, Inorg. Chim. Acta, 1998, 268, 131-133.

1997

83.      Neutral and cationic diphenylphosphine and diphenylphosphido derivatives of a trinuclear ruthenium carbonyl cluster containing a bridging 1-azavinylidene ligand. (PDF)

           J.A. Cabeza, I. del Río and V. Riera, J. Organomet. Chem., 1997, 548, 255-261.

82.      Carbonyl metal clusters with mixed O,N-donor ligands: Reactivity of the ureato cluster [Ru₃(µ-H)(µ₃-HNCONMe₂)(CO)₉] with phosphines. Structural characterization of a triphenylphosphine derivative and of a bis(diphenylphosphido) derivative which also contains a bridging h1-phenyl ligand. (PDF)

           J.A. Cabeza, I. del Río, V. Riera, S. García-Granda and S.B. Sanni, Organometallics, 1997, 16, 3914-3920.

81.      Reactivity of a 1-azavinylidene ligand with diphenylacetylene on a ruthenium carbonyl cluster. A remarkable alkyne insertion into a metal-nitrogen bond. (PDF)

           J.A. Cabeza, I. del Río, R.J. Franco, F. Grepioni and V. Riera, Organometallics, 1997, 16, 2763-2764.

80.      Reversible thermal activation of a triphenylphosphine P-C bond on a cationic non-hydridic triruthenium carbonyl cluster complex. Structural characterization of a µ-η¹:η²-benzoyl derivative. (PDF)

           J.A. Cabeza, I. del Río, V. Riera, S. García-Granda and S.B. Sanni, Organometallics, 1997, 16, 1743-1748.

79.      Reactivity of a cationic non-hydridic triruthenium carbonyl cluster complex with anionic reagents. Synthesis of new tri- and hexanuclear derivatives. (PDF)

           J.A. Cabeza, I. del Río, V. Riera and F. Grepioni, Organometallics, 1997, 16, 812-815.

78.      Pyrazolate-bridged ruthenium(I) carbonyl complexes.

           J.A. Cabeza and L.A. Oro, Inorg. Synth., 1997, 31, 217-220.

1996

77.      Triosmium carbonyl complexes containing bridging ligands derived from ortho-functionalized anilines. (PDF)

           J.A. Cabeza, M.A. Martínez-García, V. Riera, S. García-Granda and D. Ardura, J. Organomet. Chem., 1996, 525, 133-138.

76.      Synthesis and reactivity of triruthenium carbonyl cluster complexes containing a bridging 1-azavinylidene ligand derived from benzophenone imine. (PDF)

           P.L. Andreu, J.A. Cabeza, I. del Río, V. Riera and C. Bois, Organometallics, 1996, 15, 3004-3010.

75.      Neutral and anionic pyrazolyl-bridged triruthenium carbonyl cluster complexes. Reactions with bis(diphenylphosphino)methane, triphenylphosphine and diphenylphosphine. (PDF)

           J.A. Cabeza, I. del Río and V. Riera, J. Organomet. Chem., 1996, 523, 127-131.

74.      Tri- and binuclear ruthenium carbonyl complexes containing bridging ligands derived from ortho-substituted anilines. A comparative study of their syntheses using RuCl₃.H₂O or [Ru₃(CO)₁₂] as starting materials.

           J.A. Cabeza, M.A. Martínez-García, V. Riera, S. García-Granda and J.F. Van der Maelen, J. Organomet. Chem., 1996, 514, 197-202.

73.      Reactivity of a cationic hydrido-alkenyl carbonyl cluster complex toward nucleophilic reagents. Carbonyl substitution versus alkene elimination reactions. (PDF)

           J.A. Cabeza, I. del Río, A. Llamazares and V. Riera, J. Organomet. Chem., 1996, 511, 103-109.

72.      Homogeneous hydrogenation of diphenylacetylene promoted by a cationic hydridoalkenyltriruthenium cluster complex. Kinetic evidence for cluster catalysis. (PDF)

           J.A. Cabeza, I. del Río, J.M. Fernández-Colinas and V. Riera, Organometallics, 1996, 15, 449-451.

1995

71.      Alkyne, triorganosilyl, and triorganostannyl derivatives of anionic triruthenium carbonyl cluster complexes containing bridging pyrazolyl ligands. (PDF)

           J.A. Cabeza, R.J. Franco, V. Riera, S. García-Granda and J.F. Van der Maelen, Organometallics, 1995, 14, 3342-3348.

70.      Derivative chemistry of cationic triruthenium carbonyl cluster compounds. Reactions leading to a neutral hexanuclear complex consisting of two vertex-linked metal triangles. (PDF)

           J.A. Cabeza, I. del Río, V. Riera and F. Grepioni, Organometallics, 1995, 14, 3124-3126.

69.      IR studies and hydrogenation catalytic activity of heterogeneous catalysts prepared by thermal treatments of a face-bridged triruthenium carbonyl cluster supported on silica and alumina.

           J.A. Cabeza, J.M. Fernández-Colinas, A. Choplin and A. Theolier, Inorg. Chim. Acta, 1995, 237, 103-109.

68.      Synthesis, characterization, reactivity, and hydrogenation catalytic activity of the hexanuclear hexahydrido carbonyl cluster compound [Ru₆(µ-H)₆(µ₃,η²-ampy)₂(CO)₁₄] (Hampy = 2-amino-6-methylpyridine). (PDF)

           J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, A. Llamazares and V. Riera, J. Organomet. Chem., 1995, 494, 169-177.

67.      Cationic trinuclear 48-electron ruthenium carbonyl cluster complexes containing no hydride ligands. (PDF)

           J.A. Cabeza, I. del Río, A. Llamazares, V. Riera, S. García-Granda and J.F. Van der Maelen, Inorg. Chem., 1995, 34, 1620-1623.

1994

66.      Organosilicon and organotin derivatives of triruthenium carbonyl cluster complexes.

           J.A. Cabeza, R.J. Franco and A. Llamazares, en Trends in Organometallic Chemistry; J. Menon (Ed.), Council of Scientific Research Int., Trivandrum, India, 1994, vol 1, p 29.

65.      Tricyclohexylphosphine- versus triphenylphosphine-substituted derivatives of a face-bridged triruthenium carbonyl cluster complex. A comparative study of their synthesis, structure, and catalytic activity in the homogeneous hydrogenation of diphenylacetylene. (PDF)

           S. Alvarez, P. Briard, J.A. Cabeza, I. del Río, J.M. Fernández-Colinas, F. Mulla, L. Ouahab and V. Riera, Organometallics, 1994, 13, 4360-4366.

64.      Reactivity of [PPN][Ru₃(µ-NO)(CO)₁₀] with tertiary silanes and stannanes. (PDF)

           J.A. Cabeza, R.J. Franco and V. Riera, Inorg. Chem., 1994, 33, 5952-5954.

63.      Crystal structure of [RuCl₂(PH₂Cy)(η⁶-p-cymene)]. (PDF)

           J.F. Van der Maelen, S. García-Granda, J.A. Cabeza and I. del Río, Acta Crystallogr., Sect. C, 1994, 50, 1064-1065.

62.      Carbonyl clusters as homogeneous catalysts. Kinetic and molecular aspects of the hydrogenation of diphenylacetylene promoted by an alkenyl-bridged triruthenium cluster complex.(PDFa) (PDFb)

           J.A. Cabeza, J.M. Fernández-Colinas, A. Llamazares, V. Riera, S. García-Granda and J.F. Van der Maelen, Organometallics, 1994, 13, 4352-4359; Organometallics, 1995, 14, 3120.

61.      Synthesis, structure and hydrogenation catalytic activity of [Ru₃(µ₃,η²-ampy)(µ,η¹:η²-PhC=CHPh)(CO)₆(PPh₃)₂] (Hampy = 2-amino-6-methylpyridine).

           J.A. Cabeza, A. Llamazares, V. Riera, P. Briard and L. Ouahab J. Organomet. Chem., 1994, 480, 205-212.

60.      Synthesis and derivative chemistry of [Ru₂(µ-PPh₂)(µ-OH)₂(η⁶-p-cymene)₂]⁺.

           J.A. Cabeza, F. Mulla and V. Riera, J. Organomet. Chem., 1994, 470, 173-177.

59.      Preparation and characterization of 92-electron hexahydridohexaruthenium carbonyl cluster complexes. Their potential significance in homogeneous catalytic hydrogenation. (PDF)

           J.A. Cabeza, J.M. Fernández-Colinas, S. García-Granda, A. Llamazares, F. López-Ortiz, V. Riera and J.F. Van der Maelen, Organometallics, 1994, 13, 426-428.

58.      h¹-Aryl-bridged triruthenium cluster complexes.(PDF)

           J.A. Cabeza, R.J. Franco, A. Llamazares, V. Riera, E. Pérez-Carreño and J.F. Van der Maelen, Organometallics, 1994, 13, 55-59.

1993

57.      Structure of µ-[bis(chloroacetato-O)-mercury(II)-κ²Hg]-µ-[1,8-naphthalene-diamido-κ²NN’:κ²NN’]-bis[cis-dicarbonyl(triisopropylphosphine-P)ruthenium(I)] (Ru-Ru). (PDF)

           S. García-Granda, J.F. Van der Maelen, J.A. Cabeza, J.M. Fernández-Colinas and V. Riera, Acta Crystallogr., Sect. C, 1993, 49, 1483-1485.

56.      Molecular clusters in homogeneous catalysis: kinetic and chemical evidence for the participation of triruthenium cluster complexes in a cluster-promoted hydrogenation of diphenylacetylene. (PDF)

           J.A. Cabeza, J.M. Fernández-Colinas, A. Llamazares and V. Riera, Organometallics, 1993, 12, 4141-4144.

55.      Reactivity of tertiary silanes and stannanes with an edge-bridged triruthenium carbonyl cluster complex. (PDF)

           J.A. Cabeza, R.J. Franco, A. Llamazares, V. Riera, C. Bois and Y. Jeannin, Inorg. Chem., 1993, 32, 4640-4642.

54.      Incorporation of silanes and diphenylacetylene into face-bridged triruthenium carbonyl clusters. Attempted hydrosilylation of diphenylacetylene. (PDF)

           J.A. Cabeza, S. García-Granda, A. Llamazares, V. Riera and J.F. Van der Maelen, Organometallics, 1993, 12, 2973-2979.

53.      Synthesis and structural characterization of triruthenium cluster complexes containing bridging η¹-phenyl and terminal η¹-phenyl ligands arising from the cleavage of triphenylphosphine ligands. (PDF)

           P. Briard, J.A. Cabeza, A. Llamazares, L. Ouahab and V. Riera, Organometallics, 1993, 12, 1006-1008.

52.      Reactivity of a face-bridged trinuclear ruthenium carbonyl cluster with diphenylacetylene and triorganotin hydrides. Attempted hydrostannation of diphenylacetylene. (PDF)

           J.A. Cabeza, S. García-Granda, A. Llamazares, V. Riera and J.F. Van der Maelen, Organometallics, 1993, 12, 157-164.

1992

51.      Kinetic and chemical evidence for the participation of mononuclear catalytic species in the homogeneous hydrogenation of diphenylacetylene promoted by an edge-bridged triruthenium carbonyl cluster complex.(PDF)

           J.A. Cabeza, J.M. Fernández-Colinas, A. Llamazares and V. Riera, Organometallics, 1992, 11, 4355-4358.

50.      Synthesis and reactivity of dithiodiphenylphosphinato derivatives of rhodium. Crystal structure of the square-pyramidal rhodium(III) complex [RhI(η²-S₂PPh₂)(COMe)(PPh₃)].

           J.A. Cabeza, V. Riera, M.A. Villa-García, L. Ouahab and S. Triki, J. Organomet. Chem., 1992, 441, 323-331.

49.      Incorporation of trialkylsilyl and trialkylstannyl groups into ruthenium carbonyl clusters. Carbonyl substitution versus trialkylsilane or trialkylstannane elimination in these clusters. (PDF)

           J.A. Cabeza, A. Llamazares, V. Riera, S. Triki and L. Ouahab, Organometallics, 1992, 11, 3334-3339.

48.      Cationic and neutral 50-electron triruthenium carbonyl clusters containing three bridging diphenylphosphido ligands. (PDF)

           J.A. Cabeza, F.J. Lahoz and A. Martín, Organometallics, 1992, 11, 2754-2756.

47.      Mercury-bridged transition-metal clusters. Synthesis of pentanuclear Ru₃HgM (M = Mo, W, or Co) clusters and X-ray structure of [{Ru₃(µ₃,η²-ampy)(CO)₉}(µ₃-Hg)Co(CO)₄] (Hampy = 2-amino-6-methylpyridine).

           P.L. Andreu, J.A. Cabeza, A. Llamazares, V. Riera, S. García-Granda and J.F. Van der Maelen, J. Organomet. Chem., 1992, 434, 123-132.

46.      Synthesis and reactivity of triruthenium carbonyl clusters containing bis(diphenylphosphino)methane and the face-bridging ligand 2-amido-6-methylpyridine.

           P.L. Andreu, J.A. Cabeza, J.L. Cuyás and V. Riera, J. Organomet. Chem., 1992, 427, 363-368.

45.      The hydrogenation activity of [Ru₃(µ-H)(µ₃-ampy)(CO)₉] under homogeneous conditions (Hampy = 2-amino-6-methylpyridine).

           J.A. Cabeza, J.M. Fernández-Colinas, A. Llamazares and V. Riera, J. Mol. Catal., 1992, 71,  L7-L11.

44.      Addition of mercury(II) electrophiles to [Ru₂(C₁₀H₈N₂)(CO)₄(PⁱPr₃)₂] and selective insertion versus addition in the reactions of mercury(II) electrophiles with trinuclear Ru₂Hg clusters. X-Ray structures of [Ru₂Hg(O₂CCF₃)₂(C₁₀H₈N₂)(CO)₄(PⁱPr₃)₂] and [Ru₂Hg₂Cl₄(C₁₀H₈N₂)(CO)₄(PⁱPr₃)₂]·CH₂Cl₂ (C₁₀H₁₀N₂ = 1,8-diaminonaphthalene). (PDF)

           J.A. Cabeza, J.M. Fernández-Colinas, S. García-Granda, V. Riera and J.F. Van der Maelen, Inorg. Chem., 1992, 31, 1233-1238.

1991

43.      The chemical and electrochemical oxidation of pyridonate-bridged ruthenium(I) dimers. X-Ray structure of [Ru₂(µ-pyO)₂(CO)₄(pyOH)₂] (pyOH = 2-pyridone).

           P.L. Andreu, J.A. Cabeza, G.A. Carriedo, V. Riera, S. García-Granda, J.F. Van der Maelen and G. Mori, J. Organomet. Chem., 1991, 421, 305-314.

42.      Mercury-ruthenium mixed-metal carbonyl clusters containing 2-amido-6-methylpyridine (ampy) as a µ₃,η²-ligand. Crystal structures of [Ru₆(µ₄-Hg)(µ₃-ampy)₂(CO)₁₈].2C₄H₈O and [Ru₃(µ-HgBr)(µ₃-ampy)(CO)₉].

           P.L. Andreu, J.A. Cabeza, A. Llamazares, V. Riera, C. Bois and Y. Jeannin, J. Organomet. Chem., 1991, 420, 431-442.

41.      Extensive substitution, protonation and methoxidation reactions of triruthenium carbonyl clusters containing 2-amino-6-methylpyridinato (µ₃-ampy) as a face-bridging ligand. X-Ray structures of [Ru₃(µ-H)(µ₃-ampy)(CO)₇(PPh₃)₂] and [Ru₃(µ-H)₂(µ₃-ampy)(CO₂Me)(CO)₆(PPh₃)₂].MeOH. (PDF)

           P.L. Andreu, J.A. Cabeza, M.A. Pellinghelli, V. Riera and A. Tiripicchio, Inorg. Chem., 1991, 30, 4611-4616.

40.      Synthesis and reactivity of diphenylphosphine derivatives of [Ru₃(µ-H)(µ₃-ampy)(CO)₉] and [Ru₃(µ-H)₂(µ₃-ampy)(CO)₉][BF₄] (Hampy = 2-amino-6-methylpyridine).

           P.L. Andreu, J.A. Cabeza and V. Riera, Inorg. Chim. Acta,  1991, 186, 225-230.

39.      The addition of protons and metallic electrophiles to the electron-rich Ru-Ru bond of [Ru₂(µ-dan)(CO)₄(PⁱPr₃)₂]. X-Ray structure of [Ru₂(µ-AgPPh₃)(µ-dan)(CO)₄(PⁱPr₃)₂][BF₄].CH₂Cl₂ (H₂dan = 1,8-diaminonaphthalene).

           J.A. Cabeza, J.M. Fernández-Colinas, V. Riera, S. García-Granda and J.F. Van der Maelen, Inorg. Chim. Acta,  1991, 185, 187-192.

38.      Selective insertion of mercury(II) halides into the Ru-Hg bonds of trinuclear Ru₂Hg clusters.

           J.A. Cabeza, J.M. Fernández-Colinas, S. García-Granda, V. Riera and J.F. Van der Maelen, J. Chem. Soc., Chem. Commun.,  1991, 168-170.

37.      Improved synthesis, solution and solid state structure, and reactivity of [Ru₂(µ-SePh)₂(CO)₆].

           P.L. Andreu, J.A. Cabeza, D. Miguel, V. Riera, M.A. Villa and S. García-Granda,  J. Chem. Soc., Dalton Trans.,  1991, 533-536.

36.      Synthesis and reactions with electrophiles and nucleophiles of the ruthenium(I) complex [Ru₂(µ-C₁₀H₈N₂)(CO)₆]. Crystal structure of [Ru₂(µ-C₁₀H₈N₂)(CO)₄{P(OPh)₃}₂] (C₁₀H₁₀N₂ = 1,8-diaminonaphthalene).

           J.A. Cabeza, J.M. Fernández-Colinas, V. Riera, M.A. Pellinghelli and A. Tiripicchio, J. Chem. Soc., Dalton Trans.,  1991, 371-377.

1990

35.      Protonation and deprotonation reactions of triruthenium nona- and octa-carbonyl clusters containing a µ₃-2-amido-6-methylpyridine (µ₃-ampy) ligand. X-ray structures of [Ru₃(µ-H)₂(µ₃-ampy)(CO)₉][BF₄] and of one of the two isolated isomers of [Ru₃(µ-H)₂(µ₃-ampy)(CO)₈(PPh₃)][BF₄].

           P.L. Andreu, J.A. Cabeza, V. Riera, C. Bois and Y. Jeannin, J. Chem. Soc., Dalton. Trans., 1990, 3347-3353.

34.      Synthesis and reactivity of mono-, tri- and polynuclear ruthenium carbonyl complexes containing the pyridine-2-thiolate ligand (pyS). Stepwise preparation of [Ru(pyS)₂(CO)₂] by reaction of [Ru₃(CO)₁₂] with pyridine-2-thiol. (PDF)

           P.L. Andreu, J.A. Cabeza, J.M. Fernández-Colinas and V. Riera, J. Chem. Soc., Dalton Trans., 1990, 2927-2930.

33.      Diphenylphosphine and diphenylphosphido derivatives of [Ru₃(µ-H)(µ₃-ampy)(CO)₉] (Hampy = 2-amino-6-methylpyridine).

           P.L. Andreu, J.A. Cabeza and V. Riera, J. Organomet. Chem., 1990, 393, C30-C33.

32.      Reactions of [Ru₂{µ-1,2-(NH)₂C₆H₄}(CO)₄(PPh₃)₂] with H⁺, NO⁺ and group-11 metal fragments. Syntheses of trinuclear Ru₂M (M = Cu, Ag, Au) and pentanuclear Ru₄Au clusters.

           A. Anillo, J.A. Cabeza, R. Obeso-Rosete and V. Riera, J. Organomet. Chem., 1990, 393, 423-429.

31.      The different reactivity of 2-aminopyridines and 2-pyridone with [Ru₃(CO)₁₂]. X-Ray crystal structure of [Ru₃(µ-H)(µ₃-anpy)(CO)₉] (Hanpy = 2-anilinopyridine).

           P.L. Andreu, J.A. Cabeza, V. Riera, Y. Jeannin and D. Miguel, J. Chem. Soc., Dalton Trans., 1990, 2201-2206.

30.      Selective carbonyl substitution reactions on [Ru₃(µ-H)(µ₃-ampy)(CO)₉] and on its protonated derivative. Crystal structure of [Ru₃(µ-H)₂(µ₃-ampy)(CO)₉][BF₄] (Hampy = 2-amino-6-methylpyridine).

           P.L. Andreu, J.A. Cabeza, V. Riera, C. Bois and Y. Jeannin, J. Organomet. Chem., 1990, 384, C25-C28.

29.      Nuclear magnetic resonance evidence for three different isomers of [Ru₃(µ-H)(µ-bzim)(CO)₉(PPh₃)] (bzim = benzimidazolate). Crystal structure of [Ru₃(µ-H)(µ-bzim)(CO)₁₀].Me₂CO.

           M.A. Pellinghelli, A. Tiripicchio, J.A. Cabeza and L.A. Oro, J. Chem. Soc., Dalton Trans.,  1990, 1509-1512.

28.      The thermal and photochemical reactions of [Ru₃(CO)₁₂] with tetraethyldiphosphite. X-Ray structure of [Ru₃(CO)₁₀{µ-(EtO)₂POP(OEt)₂}].

           J.A. Cabeza, V. Riera, Y. Jeannin and D. Miguel, Inorg. Chim. Acta, 1990, 168, 77-82.

1989

27.      µ-Amido complexes of ruthenium carbonyl. Asymmetric versus symmetric bridging preference of the monodeprotonated derivatives of 1,2-arenediamines. Crystal structure of [Ru₃(µ-H)(µ-H₃N₂-4,5-Me-1,2-phenylene)(CO)₉].

           J.A. Cabeza, V. Riera, M.A. Pellinghelli and A. Tiripicchio, J. Organomet. Chem., 1989, 376, C23-C25.

26.      Liquid crystal derivatives of transition metals (I): tetracoordinated copper(II) complexes derived from Schiffs bases.

           M. Marcos, P. Romero, J.L. Serrano, C. Bueno, J.A. Cabeza and L. A. Oro, Mol. Cryst. Liq. Cryst., 1989, 167, 123-134.

25.      [Ru₃(CO)₉(PPh₃)₃]: A convenient starting material for the synthesis of binuclear ruthenium(I) complexes. Crystal structure of [Ru₂(µ-L₂)(CO)₄(PPh₃)₂] (H₂L₂ = 1,8-diaminonaphthalene).

           P.L. Andreu, J.A. Cabeza, V. Riera, F. Robert and Y. Jeannin, J. Organomet. Chem., 1989, 372, C15-C18.

24.      Synthesis and reactivity of binuclear pyrazolate-bridged ruthenium(I) complexes. Crystal structures of bis[µ-(3,5-dimethylpyrazolato-NN')tricarbonyl-ruthenium(I)] (Ru-Ru) and bis[µ-(3,5-dimethylpyrazolato-NN')]-µ-iodo-bis[tricarbonylruthenium(II)] tri-iodide.

           J.A. Cabeza, C. Landázuri, L.A. Oro, D. Belletti, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Dalton Trans., 1989, 1093-1100.

1988

23.      Homogeneous hydrogenation of tetrasubstituted alkene moieties in prochiral didehydro aminoacid derivatives catalysed by iridium complexes.

           J.A. Cabeza, C. Cativela, M.D. Díaz de Villegas and L.A. Oro, J. Chem. Soc., Perkin Trans., I, 1988, 1881-1884.

22.      The reactions of [Ru₃(CO)₁₂] with nitrogen-containing heterocycles. Crystal structures of [Ru₃(µ-H)(µ₃-ppy)(CO)₉] and [Ru₃(µ-napy)(µ-CO)₃(CO)₇].

           J.A. Cabeza, L.A. Oro, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Dalton Trans., 1988, 1437-1444.

21.      The synthesis of di- and tetra-nuclear p-cymene-osmium hydride complexes; characterization by ¹H{¹⁸⁷Os} reverse INEPT two-dimensional n.m.r. spectroscopy.

           J.A. Cabeza, B.E. Mann, P.M. Maitlis and C. Brevard, J. Chem. Soc., Dalton Trans., 1988, 629-634.

1987

20.      The reactions of dichloro-bis(µ-chloro)-bis(η⁶-p-cymene)diosmium(II) and diruthenium(II) with hexamethyldialuminium.

           J.A. Cabeza, B.F. Taylor and P.M. Maitlis, Inorg. Chim. Acta, 1987, 133, 67-70.

19.      Pyrazolate bridged ruthenium(I) complexes. A convenient synthesis of ruthenium(I) compounds. The X-ray structure of bis(µ-3,5-dimethylpyrazolate)-bis(tricarbonylruthenium(I)) (Ru-Ru).

           J.A. Cabeza, C. Landázuri, L.A. Oro, A. Tiripicchio and M. Tiripicchio-Camellini, J. Organomet. Chem., 1987, 322, C16-C20.

18.      The cyclometallation of benzoic acid to give rhodium, iridium and osmium C,O-benzoates. X-Ray structure determination of the dibenzoate [(C₅Me₅)Rh(OOCPh)₂(H₂O)].

           J.M. Kisenyi, G.J. Sunley, J.A. Cabeza, A.J. Smith, H. Adams. N.J. Salt and P.M. Maitlis, J. Chem. Soc., Dalton Trans., 1987, 2459-2466.

1986

17.      Dicationic tetranuclear tetrahydrides of iridium, ruthenium and osmium. (PDF)

           J.A. Cabeza, A. Newton, B.E. Mann, C. Brevard and P.M. Maitlis, Inorg. Chim Acta., 1986, 115, L47-L48.

16.      The reactions of the tri-µ-hydroxo-bis[η⁶-p-cymeneosmium(II)] cation with aldehydes and acids and the homogeneously catalysed oxidation of acetaldehyde and propionaldehyde with water. X-Ray structure of [(p-MeC₆H₄CHMe₂)₂Os₂(µ-HCO₂)(µ-OH)(µ-H)][PF₆].

           J.A. Cabeza, A.J. Smith, H. Adams and P.M. Maitlis, J. Chem. Soc., Dalton Trans.,  1986, 1155-1160.

15.      The X-ray molecular structure of (η⁶-p-cymene)(dimethylsulphoxide-S) dicloroosmium(II).

           J.A. Cabeza, H. Adams and A.J. Smith, Inorg. Chim. Acta, 1986, 114, L17-L18.

1985

14.      The cyclometallation of benzoic acid and the X-ray crystal structure of [C₅Me₅Ir(O₂CC₆H₄)(Me₂SO)].

           J.M. Kisenyi, J.A. Cabeza, A.J. Smith, H. Adams, G.J. Sunley, N.J.S. Salt and P.M. Maitlis, J. Chem. Soc., Chem. Commun., 1985, 770-771.

13.      Dinuclear methoxy, cyclooctadiene and barrelene complexes of rhodium(I) and iridium(I).

           R. Usón, L.A. Oro and J.A. Cabeza, Inorg. Synth., 1985, 23, 126-130.

12.      Dinuclear p-cymeneosmium hydride complexes; the measurement of ¹⁸⁷Os chemical shifts using ¹H-{¹⁸⁷Os} two-dimensional N.M.R. spectroscopy.

           J.A. Cabeza, B.E. Mann, C. Brevard and P.M. Maitlis, J. Chem. Soc., Chem. Commun., 1985, 65-67.

11.      Mononuclear η⁶-p-cymeneosmium(II) complexes and their reactions with Al₂Me₆ and other methylating reagents.

           J.A. Cabeza and P.M. Maitlis, J. Chem. Soc., Dalton Trans., 1985, 573-578.

1984

10.      Rhodium(I) and rhodium(III) arene complexes with N-carbazolyltriphenylphos-phinegold(I) and other polycyclic arene ligands.

           R. Usón, L.A. Oro and J.A. Cabeza, Polyhedron, 1984, 3, 497-501.

1983

   9.     Iridium-catalysed homogeneous hydrogenation of prochiral enamides containing tetrasubstituted alkene moieties.

           L.A. Oro, J.A. Cabeza, C. Cativiela, M.D. Díaz de Villegas and E. Meléndez, J. Chem. Soc., Chem. Commun., 1983, 1383-1384.

   8.     Biimidazole (H₂bim) and bibenzimidazole η³-allylic complexes of palladium(II). Mono- and tetranuclear palladium(II) and heteronuclear palladium(II)-rhodium(I) complexes. Crystal structure of [Pd₄(η³-C₃H₅)₄(µ-bim)₂].CH₂Cl₂.

           R. Usón. J. Gimeno, L.A. Oro, J.M. Martínez de Ilarduya, J.A. Cabeza, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Dalton Trans., 1983, 1729-1737.

   7.     Synthesis and reactivity of mono- and heteronuclear rhodium(I) or iridium(I) complexes with 2-(2'-pyridyl)benzimidazole.

           R. Usón, L.A. Oro and J.A. Cabeza, J. Organomet. Chem., 1983, 247, 105-116.

   6.     2,2'-Bibenzimidazolate anions as bridging ligands in cationic heteronuclear gold(I)-rhodium(I) complexes. Crystal structure of [(PPh₃)₂Au₂(µ-bbzim)Rh(cod)]ClO₄.CHCl₃.

           R. Usón, L.A. Oro, J. Gimeno, M.A. Ciriano, J.A. Cabeza, A. Tiripicchio and M. Tiripicchio-Camellini, J. Chem. Soc., Dalton Trans., 1983, 323-330.

   5.     Rhodium(I) and iridium(I) π-arene complexes of indole and of N-indolylgold(I) derivatives. X-Ray structure of [(Me₃TFB)Rh(η⁶-HInd)]ClO₄.

           R. Usón, L.A. Oro, J.A. Cabeza, C. Foces-Foces, F.H. Cano and S. García-Blanco, J. Organomet. Chem., 1983, 246, 73-81.

   4.     New biimidazole and bibenzimidazole derivatives: mono and binuclear palladium(II) or platinum(II) complexes and heterobinuclear palladium(II)-rhodium(I) or platinum(II)-rhodium(I) complexes.

           R. Usón, J. Gimeno, L.A. Oro, M.A. Aznar and J.A. Cabeza, Polyhedron, 1983, 2, 163-166.

   3.     N-Indolyltriarylphosphinegold(I) derivatives as η⁶-ligands in pentamethylcyclopentadienylrhodium(III) complexes. X-Ray structure of [(C₅Me₅)Rh(µ-Ind)AuP(C₆H₅)₃](ClO₄)₂.CH₂Cl₂.

           A. Tiripicchio, M. Tiripicchio-Camellini, R. Usón, L.A. Oro and J.A. Cabeza, J. Organomet. Chem., 1983, 244, 165-174.

1982

   2.     Indolylgold(I) derivatives and indole as π-arene ligands in cationic rhodium(I) complexes.

           R. Usón, L.A. Oro, J.A. Cabeza and M. Valderrama, J. Organomet. Chem., 1982, 231, C81-C83.

1981

   1.     Gold(I) and platinum(II) azolates as ligands in cationic rhodium(I) complexes. (PDF)

           R. Usón, L.A. Oro, M.A. Ciriano, M.T. Pinillos and J.A. Cabeza, J. Organomet. Chem., 1981, 221, 249-255.

Book Chapters

   3.     Homogeneous catalysis with ruthenium carbonyl cluster complexes: hydrogenation of alkynes. (PDF)

           J.A. Cabeza, in Metal Clusters in Chemistry; P. Braunstein, L.A. Oro and P.R. Raithby (Eds.), Wiley-VCH, Weinheim, Germany, 1999, pp. 715-740; ISBN: 3-527-29549-6 (editors' invitation).

   2.     Pyrazolate-bridged ruthenium(I) carbonyl complexes. (PDF)

           J.A. Cabeza and L.A. Oro, in Inorganic Syntheses, vol. 31; A.H. Cowley (Ed.), John Wiley & Sons, New York, USA, 1997, pp. 217-220; ISBN: 0-471-15288-9.

   1.     Dinuclear methoxy, cyclooctadiene, and barrelene complexes of rhodium(I) and iridium(I). (PDF)

           R. Usón, L.A. Oro and J.A. Cabeza, in Inorganic Syntheses, vol. 23; S. Kirschner (Ed.), John Wiley & Sons, New York, USA, 1985, pp. 126-130; ISBN: 0-471-81873-9.